Search results for "Particules"
showing 10 items of 53 documents
Study of the dynamics of biomolecules by high speed atomic force microscopy and surface enhanced Raman spectroscopy
2015
This thesis focuses on the coupling of High–Speed Atomic Force Microscopy (HS-AFM) and Surface Enhanced Raman Spectroscopy (SERS) for biomolecule analysis. We have designed a fabrication protocol to manufacture “SERS-active” substrates. The efficacy of gold, silver and gold-silver bimetallic crystalline nanoparticle substrates were evaluated. We have investigated the impact of optical and morphological features of the substrates on Raman signal intensity by analyzing well-known samples such as bipyridine ethylene and methylene blue molecules. We took an interest in three distinct biological problematics with HS-AFM and SERS analyses. First, we have detected the chemical signature of cytochr…
Micro/nanostructured thin films : synthesis by ALD of composites associating TiO2 inverse opals and gold nanoparticles for photocatalysis applications
2021
The aim of this work was to improve the photocatalytic properties of titanium dioxide (TiO2) thin films, a semiconductor that is widely used for photocatalysis applications, particularly for the treatment of polluted water. For this purpose, two complementary approaches were studied: increasing the surface area available for photocalatytic reactions and coupling between TiO2 and gold nanoparticles.. For the first approach, TiO2 thin films with different morphological structures were fabricated by Atomic Layer Deposition: dense and porous flat films, and inverse opals films.In order to evaluate photocatalytic activity of the different films, the degradation of methylene blue in aqueous solut…
Characterization of organic matter in topsoils under rain forest and pasture in the eastern Brazilian Amazon basin
1999
In topsoils under forest and 7-, 12- and 17-year-old pastures, organic matter was characterized by analysing C and N distribution in particle-size fractions, the C decomposition rates of soil and particle-size fractions and by employing density-fractionation of macro-organic matter (>150 μm). The C and N associated with clay fractions increased with increasing age of pasture. The weight (%) of macro-organic matter and its heavy fractions (>1.37 g cm–3) also increased with increasing age of pasture. However, in a long-term incubation (100 days), these changes seemed to involve an increase in the C decomposition rate in the topsoil of the oldest pasture. Using the C decomposition rates of par…
Search for transient sources with the ANTARES and KM3NeT neutrino telescopes in the multi-messenger astronomy era
2020
En el presente manuscrito se expone el trabajo realizado en el seno de la Collaboración ANTARES-KM3NeT sobre la astronomía multi-mensanjero con neutrinos, que se ha enfocado en dos ejes: la detección de neutrinos de supernova a bajas energías (MeV) con los telecopios KM3NeT y la búsqueda de neutrinos de alta energía (TeV-PeV) en ANTARES en coincidencia con fuentes transitorias detectadas en ondas gravitationales o rayos gamma de muy alta energía O(TeV). El primer análisis, explora la capacidad de los telescopios de neutrinos KM3NeT para detectar la señal de una explosión de supernova (CCSN), así como el potencial de explotar dicha detección para aprender sobre la física que hay detrás, en p…
Searches for heavy neutrinos from Z decays
1992
We have searched for possible fourth family heavy neutrinos, pair produced in Z0 decays, in a sample of about 112 000 hadronic Z0 final states collected with the DELPHI detector. For all mixing matrix elements we exclude a new Dirac neutrino lighter than 44.5 GeV at a 95% confidence level, if the neutrino couples to the electron or muon family, and lighter than 44.0 GeV, if the neutrino couples to the tau family. Depending on the values of the mixing element and to which lepton family the neutrino couples, we obtain mass limits up to 46.2 GeV. For all mixing matrix elements we exclude a new Majorana neutrino lighter than 39.0 GeV, if it couples to the electron or the muon family, and lighte…
Syntheses of TiO2 anatase nanocrystals with controlled size distribution. Influence of the crystallites size on the Raman spectrum and investigation …
2006
The determination of the size and the size distribution of anatase TiO2 nanopowders using Raman spectroscopy is presented. Several synthesis methods (soft chemistry, water-in-oil microemulsion, continuous hydrothermal synthesis) are used in order to control the size (from 3 to 20 nm), shape, phase and size distribution. The shift and width of the anatase Eg peak are often used to obtain the nanoparticles size. Homever, this peak is also sensitive to nonstoichiometry and others parameters. Low-frequency Raman scattering does not suffer from this problem. Size distibutions obtained by Raman spectroscopy and MET micrographs are compared. Finally, in situ Raman spectroscopy is used to study the…
Étude des propriétés optiques et spectroscopiques de nanorods dopés au lanthanide pour des applications de nanosondes en champ proche
2022
Lanthanide-doped nanoparticles constitute a versatile family of photoluminescent local nanoprobes. In this work, we study the photoluminescence of Eu3+-doped NaYF4 nanorods characterized by highly polarized spectra. We develop a full theoretical model and paraxial approximation for nanorod dipole emission. We measure the photoluminescence of individual nanorods by fluorescence confocal microscopy and determine some of their intrinsic optical properties. We also determine the nature (electric or magnetic) and orientations of dipoles moments of the optical transitions used for nanoprobing in the visible range.In addition to the full theoretical model and the paraxial approximation, Fourier mi…
Rôle des antigènes tissulaires de groupes sanguins humains A, B, H et Lewis dans l'évolution des Norovirus GII.4
2011
Noroviruses are one of the leading causes of gastroenteritis worldwide. Since 2002 successive GII.4 variants have circulated in the population before being replaced every 2-3 years, which raises questions about the role of their histo-blood group antigen (HBGAs) receptors in their evolution. We analyzed the interaction between representative GII.4 variants and HBGAs and determined the role of selected amino acids (aa) in the binding profiles. By mutagenesis, we showed that there was a strict structural requirement for the aa directly implicated in HBGA bindings. The ablation of the threonine 395 residue, an epidemiological feature of the post 2002 variants, allowed to gain the capacity to b…
Computational Techniques for the Analysis of Small Signals in High-Statistics Neutrino Oscillation Experiments
2020
The current and upcoming generation of Very Large Volume Neutrino Telescopes – collecting unprecedented quantities of neutrino events – can be used to explore subtle effects in oscillation physics, such as (but not restricted to) the neutrino mass ordering. The sensitivity of an experiment to these effects can be estimated from Monte Carlo simulations. With the high number of events that will be collected, there is a trade-off between the computational expense of running such simulations and the inherent statistical uncertainty in the determined values. In such a scenario, it becomes impractical to produce and use adequately-sized sets of simulated events with traditional methods, such as M…
The effect of heat treatment on the morphology and mobility of Au nanoparticles
2020
This work was supported by The Centre National de la Recherche Scientifique (CNRS) of France and the French Embassy Program. The authors are also grateful for partial support by COST Action CA15216, the Estonian Science Foundation (grants PUT1689 and PUT1372), the Estonian Centre of Excellence in Zero Energy and Resource Efficient Smart Buildings and Districts, ZEBE, grant 2014-2020.4.01.15.0016 and Latvian Science Council grant lzp-2018/2-0083.