Search results for "Passivity"
showing 10 items of 34 documents
On Stability of Virtual Torsion Sensor for Control of Flexible Robotic Joints with Hysteresis
2019
Author's accepted manuscript (postprint). This article has been published in a revised form in Robotica, http://doi.org/10.1017/S0263574719001358. This version is free to view and download for private research and study only. Not for re-distribution or re-use. © 2019 Cambridge University Press. Available from 25/03/2020. Aim of the virtual torsion sensor (VTS) is in observing the nonlinear deflection in the flexible joints of robotic manipulators and, by its use, improving positioning control of the joint load. This model-based approach utilizes the motor-side sensing only and, therefore, replaces the load-side encoders at nearly zero hardware costs. For being applied in the closed control …
A CEMS/AES study of the passivation of iron
1989
The passivation of iron and steel (DIN 1623) was studied by integral and depth selective conversion electron Mossbauer spectroscopy and Auger electron spectroscopy. Thickness and phase composition of the passive layer formed in sulphate solution and in a phosphate buffer were determined in dependence on the anodic potential and the duration of the passivating procedure. The experimental results lead to the conclusion that not the whole oxidic layer is responsible for the passivity but only a very thin intermediate layer formed between the cubic substrate and the rhombic oxide (γ-FeOOH) cover.
Technical Note:Study of the Cl−-Induced Breakdown of the Passive Layer on Steel
1991
Abstract The Cl−-induced breakdown of the passive layer on a standard steel has an induction time that increases in a nearly linear fashion with the previous holding time (at the passivation potent...
State-feedback sampled-data control design for nonlinear systems via passive theory
2013
Published version of an article in the journal: Mathematical Problems in Engineering. Also available from the publisher at: http://dx.doi.org/10.1155/2013/230413 Open Access This paper investigates the problem of passive controller design for a class of nonlinear systems under variable sampling. The Takagi-Sugeno (T-S) fuzzy modeling method is utilized to represent the nonlinear systems. Attention is focused on the design of passive controller for the T-S fuzzy systems via sampled-data control approach. Under the concept of very-strict passivity, a novel time-dependent Lyapunov functional is constructed to develop passive analysis criteria and passive controller synthesis conditions. A new …
Optimal nonlinear damping control of second-order systems
2020
Novel nonlinear damping control is proposed for the second-order systems. The proportional output feedback is combined with the damping term which is quadratic to the output derivative and inverse to the set-point distance. The global stability, passivity property, and convergence time and accuracy are demonstrated. Also the control saturation case is explicitly analyzed. The suggested nonlinear damping is denoted as optimal since requiring no design additional parameters and ensuring a fast convergence, without transient overshoots for a non-saturated and one transient overshoot for a saturated control configuration.
Passive and transpassive behaviour of Alloy 31 in a heavy brine LiBr solution
2013
The passive and transpassive behaviour of Alloy 31, a highly alloyed austenitic stainless steel (UNS N08031), has been investigated in a LiBr heavy brine solution (400 g/l) at 25 °C using potentiostatic polarisation combined with electrochemical impedance spectroscopy and Mott–Schottky analysis. The passive film formed on Alloy 31 has been found to be p-type and/or n-type in electronic character, depending on the film formation potential. The thickness of the film formed at potentials within the passive region increases linearly with applied potential. The film formed at transpassive potentials is thinner and more conductive than the film formed within the passive region. These observations…
Critical Review—Photocurrent Spectroscopy in Corrosion and Passivity Studies: A Critical Assessment of the Use of Band Gap Value to Estimate the Oxid…
2017
A critical assessment of the Photocurrent Spectroscopy (PCS) Technique for the semi-quantitative characterization of passive film and corrosion layers composition is carried out. We take into account more than three decades of PCS usage as "in-situ" analytical technique and related results as well as the criticism of the underlying semi-empirical correlation relating the measured optical bandgap (Eg) to the passive film composition. The discrepancies between the experimental data, gathered by PCS measurements, and Egestimates originating from recently developed Density Functional Theory based modeling of solid state properties are stressed with particular emphasis on the case of anodic pass…
Effect of NaClO disinfection/cleaning on passive films on AISI 316L
2020
Abstract 316 L stainless steel samples were passivated in NaClO containing solutions in order to simulate disinfection processes. Passive films were grown at the open circuit potential by immersion in NaClO aqueous solutions at different concentrations and temperature in order to understand how exposure to aggressive environments could affect subsequent corrosion resistance of SSs. In the attempt to study the passive film growth mechanism, in-situ Open Circuit Potential measurements were performed in the same growth solutions. Photoelectrochemical and impedance investigation of passive films was carried out in order to link their solid state properties with their corrosion behaviour.
Corrosion resistance of passive films on different stainless steel grades in food and beverage industry
2020
Abstract Passive films were grown on 304 L, 316 L and Duplex stainless steels by immersion at open circuit potential in solutions mimicking food and beverage industry environments. In acidic food stainless steel surfaces are covered by Cr rich passive films, and generalized dissolution occurs on their surface with consequent ions release into the electrolyte. In fatty food the concentration of released ions is significantly lower since generalized corrosion does not occur, but the loss on MnS inclusions strongly reduces the polarization resistance in this environment especially for 304 L due to its higher localized corrosion susceptibility with respect to the other grades.
Analogy between the effects of a mechanical and chemical perturbation on the conductivity of passive films
2002
Abstract In order to study the passivity breakdown of a type 316L stainless steel, the electrochemical impedance and surface stresses were measured under straining conditions. The Mott–Schottky analysis, performed at high frequency, appears as very useful method to study, below the apparent yield strength, the effects of a mechanical stress on the capacitance values. The results obtained in sodium chloride media indicate that the semiconducting properties of passive films formed in a tensile stress field reflect a higher vacancies concentration than those formed in a stress-free state, suggesting that the passive film conductivity is increased. It was also shown that the Mott–Schottky plots…