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showing 10 items of 6843 documents
Facile synthesis and characterization of monocrystalline cubic ZrO2 nanoparticles
2007
Abstract Crystalline ZrO2 nanoparticles were prepared from zirconium isopropoxide by slow hydrolysis and subsequent hydrothermal treatment of solutions containing various amounts of sodium hydroxide at 180 °C. Whereas moderately basic solutions lead to the formation of nanoparticles of monoclinic ZrO2 with plate-like morphology, and nanoparticles of the cubic ZrO2 high-temperature polymorph with diameters of approx. 5 nm were obtained from strongly basic solutions. The morphology, structure and properties of as-synthesized nanoparticles were characterized using HRTEM, XRD, Raman spectroscopy, UV–vis, PL spectroscopy and BET measurements. The formation of both, the monoclinic and the cubic p…
ChemInform Abstract: Facile Synthesis and Characterization of Monocrystalline Cubic ZrO2Nanoparticles.
2008
Abstract Crystalline ZrO2 nanoparticles were prepared from zirconium isopropoxide by slow hydrolysis and subsequent hydrothermal treatment of solutions containing various amounts of sodium hydroxide at 180 °C. Whereas moderately basic solutions lead to the formation of nanoparticles of monoclinic ZrO2 with plate-like morphology, and nanoparticles of the cubic ZrO2 high-temperature polymorph with diameters of approx. 5 nm were obtained from strongly basic solutions. The morphology, structure and properties of as-synthesized nanoparticles were characterized using HRTEM, XRD, Raman spectroscopy, UV–vis, PL spectroscopy and BET measurements. The formation of both, the monoclinic and the cubic p…
On the origin of the halo stabilization
2012
Monte Carlo simulations show that charge-regulation alone can cause highly charged zirconium nanoparticles to adsorb to a similarly charged or neutral silica particle and thereby stabilizing the latter. This mechanism, referred to as halo stabilization, is quite general and applicable in a range of systems provided that pH, van der Waals forces, and dissociation constants of the charge-regulating particles are properly chosen. In our modeling we see an overall attraction at low volume fractions of nanoparticles, while at higher a repulsive barrier is created, stabilizing the microparticles and protecting them from aggregation. The charge-regulation mechanism also turns the silica surface fr…
Extensions of the witness method to characterize under-, over- and well-constrained geometric constraint systems
2011
International audience; This paper describes new ways to tackle several important problems encountered in geometric constraint solving, in the context of CAD, and which are linked to the handling of under- and over-constrained systems. It presents a powerful decomposition algorithm of such systems. Our methods are based on the witness principle whose theoretical background is recalled in a first step. A method to generate a witness is then explained. We show that having a witness can be used to incrementally detect over-constrainedness and thus to compute a well-constrained boundary system. An algorithm is introduced to check if anchoring a given subset of the coordinates brings the number …
Noise removal using a nonlinear two-dimensional diffusion network
1998
Un reseau electrique non lineaire bidimensionnel, constitue de N×N cellules identiques, et modelisant l’equation de Nagumo discrete est presente. A l’aide d’une nouvelle description de la fonction non lineaire, on peut predire analytiquement l’evolution temporelle de la partie coherente du signal, ainsi que celle des perturbations de petites amplitudes qui lui sont superposees. Enfin, des applications a l’amelioration du rapport signal sur bruit, ou au traitement d’images sont suggerees.
Noise estimation from digital step-model signal
2013
International audience; This paper addresses the noise estimation in the digital domain and proposes a noise estimator based on the step signal model. It is efficient for any distribution of noise because it does not rely only on the smallest amplitudes in the signal or image. The proposed approach uses polarized/directional derivatives and a nonlinear combination of these derivatives to estimate the noise distribution (e.g., Gaussian, Poisson, speckle, etc.). The moments of this measured distribution can be computed and are also calculated theoretically on the basis of noise distribution models. The 1D performances are detailed, and as our work is mostly dedicated to image processing, a 2D…
Computational approach to compact Riemann surfaces
2017
International audience; A purely numerical approach to compact Riemann surfaces starting from plane algebraic curves is presented. The critical points of the algebraic curve are computed via a two-dimensional Newton iteration. The starting values for this iteration are obtained from the resultants with respect to both coordinates of the algebraic curve and a suitable pairing of their zeros. A set of generators of the fundamental group for the complement of these critical points in the complex plane is constructed from circles around these points and connecting lines obtained from a minimal spanning tree. The monodromies are computed by solving the defining equation of the algebraic curve on…
Darboux curves on surfaces I
2017
International audience; In 1872, G. Darboux defined a family of curves on surfaces of $\mathbb{R}^3$ which are preserved by the action of the Mobius group and share many properties with geodesics. Here, we characterize these curves under the view point of Lorentz geometry and prove that they are geodesics in a 3-dimensional sub-variety of a quadric $\Lambda^4$ contained in the 5-dimensional Lorentz space $\mathbb{R}^5_1$ naturally associated to the surface. We construct a new conformal object: the Darboux plane-field $\mathcal{D}$ and give a condition depending on the conformal principal curvatures of the surface which guarantees its integrability. We show that $\mathcal{D}$ is integrable w…
Interior Eigenvalue Density of Jordan Matrices with Random Perturbations
2017
International audience; We study the eigenvalue distribution of a large Jordan block subject to a small random Gaussian perturbation. A result by E. B. Davies and M. Hager shows that as the dimension of the matrix gets large, with probability close to 1, most of the eigenvalues are close to a circle.We study the expected eigenvalue density of the perturbed Jordan block in the interior of that circle and give a precise asymptotic description.; Nous étudions la distribution de valeurs propres d’un grand bloc de Jordan soumis à une petite perturbation gaussienne aléatoire. Un résultat de E. B. Davies et M. Hager montre que quand la dimension de la matrice devient grande, alors avec probabilité…
Spectral approach to D-bar problems
2017
We present the first numerical approach to D-bar problems having spectral convergence for real analytic, rapidly decreasing potentials. The proposed method starts from a formulation of the problem in terms of an integral equation that is numerically solved with Fourier techniques. The singular integrand is regularized analytically. The resulting integral equation is approximated via a discrete system that is solved with Krylov methods. As an example, the D-bar problem for the Davey-Stewartson II equations is considered. The result is used to test direct numerical solutions of the PDE.© 2017 Wiley Periodicals, Inc.