Search results for "Microstructure"
showing 10 items of 707 documents
Interfacial Self-Assembly to Spatially Organize Graphene Oxide Into Hierarchical and Bioactive Structures
2020
Multicomponent self-assembly holds great promise for the generation of complex and functional biomaterials with hierarchical microstructure. Here, we describe the use of supramolecular co-assembly between an elastin-like recombinamer (ELR5) and a peptide amphiphile (PA) to organize graphene oxide (GO) flakes into bioactive structures across multiple scales. The process takes advantage of a reaction—diffusion mechanism to enable the incorporation and spatial organization of GO within multiple ELR5/PA layers. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and ImageJ software were used to demonstrate the hierarchical organization of GO flakes within the ELR5/PA lay…
Single-Point Incremental Forming of Titanium and Titanium Alloy Sheets.
2021
Incremental sheet forming of titanium and its alloys has a significant role in modern manufacturing techniques because it allows for the production of high-quality products with complex shapes at low production costs. Stamping processes are a major contributor to plastic working techniques in industries such as automotive, aerospace and medicine. This article reviews the development of the single-point incremental forming (SPIF) technique in titanium and its alloys. Problems of a tribological and microstructural nature that make it difficult to obtain components with the desired geometric and shape accuracy are discussed. Great emphasis is placed on current trends in SPIF of difficult-to-fo…
A Data-Driven Approach for Studying the Influence of Carbides on Work Hardening of Steel
2022
This study proposes a new approach to determine phenomenological or physical relations between microstructure features and the mechanical behavior of metals bridging advanced statistics and materials science in a study of the effect of hard precipitates on the hardening of metal alloys. Synthetic microstructures were created using multi-level Voronoi diagrams in order to control microstructure variability and then were used as samples for virtual tensile tests in a full-field crystal plasticity solver. A data-driven model based on Functional Principal Component Analysis (FPCA) was confronted with the classical Voce law for the description of uniaxial tensile curves of synthetic AISI 420 ste…
Improved time-resolved acousto-optic technique for optical fiber analysis of axial non-uniformities by using edge interrogation
2015
The time-resolved acousto-optic technique demonstrated recently to be a very useful method for the analysis of fiber axial non-uniformities, able to detect variations of fiber diameter in the nanometric scale with a spatial resolution of few cm. An edge interrogation approach is proposed to improve further the performance of this technique. The detection of subnanometer fiber diameter changes or sub-ppm changes of the core refractive index is demonstrated.
Effect of Cu-Zn coated steel fibers on high temperature resistance of reactive powder concrete
2019
Abstract Even though many studies have reported about the impacts of shape, length and distribution of steel fiber reinforcement on global concrete properties, there is a lack of information about the influence of coating type of steel fibers on high temperature resistance of concrete. This paper describes the effect of Cu-Zn coated steel fibers on selected properties of reactive powder concrete (RPC) after exposure to elevated temperatures. The initial corrosion of zinc in Cu-Zn surface layer is found to be already activated by the alkaline environment of the fresh concrete. The RPC samples reinforced with Cu-Zn coated steel fibers are heated to 600 °C and 1000 °C, and the influence of the…
Long-term stability of phase-separated half-Heusler compounds
2015
Half-Heusler (HH) compounds have shown high figure of merit up to 1.5. Here, we address the long-term stability of n- and p-type HH materials. For this purpose, we investigated HH materials based on the Ti0.3Zr0.35Hf0.35NiSn-system after 500 cycles (1700 h) from 373 to 873 K. Both compounds exhibit a maximum Seebeck coefficient of |α|≈ 210 μV K(-1) and a phase separation into two HH phases. The dendritic microstructure is temperature resistant and upon cycling the changes in the microstructure are so marginal that the low thermal conductivity values (κ4 W m(-1) K(-1)) could be maintained. Our results emphasize that phase-separated HH compounds are suitable low cost materials and can lead to…
Nanocrystalline ZnCO3—A novel sorbent for low-temperature removal of H2S
2013
Abstract The reactivity of a nanocrystalline ZnCO 3 toward H 2 S (0.2 vol% in N 2 /H 2 mixture) at 140–180 °C was characterized by thermal gravimetric analysis and by breakthrough curves measurements. We have found that under used conditions transformation of ZnCO 3 into ZnS is complete and the rate determining step of the sulfidation is the surface reaction. Such behavior is in strike contrast with that of ZnO whose sulfidation is severely limited by diffusion. The higher reactivity of ZnCO 3 in comparison with ZnO is attributed to the different microstructure of ZnS layer formed in these materials after a partial sulfidation. As in ZnO–ZnS transformation the molar volume increases (from 1…
Influence of the Preparation Method and Photo-Oxidation Treatment on the Thermal and Gas Transport Properties of Dense Films Based on a Poly(ether-bl…
2018
Dense films based on the hydrophobic Pebax®
Ceria-based electrolytes prepared by solution combustion synthesis: The role of fuel on the materials properties
2016
Ce0.8Sm0.2O2 â xpowders were synthesized by solution combustion synthesis using citric acid, cellulose and sucrose as single, or intimately mixed, fuels. The powders were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, N2sorption at â196 °C, H2-temperature programmed reduction and thermogravimetric analyses. Textural properties of the powders were shaped by the peculiar employed fuel. The study of reducibility revealed that oxygen vacancies formation is mainly influenced by both parameters, specific surface area and total pore volume. The different tendency toward reduction played a key role in sintering under reducing atmosphe…
Artichoke (Cynara cardunculus L.) fibres as potential reinforcement of composite structures
2011
Abstract The aim of this paper is to examine the use of artichoke fibres as potential reinforcement in polymer composites. The fibres are extracted from the stem of artichoke plant, which grows in Southern Sicily. In order to use these lignocellulosic fibres as potential reinforcement in polymer composites, it is fundamental to investigate their microstructure, chemical composition and mechanical properties. Therefore, the morphology of artichoke fibres was investigated through electron microscopy, the thermal behaviour through thermogravimetric analysis and the real density through a helium pycnometer. The chemical composition of the natural fibres in terms of cellulose, lignin, and ash co…