Search results for "Note"
showing 10 items of 10709 documents
Benchmarking of strength models for unidirectional composites under longitudinal tension
2018
© 2018 Elsevier Ltd Several modelling approaches are available in the literature to predict longitudinal tensile failure of fibre-reinforced polymers. However, a systematic, blind and unbiased comparison between the predictions from the different models and against experimental data has never been performed. This paper presents a benchmarking exercise performed for three different models from the literature: (i) an analytical hierarchical scaling law for composite fibre bundles, (ii) direct numerical simulations of composite fibre bundles, and (iii) a multiscale finite-element simulation method. The results show that there are significant discrepancies between the predictions of the differe…
Plasmonic nanostructures through DNA-assisted lithography
2018
DALI combines DNA origami with conventional top-down fabrication for creating designer high-resolution plasmonic nanostructures.
Ultrathin Films of 2D Hofmann-Type Coordination Polymers: Influence of Pillaring Linkers on Structural Flexibility and Vertical Charge Transport
2019
Searching for novel materials and controlling their nanostructuration into electronic devices is a challenging task ahead of chemists and chemical engineers. Even more so when this new application requires an exquisite control over the morphology, crystallinity, roughness and orientation of the films produced. In this context, it is of critical importance to analyze the influence of the chemical composition of perspective materials on their properties at the nanoscale. We report the fabrication of ultrathin films (thickness < 30 nm) of a family of FeII Hofmann-like coordination polymers by using an optimized liquid phase epitaxy (LPE) set-up. The series [Fe(L)2{Pt(CN)4}] (L = pyridine, pyri…
Graphene Field-Effect Transistors Employing Different Thin Oxide Films: A Comparative Study
2019
In this work, we report on a comparison among graphene field-effect transistors (GFETs) employing different dielectrics as gate layers to evaluate their microwave response. In particular, aluminum oxide (Al$_{2}$O$_{3}$), titanium oxide (TiO$_{2}$), and hafnium oxide (HfO$_{2}$) have been tested. GFETs have been fabricated on a single chip and a statistical analysis has been performed on a set of 24 devices for each type of oxide. Direct current and microwave measurements have been carried out on such GFETs and short circuit current gain and maximum available gain have been chosen as quality factors to evaluate their microwave performance. Our results show that all of the devices belonging …
Synthesis and helical supramolecular organization of discotic liquid crystalline dibenzo[hi,st]ovalene
2019
Dibenzo[hi,st]ovalene (DBOV) has emerged as a new polycyclic aromatic hydrocarbon (PAH) with intriguing optical properties with strong red emission. Nevertheless, DBOV derivatives thus far synthesized either had mesityl groups that hinder the pi-pi stacking of the aromatic cores or showed low solubility, and the self-assembly of DBOVs has not been investigated. In this work, two 3,4,5-tris(dodecyloxy)phenyl (TDOP) groups are introduced at the meso-positions of DBOV in order to enhance its solubility without compromising the intermolecular interactions. The obtained DBOV-TDOP forms at elevated temperatures a discotic liquid crystalline phase. Due to pi-pi-stacking interactions as well as loc…
MoSi2 laser cladding—a comparison between two experimental procedures: Mo–Si online combination and direct use of MoSi2
2001
International audience; There are very strong interests in developing low density advanced material systems for service at temperatures up to 1300°C. These materials should mainly have moderate fracture toughness at low and intermediate temperatures and should exhibit oxidation resistant behaviour. The intermetallic compound, MoSi2 has been considered to be an attractive candidate due to its melting point (2030°C) and excellent oxidation resistance at high temperatures. In this paper, we compare the results obtained with two different techniques for laser cladding, one using an online combination between Mo and Si powders, the second using direct injection of the MoSi2 powder.
Grafting of (3-chloropropyl)-trimethoxy silane on halloysite nanotubes surface
2021
Modified halloysite nanotubes (HNTs-Cl) were synthesized by a coupling reaction with (3-chloropropyl) trimethoxysilane (CPTMS). The incorporation of chloro-silane onto HNTs surface creates HNTs-Cl, which has great chemical activity and is considered a good candidate as an active site that reacts with other active molecules in order to create new materials with great applications in chemical engineering and nanotechnology. The value of this work lies in the fact that improving the degree of grafting of chloro-silane onto the HNT’s surface has been accomplished by incorporation of HNTs with CPTMS under different experimental conditions. Many parameters, such as the dispersing media, the molar…
Radiation-Induced Stable Radicals in Calcium Phosphates: Results of Multifrequency EPR, EDNMR, ESEEM, and ENDOR Studies
2021
This article presents the results of a study of radiation-induced defects in various synthetic calcium phosphate (CP) powder materials (hydroxyapatite—HA and octacalcium phosphate—OCP) by electron paramagnetic resonance (EPR) spectroscopy at the X, Q, and W-bands (9, 34, 95 GHz for the microwave frequencies, respectively). Currently, CP materials are widely used in orthopedics and dentistry owing to their high biocompatibility and physico-chemical similarity with human hard tissue. It is shown that in addition to the classical EPR techniques, other experimental approaches such as ELDOR-detected NMR (EDNMR), electron spin echo envelope modulation (ESEEM), and electronnuclear double resonance…
Evaluation of Rhodamine B Photocatalytic Degradation over BaTiO
2021
This research was funded by UIDB/50006/2020 with funding from FCT/MCTES through national funds and from the Institute of General and Ecological Chemistry of Lodz University of Technology. Susana L.H. Rebelo and Iwona Kuźniarska-Biernacka thank FCT (Fundação para a Ciência e Tecnologia) for funding through program DL 57/2016–Norma transitória (RE-QUIMTE/EEC2018/30 (SLHR) and REQUIMTE/EEC2018/14 (IKB)).
A New Methodological Approach to Correlate Protective and Microscopic Properties by Soft X-ray Microscopy and Solid State NMR Spectroscopy: The Case …
2021
Hydrophobic treatment is one of the most important interventions usually carried out for the conservation of stone artefacts and monuments. The study here reported aims to answer a general question about how two polymers confer different protective performance. Two fluorinated-based polymer formulates applied on samples of Cusa’s stone confer a different level of water repellence and water vapour permeability. The observed protection action is here explained on the basis of chemico-physical interactions. The distribution of the polymer in the pore network was investigated using scanning electron microscopy and X-ray microscopy. The interactions between the stone substrate and the protective…