Search results for "Molar"
showing 10 items of 1069 documents
Demixing of Mixed Micelles. Thermodynamics of Sodium Perfluorooctanoate−Sodium Dodecanoate Mixtures in Water
1997
Conductivity, density, heat capacity, enthalpy of dilution, and osmotic coefficient measurements of water−sodium perfluorooctanoate (NaPFO)−sodium dodecanoate systems were carried out as functions of the surfactants' total molality (mt) at different mole fractions (XNaPFO). From conductivity data, the critical micelle concentration (cmc) and the degree of ionization (β) of the micelles were derived. The cmc's of the micelles are higher than those of the pure surfactants while β depends linearly on XNaPFO. At a given mole fraction, the apparent molar volume (VΦ) and heat capacity (CΦ) of the mixture increases and decreases monotonically with mt, respectively. From data in the premicellar reg…
Calorimetric investigation of the formation of ZnS nanoparticles in w/o microemulsions
1998
The enthalpies of precipitation of ZnS nanoparticles within water containing reversed micelles of sodium bis(2-ethylhexyl) solfosuccinate, L-α phosphatidylcholine, tetraethyleneglycol-mono-n-dodecyl ether and didodecyldimethylammonium bromide as a function of the molar concentration ratioR (R=[water]/[surfactant]) were measured by calorimetric technique. The results indicate that the energetic state of ZnS nanoparticles confined in the aqueous core of the reversed micelles is different from that in bulk water. Effects due to nanoparticle size, adsorption of HS− ions on the nanoparticle surface and interactions between nanoparticles and water/surfactant interfaces are discussed.
Mechanistic analysis and experimental verification of bicarbonate-controlled enteric coat dissolution: Potential in vivo implications
2019
Enteric coatings have shown in vivo dissolution rates that are poorly predicted by traditional in vitro tests, with the in vivo dissolution being considerably slower than in vitro. To provide a more mechanistic understanding of this, the dependence of the release properties of various enteric-coated (EC) products on bulk pH and bicarbonate molarity was investigated. It was found that, at presumably in vivo-relevant values, the bicarbonate molarity is a more significant determinant of the dissolution profile than the bulk pH. The findings also indicate that this steep relationship between the dissolution of enteric coatings and bicarbonate molarity limits those coatings' performance in vivo.…
Uptake of Acidic and Basic Sugar Derivatives in Lemna gibba G1
1989
The uptake of acidic and basic sugar derivatives in Lemna gibba L. was studied. Uronic acids applied to the experimental solution (50 millimolar) induced a small decrease of the membrane potential (10 +/- 1 millivolt galacturonic acid, and 20 +/- 4 millivolt glucuronic acid). After incubation of the plants in a 0.1 millimolar solution of these substrates, no decrease in the concentration of reducing groups in the external solution was detected. Respiration increased by 31% with 50 millimolar galacturonic acid, whereas no effect was found with the same concentration of glucuronic acid. Glucosamine caused a considerable concentration-dependent membrane depolarization. ((14)C)glucosamine uptak…
Thermodynamic studies of actinide complexes. 1. A reappraisal of the solution equilibria between plutonium(IV) and ethylenediaminetetraacetic acid (E…
2007
Abstract A detailed reevaluation of the complexation equilibria of plutonium(IV) with the polyaminocarboxylic sequestering agent EDTA4− has been performed in 1 M (H,K)NO3 media at 298 K by means of visible absorption spectrophotometry and glass-electrode potentiometry at millimolar concentration levels. The high binding affinity even under strongly acidic conditions supports the exclusive formation of the neutral Pu(EDTA) complex over the range 0.01 ≤ [H+] ≤ 0.9 M with an apparent formation constant of log β110 = 25.8(1) at 0.9 M HNO3. Extrapolation to zero ionic strength using the SIT approach provides the first ever-reported NEA–TDB compliant estimate of β 110 0 ( log β 110 0 = 32.2 ( 3 )…
Solubility of NH3 and apparent pK of NH4+ in human plasma, isotonic salt solutions and water at 37 degrees C.
1998
The solubility of ammonia, alphaNH3 (mM/mmHg), was determined at 37 degrees C and low ammonia partial pressure (0.02-1 mmHg) in pure water (n =24) as 46.70+/-0.40; aqueous isotonic salt solutions (n = 7) as 46.8+/-0.81; and human plasma (n = 5) as 42.0+/-0.66. The last figure increases to 45.3+/-0.63 if expressed in molal units (mmol/kg plasma water x mmHg) instead of molarity with respect to the water content of the plasma (mean from four healthy and fasting donors: 0.908+0.005 kg H2O/kg plasma; mean density at 37 degrees C: 1.020+/-0.002 kg/l). In pure water, the solubility value is the mean of three different methods: (a) extrapolation of the salting-out effect of ammonia in aqueous NaOH…
Kinetic interpretation of influence of sodium chloride concentration and temperature on xanthan gum dispersion flow model
2001
The present study derives a fixed-concentration (0.4%) xanthan gum dispersion flow model for different molar concentrations of sodium chloride (0–0.25M) and different temperatures (20–70°C). The Ostwald–de Waele model is used in all cases. A temperature rise reduces the shear-thinning characteristics of the systems, although the power law index is much less sensitive to changes in temperature when NaCl is added, even in very small amounts. The lowest consistency values correspond to the dispersions formulated in the absence of salt, the highest values are observed for molar values of ≥0.15, and there are decreases in consistency upon raising the temperature in all cases. The viscous behavio…
Precipitation of slightly soluble silver salts in reversed AOT micelles: Calorimetric investigation
1991
The enthalpies of precipitation, of AgCl, Agl, Ag2S and silver tetraphenylborate (AgTPB) in water containing reversed sodium bis(2-ethylhexyl) sulfosuccinate (AOT) micelles as a function of the molar concentration ratio R (R=[water]/[AOT]) at various concentrations of AOT and reagent salts, were measured by a calorimetric technique. The molar enthalpies of precipitation are independent of the surfactant concentration but are dependent on the concentration of the reagent salts and the R value. The molar enthalpies for the same processes in bulk water are not approached even at the highest R value. Effects due to the smallness of the microcrystals and to the interactions between ions and mice…
Rapid hyperpolarization and purification of the metabolite fumarate in aqueous solution
2020
Significance Magnetic resonance imaging is hindered by inherently low sensitivity, which limits the method for the most part to observing water molecules in the body. Hyperpolarized molecules exhibit strongly enhanced MRI signals which opens the door for imaging low-concentration species in vivo. Biomolecules can be hyperpolarized and injected into a patient allowing for metabolism to be tracked in real time, greatly expanding the information available to the radiologist. Parahydrogen-induced polarization (PHIP) is a hyperpolarization method renowned for its low cost and accessibility, but is generally limited by low polarization levels, modest molecular concentrations, and contamination by…
Phase diagrams calculated for sheared ternary polymer blends
1997
Abstract On the basis of the generalized Gibbs energy of mixing G γ (which is the sum of the Gibbs energy for zero shear and the energy the system stores in steady flow) phase diagrams were calculated as a function of shear rate γ for ternary model blends. This modelling uses simple equations for the description of the stagnant systems (Flory-Huggins) and for the contributions resulting from flow. Surface and alignment effects are neglected. A new procedure, which does not require the derivatives of G γ with respect to composition, was used to that end. Choosing typical values for the binary interaction parameters and molar masses, four classes of ternary systems were studied in greater det…