Search results for "PROB"
showing 10 items of 8859 documents
Plasmonic Nanosensor Array for Multiplexed DNA-based Pathogen Detection
2019
In this research we introduce a plasmonic nanoparticle based optical biosensor for monitoring of molecular binding events. The sensor utilizes spotted gold nanoparticle arrays as sensing platform. The nanoparticle spots are functionalized with capture DNA sequences complementary to the analyte (target) DNA. Upon incubation with the target sequence, it will bind on the respectively complementary functionalized particle spot. This binding changes the local refractive index, which is detected spectroscopically as the resulting changes of the localized surface plasmon resonance (LSPR) peak wavelength. In order to increase the signal, a small gold nanoparticle label is introduced. The binding ca…
A taylor series model to evaluate the interelemental effects in X-ray fluorescence analysis, applied to the iron-zirconium-diluent system
1995
A semi-empirical model has been developed to quantify the interelemental effects in X-ray fluorescence analysis. The measured X-ray fluorescence intensity has been expressed as a function of the different fluorescence elements composing the sample. this complex function has become an operative function via a Taylor series development. An explication has been given for the significance of the different terms of the series. These terms respond to mathematical functions known as characteristic functions for each chemical system. A parameter (B) has been defined which makes it possible to quantify the influence of the interelemental effect as a function of the analyte concentration (C) and that…
An Application of Analytic Network Process in the Planning Process: The Case of an Urban Transformation in Palermo (Italy)
2014
The primary objective of this study is to test the multicriteria analysis application in favor of a selection process among alternative transformations of an urban area in the city of Palermo. The choice is referred to as a strategyoriented one aiming to create “new urban centralities” able to redraw all urban structures that start to activate renewal processes within the existing city. The application of multicriteria analysis technique, such as the Analytic Network Process (ANP) - BOCR model, is due to the need to represent the complexity of the decision problem characterized by interrelations among several elements described by many indicators from different levels. The case study is als…
A Paradigm Interpreting the City and the Analytic Network Process for the Management of Urban Transformations
2018
When urban and environmental transformations occur in areas where the equilibrium between nature and culture is complex and fragile, public ad-ministrations could decide to induce private investments using several tools, such as financial contributions to those projects of refurbishment that better re-spect the purpose of improving the environmental quality and of preserving the local architecture. Multicriteria models may support public decision process re-garding this issue, but it is essential to adopt a scientific paradigm that provides a major theoretical reference. This study proposes the development of a net-work model based on the scientific paradigm by Rizzo and the Analytic Net-wo…
Highly Selective Detection of Nerve‐Agent Simulants with BODIPY Dyes
2014
Two chromo-fluorogenic probes, each based on the boron dipyrromethene core, have been developed for the detection of nerve-agent mimics. These chemosensors display both a color change and a significant enhancement of fluorescence in the presence of diethylcyanophosphonate (DCNP) and diisopropylfluorophosphate (DFP). No interference from other organophosphorus compounds or acids has been observed. Two portable chemosensor kits have been developed and tested to demonstrate its practical application in real-time monitoring.
Preparation and characterization of Al2O3 supported TiO2 catalysts employed for 4-nitrophenol photodegradation in aqueous medium
1998
Abstract In this paper the preparation and some bulk and surface characterizations of set of Al2O3 supported TiO2 photocatalysts are reported. The powders were home prepared by a wet impregnation method using titanium (IV) isopropylate. The impregnation was followed by thermal treatments and this procedure was repeated several times in order to obtain samples with different amounts of TiO2. The solids were characterized by X-ray diffraction, specific surface area determination, scanning electron microscopy coupled with an electron microprobe used in an energy-dispersive mode and diffuse reflectance spectroscopy. Moreover, all of them were tested as photocatalysts by using different kinds of…
Multichannel multiple scattering calculation ofL2,3-edge spectra ofTiO2andSrTiO3: Importance of multiplet coupling and band structure
2010
We report a theoretical study on x-ray absorption spectroscopy at the Ti-${L}_{2,3}$-edge of rutile and anatase ${\text{TiO}}_{2}$ as well as ${\text{SrTiO}}_{3}$. Using the first-principles multichannel multiple-scattering method, we obtain good agreement with experiment in all cases. We show that both multiplet-type electron correlation effects and the long-range band structure strongly influence the spectra. The differences in line shape between the three compounds are essentially a long-range effect which reflects the different crystal structures on a length scale of 1 nm.
A new hybrid method to improve the ultra-short-term prediction of LOD
2019
Accurate, short-term predictions of Earth orientation parameters (EOP) are needed for many real-time applications including precise tracking and navigation of interplanetary spacecraft, climate forecasting, and disaster prevention. Out of the EOP, the LOD (length of day), which represents the changes in the Earth’s rotation rate, is the most challenging to predict since it is largely affected by the torques associated with changes in atmospheric circulation. In this study, the combination of Copula-based analysis and singular spectrum analysis (SSA) method is introduced to improve the accuracy of the forecasted LOD. The procedure operates as follows: First, we derive the dependence structur…
The planar two-body problem for spheroids and disks
2021
We outline a new method suggested by Conway (2016) for solving the two-body problem for solid bodies of spheroidal or ellipsoidal shape. The method is based on integrating the gravitational potential of one body over the surface of the other body. When the gravitational potential can be analytically expressed (as for spheroids or ellipsoids), the gravitational force and mutual gravitational potential can be formulated as a surface integral instead of a volume integral, and solved numerically. If the two bodies are infinitely thin disks, the surface integral has an analytical solution. The method is exact as the force and mutual potential appear in closed-form expressions, and does not invol…
A gradient elasticity theory for second-grade materials and higher order inertia
2012
Abstract Second-grade elastic materials featured by a free energy depending on the strain and the strain gradient, and a kinetic energy depending on the velocity and the velocity gradient, are addressed. An inertial energy balance principle and a virtual work principle for inertial actions are envisioned to enrich the set of traditional theoretical tools of thermodynamics and continuum mechanics. The state variables include the body momentum and the surface momentum, related to the velocity in a nonstandard way, as well as the concomitant mass-accelerations and inertial forces, which do intervene into the motion equations and into the force boundary conditions. The boundary traction is the …