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showing 10 items of 3963 documents

ATR-Spin: an open-source 3D printed device for direct cytocentrifugation onto attenuated total reflectance crystals.

2021

Infrared Spectroscopy (IR) enables the direct and rapid characterization of cells at the molecular level. Achieving a rapid and consistent cell preparation is critical for the development of Point-of-Care diagnostics for cell analysis. Here we introduce an open-source, 3D printed device for integrating the isolation, preconcentration, and measurement of attenuated total reflectance IR spectra of cells from biofluids. The tool comprises a disposable card for cytocentrifugation, equipped with magnets, which allows reproducible integration into the pathlength of the IR spectrophotometer. Preliminary results using cell media containing A459 cells indicate that this system enables a qualitative …

3d printedMaterials scienceSpectrophotometry Infraredbusiness.industryCell preparation010401 analytical chemistryBiomedical EngineeringInfrared spectroscopyBioengineeringCell analysis02 engineering and technologyGeneral Chemistry021001 nanoscience & nanotechnology01 natural sciencesBiochemistry0104 chemical sciencesOpen sourceMolecular levelAttenuated total reflectionPrinting Three-DimensionalSpectroscopy Fourier Transform InfraredOptoelectronics0210 nano-technologybusinessLab on a chip
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Genomic structure and functional characterization of the human ADAM10 promoter

2005

The ADAM10 gene encodes a membrane-bound disintegrin-metalloproteinase, which, after overexpression in an Alzheimer disease (AD) mouse model, prevents amyloid pathology and improves long-term potentiation and memory. Because enhancing ADAM10 expression appears to be a reasonable approach for treatment of AD, we functionally analyzed the ADAM10 gene. Both human and mouse ADAM10 genes comprise approximately 160 kbp, are composed of 16 exons, and are evolutionarily highly conserved within 500 bp upstream of either translation initiation site. By using luciferase reporter assays, we demonstrate that nucleotides -2179 to -1 upstream of the human ADAM10 translation initiation site represent a fun…

5' Flanking Region5' flanking regionTretinoinBiologyPolymorphism Single NucleotideBiochemistryCell LineConserved sequenceADAM10 ProteinMiceOpen Reading FramesExonAlzheimer DiseaseGeneticsAnimalsHumansPromoter Regions GeneticMolecular BiologyTranscription factorGeneConserved SequenceExpressed Sequence TagsIntronMembrane ProteinsPromoterExonsMolecular biologyIntronsADAM ProteinsOpen reading frameMutagenesis Site-DirectedAmyloid Precursor Protein SecretasesBiotechnologyThe FASEB Journal
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Small Residues Inhibit Homo-Dimerization of the Human Carbonic Anhydrase XII Transmembrane Domain

2021

Amino acids with small side chains and motifs of small residues in a distance of four are rather abundant in human single-span transmembrane helices. While interaction of such helices appears to be common, the role of the small residues in mediating and/or stabilizing transmembrane helix oligomers remains mostly elusive. Yet, the mere existence of (small)xxx(small) motifs in transmembrane helices is frequently used to model dimeric TM helix structures. The single transmembrane helix of the human carbonic anhydrases XII contains a large number of amino acids with small side chains, and critical involvement of these small amino acids in dimerization of the transmembrane domain has been sugges…

540 Chemistry and allied sciencesGALLEXGxxxGChemical technologycarbonic anhydrase XIITP1-1185transmembrane domainArticle570 Life sciencessmall amino acidsChemical engineering540 ChemieTP155-156interaction propensity570 Biowissenschaftenhelix–helix interactioninteraction motifMembranes
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CCDC 1950443: Experimental Crystal Structure Determination

2021

Related Article: Liu-Pan Yang, Li Zhang, Mao Quan, Jas S. Ward, Yan-Long Ma, Hang Zhou, Kari Rissanen, Wei Jiang|2020|Nat.Commun.|11|2740|doi:10.1038/s41467-020-16534-9

613192632394552-octabutoxy-3162942-tetraazanonacyclo[46.4.0.0510.0914.01823.02227.03136.03540.04449]dopentaconta-1(52)57911131820222426313335373944464850-icosaene-2172843-tetrone 14-dinitrobenzeneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1913148: Experimental Crystal Structure Determination

2019

Related Article: Hongxin Chai, Zhi-Sheng Pan, Liu-Pan Yang, Shan He, Fangfang Pan, Kari Rissanen, Wei Jiang|2019|Chem.Commun.|55|7768|doi:10.1039/C9CC03341F

613303749505152-octabutoxy-3162740-tetraoxanonacyclo[40.6.2.21825.0510.0914.01924.02934.03338.04348]dopentaconta-1(49)579111318202224293133353742(50)43454751-icosaene dimethylbis(4-t-butylbenzyl)ammonium hexafluorophosphateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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Unexpected Behavior of Enaminones: Interesting New Routes to 1,6-Naphthyridines, 2-Oxopyrrolidines and Pyrano[4,3,2-de][1,6]naphthyridines

