Search results for "Optical"
showing 10 items of 7671 documents
Competing factors on the frequency separation between the OH stretching modes in water
2015
Abstract Recent simulations demonstrated that the inhomogeneous broadening as observed in the vibrational spectra of liquid water at ambient conditions can be viewed as a large vibrational splitting of symmetric and asymmetric OH stretching modes, due to the asymmetry of the local hydrogen-bonding network [J. Phys. Chem. Lett., 2013, 4(19), pp 3245–3250]. In this work, we show that the finite temperature and the liquid phase do not only modulate the local hydrogen-bonding asymmetry of water molecules, but also the intramolecular coupling strength. These two factors compete together in the determination of the overall magnitude of the frequency separation between the two OH stretching modes …
Experimental investigation of the relation between H− negative ion density and Lyman-α emission intensity in a microwave discharge
2016
International audience; A new mechanism for producing negative ions in low density and low power hydrogen plasmas was proposed recently. It refers to anion formation due to collisions between hydrogen atoms being in the first excited state. The proposed mechanism was indirectly supported by the quadratic relation observed between the extracted negative ion current and Lyman-α radiation of a filament-driven arc discharge, when borrowed data from the literature were combined. The present work provides experimental data comparing directly the absolute negative ion density and Lyman-α radiation in an ECR-driven hydrogen plasma source. The previously mentioned quadratic relation is not observed …
High energy, high resolution photoelectron spectroscopy of Co2Mn(1-x)Fe(x)Si
2006
This work reports on high resolution photoelectron spectroscopy for the valence band of Co2Mn(1-x)Fe(x)Si (x=0,0.5,1) excited by photons of about 8 keV energy. The measurements show a good agreement to calculations of the electronic structure using the LDA+U scheme. It is shown that the high energy spectra reveal the bulk electronic structure better compared to low energy XPS spectra. The high resolution measurements of the valence band close to the Fermi energy indicate the existence of the gap in the minority states for all three alloys.
ECT of ethanol and hexane mixtures in the spinning disk system
2007
The paper presents the research results of electrostatic charging tendency (ECT) of ethanol and hexane mixtures, a liquid of a simple chemical structure and high purity (pro analysis). The research work was carried out in a spinning disk system, where the factors influencing the value of the electrification current registered were the composition of the mixture and the rotational speed of the disk. The research results showed that the biggest ECT changes occur in the range of up to 10% of ethanol content in hexane and the electrification current characteristic has a visible maximum for the mixture, the contents of which constitute 95% of hexane volume and 5% of ethanol by volume. In the nex…
Protection concepts from optical radiation used in places of danger from explosion of gases, vapour or cloud of particles
2005
Use of optical systems in hazardous locations can result in ignition of surrounding explosive atmosphere. The conducted research work allowed to propose three protection concepts. The primary protection concept - inherently safe optical radiation - consists in use of optical radiation with power, energy or irradiance incapable of causing ignition of surrounding explosive atmosphere. However, the arbitrary determination of values of these parameters is considered as excessively rigorous. The work presents the proposed protection concepts in relation to zone classification. The author describes his own method to determine safe values based on probability mathematics that can be used not only …
Investigation on Metal–Oxide Graphene Field-Effect Transistors With Clamped Geometries
2019
In this work, we report on the design, fabrication and characterization of Metal-Oxide Graphene Field-effect Transistors (MOGFETs) exploiting novel clamped gate geometries aimed at enhancing the device transconductance. The fabricated devices employ clamped metal contacts also for source and drain, as well as an optimized graphene meandered pattern for source contacting, in order to reduce parasitic resistance. Our experimental results demonstrate that MOGFETs with the proposed structure show improved high frequency performance, in terms of maximum available gain and transition frequency values, as a consequence of the higher equivalent transconductance obtained.
Molecular polarizability of Scn, Cn and endohedral Scn@Cm clusters
2002
The interacting induced dipoles polarization model implemented in the program POLAR is used for the calculation of the molecular dipole-dipole polarizability . The method is tested with Sc1-Sc7, Sc12, Sc17, Sc74, C, C12, C60, C70, C82-fullerene, Sc@C60, Sc@C82, Sc2@C82, Sc3@C82, C1-C6, C10, C13, C16, C19, C22, C24, C42, C54, C84 and C96-graphite clusters. The polarizability is an important quantity for the identification of clusters with different numbers of atoms and even for the separation of isomers. The results for the polarizability are of the same order of magnitude as reference calculations performed with another program based on the same formulation. The bulk limit for the polarizab…
Simple model for the vibrations of embedded elastically cubic nanocrystals
2010
The purpose of this work is to calculate the vibrational modes of an elastically anisotropic sphere embedded in an isotropic matrix. This has important application to understanding the spectra of low-frequency Raman scattering from nanoparticles embedded in a glass matrix. First some low frequency vibrational modes of a free cubically elastic sphere are found to be nearly independent of one combination of elastic constants. This is then exploited to obtain an isotropic approximation for these modes which enables to take into account the surrounding isotropic matrix. This method is then used to quantatively explain recent spectra of gold and copper nanocrystals in glasses.
Size control of InAs∕InP(001) quantum wires by tailoring P∕As exchange
2004
The size and emission wavelength of self-assembled InAs∕InP(001) quantum wires (QWrs) is affected by the P∕As exchange process. In this work, we demonstrate by in situ stress measurements that P∕As exchange at the InAs∕InP interface depends on the surface reconstruction of the InAs starting surface and its immediate evolution when the arsenic cell is closed. Accordingly, the amount of InP grown on InAs by P∕As exchange increases with substrate temperature in a steplike way. These results allow us to engineer the size of the QWr for emission at 1.3 and 1.55 μm at room temperature by selecting the range of substrate temperatures in which the InP cap layer is grown.
Spectral properties of a variable period Bragg grating including a segment isolated of external deformations
2017
In this work the behavior of a Bragg grating of variable period (usually called a linearly chirped fiber Bragg grating — CFBG) is analyzed when a small portion of it is fixed so that its properties remain unchanged, while the rest of the grating is affected by a longitudinal deformation. The system was simulated using the Transfer Matrix Method to obtain its behavior under different levels of deformation and it was observed the appearance of negative peaks in the spectral response (transmission peaks). The analysis allowed characterizing the system with different sizes of the fixed portion (defects) (0.5 to 6 mm), for a grating with 10 cm long and 3 nm spectral width.