2012

Reaction of enaminones 1a–d with 2-aminoprop-1-ene-1,1,3-tricarbonitrile (2) in the presence of AcOH/NH4OAc afforded 7-amino-5-oxo-5,6-dihydro-1,6-naphthyridine-8-carbonitrile derivatives 9a–d. On the other hand, 2-aminopyrano[4,3,2-de] [1,6]naphthyridine-3-carbonitriles 20a–c,e were the only obtained products from the reactions of 1a–d with 2 in the presence of AcOH/NaOAc, while 1d afforded [3,5-bis-(4-chloro-benzoyl)-phenyl]-(4-chloro-phenyl)-methanone 21 under the same condition. The reaction of 2 with diethyl acetylenedicarboxylate in the presence of AcOH/NH4OAc afforded (4-cyano-5-dicyanomethylene-2-oxo-2,5-dihydro-1H-pyrrol-3-yl)-acetic acid eth…

7-amino-5-oxo-56-dihydro-16-naphthyridine-8-carbonitrileMagnetic Resonance Spectroscopy2-aminoprop-1-ene-113-tricarbonitrileMolecular StructureChemistryOrganic ChemistryPharmaceutical ScienceEthyl esterMedicinal chemistryArticleAnalytical Chemistrylcsh:QD241-441Diethyl acetylenedicarboxylate3-amino-2-cyanopent-2-enedinitrilelcsh:Organic chemistryChemistry (miscellaneous)enaminonesNitrilesDrug DiscoveryTransition TemperatureMolecular Medicineenaminones; 3-amino-2-cyanopent-2-enedinitrile; 7-amino-5-oxo-56-dihydro-16-naphthyridine-8-carbonitrile; 2-aminoprop-1-ene-113-tricarbonitrileNaphthyridinesPhysical and Theoretical ChemistryMolecules
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CCDC 749971: Experimental Crystal Structure Determination

2010

Related Article: Y.Rousselin, N.Sok, F.Boschetti, R.Guilard, F.Denat|2010|Eur.J.Org.Chem.|2010|1688|doi:10.1002/ejoc.200901183

8b8c-Dimethyldecahydro-2a4a6a8a-tetraazacyclopenta[fg]acenaphthylene-1-carbonitrileSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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La adopción abierta en el derecho español

2016

El reconocimiento del derecho del menor adoptado a mantener contactos o relaciones con sus familiares de origen y sus anteriores acogedores representa un nuevo modelo de adopción en el Derecho español, denominado “adopción abierta”, recientemente introducida por la Ley 26/2015, de 28 de julio, que reforma el sistema español de protección de la infancia y la adolescencia. La nueva regulación se inspira en el Derecho de otros países pero tiene precedentes en ciertas normas autonómicas españolas The recognition of the right of the adopted children to maintain contacts or relations with their families of origin and previous welcoming, represents a new model of adoption in the Spanish law, which…

:CIENCIAS JURÍDICAS [UNESCO]Cartas y comunicacionesMantenimiento de relaciones con la familia de origen por acuerdo judicialPost adoption contact orderOpen adoptionAuto de adopciónCiencias jurídicasDerecho de visitaUNESCO::CIENCIAS JURÍDICASAdopción abiertaRight of visitLetter-boxAdoption orderWelfare checklistContact boxCiencias jurídicas. GeneralidadesBienestar emocional del menor
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Portales educativos : la producción de materiales didácticos digitales

2018

El objetivo principal de este artículo es conocer cómo se organiza la producción de los materiales didácticos digitales de creación propia de portales institucionales de recursos educativos, tomando como referencia la perspectiva de sus principales responsables. En concreto, se analiza el caso del repositorio institucional de recursos de la Comunidad Autónoma de Canarias, Ecoescuela 2.0; y del portal de recursos educativos en abierto Procomún (Ministerio de Educación, Cultura y Deporte). Con este estudio se pretende dar respuesta a distintas cuestiones relacionadas con la autoría de los materiales, el proceso y desarrollo, así como los criterios que establecen los portales institucionales p…

:CIENCIAS TECNOLÓGICAS [UNESCO]060106 history of social sciencesProcess (engineering)05 social sciences050301 education06 humanities and the artsUNESCO::CIENCIAS TECNOLÓGICASOpen educational resourcesPolitical scienceEducational resourcesProduction (economics)0601 history and archaeologyChristian ministryEngineering ethics0503 educationInclusion (education)Know-howQualitative research methodology
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Performance optimisation of biological pathway data storage, retrieval, analysis and its interactive visualisation

2018

The aim of this research was to optimise the performance of the storage, retrieval, analysis and interactive visualisation of biomolecular pathways data. This was achieved by the adoption of new technologies and a variety of highly optimised data structures, algorithms and strategies across the different layers of the software. The first challenge to overcome was the creation of a long-lasting, large-scale web application to enable pathways navigation; the Pathway Browser. This tool had to aggregate different modules to allow users to browse pathway content and use their own data to perform pathway analysis. Another challenge was the development of a high-performance pathway analysis tool t…

:CIENCIAS TECNOLÓGICAS [UNESCO]Pathway analysisUNESCO::CIENCIAS TECNOLÓGICASBiological pathwayOpen sourceGraph databaseData visualisation
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