Search results for "Pentane"

showing 10 items of 174 documents

Volatile Profiles of Emissions from Different Activities Analyzed Using Canister Samplers and Gas Chromatography-Mass Spectrometry (GC/MS) Analysis: …

2017

The objective of present study was to identify volatile organic compounds (VOCs) emitted from several sources (fuels, traffic, landfills, coffee roasting, a street-food laboratory, building work, indoor use of incense and candles, a dental laboratory, etc.) located in Palermo (Italy) by using canister autosamplers and gas chromatography-mass spectrometry (GC-MS) technique. In this study, 181 VOCs were monitored. In the atmosphere of Palermo city, propane, butane, isopentane, methyl pentane, hexane, benzene, toluene, meta- and para-xylene, 1,2,4 trimethyl benzene, 1,3,5 trimethyl benzene, ethylbenzene, 4 ethyl toluene and heptane were identified and quantified in all sampling sites.

010504 meteorology & atmospheric sciencescanisterHealth Toxicology and Mutagenesislcsh:Medicine010501 environmental sciences01 natural sciencesEthylbenzenePalermoArticleGas Chromatography-Mass Spectrometrychemistry.chemical_compoundPropaneCitiesBenzeneindoor0105 earth and related environmental sciencesvolatile organic compounds (VOCs)Air PollutantsVolatile Organic Compoundscanister; indoor; volatile organic compounds (VOCs); PalermoAtmospherelcsh:RPublic Health Environmental and Occupational HealthButaneToluenePentaneIsopentanechemistryItalyEnvironmental chemistryEnvironmental scienceGas chromatography–mass spectrometryEnvironmental MonitoringInternational Journal of Environmental Research and Public Health
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Trichoderma harzianum Strain T22 Modulates Direct Defense of Tomato Plants in Response to Nezara viridula Feeding Activity

2021

AbstractPlant growth-promoting fungi belonging to genus Trichoderma are known to help plants when dealing with biotic stressors by enhancing plant defenses. While beneficial effects of Trichoderma spp. against plant pathogens have long been documented, fewer studies have investigated their effect on insect pests. Here, we studied the impact of Trichoderma root colonization on the plant defense responses against stink bug feeding attack. For this purpose, a model system consisting of tomato plant, Solanum lycopersicum cv Dwarf San Marzano, Trichoderma harzianum strain T22 and the southern green stink bug, Nezara viridula, was used. We firstly determined stink bug performance in terms of rela…

0106 biological sciences0301 basic medicineTime FactorsTranscription GeneticGreen stink bugBeneficial soil microbes Jasmonic acid signaling pathway Pentatomidae Solanum lycopersicum Stink bugsCyclopentanesGenes PlantPlant Roots01 natural sciencesBiochemistryArticleHeteroptera03 medical and health scienceschemistry.chemical_compoundSolanum lycopersicumGene Expression Regulation PlantPentatomidaePlant defense against herbivoryAnimalsHerbivoryOxylipinsSymbiosisStink bugsEcology Evolution Behavior and SystematicsbiologyBeneficial soil microbesJasmonic acidfungifood and beveragesTrichoderma harzianumGeneral MedicinePentatomidaebiology.organism_classificationHorticulture030104 developmental biologychemistryNezara viridulaJasmonic acid signaling pathwayTrichodermaHypocrealesSeedsFemaleSolanumSignal Transduction010606 plant biology & botany
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Polyamine Oxidase 5 loss-of-function mutations in Arabidopsis thaliana trigger metabolic and transcriptional reprogramming and promote salt stress to…

2017

The family of polyamine oxidases (PAO) in Arabidopsis (AtPAO1-5) mediates polyamine (PA) back-conversion, which reverses the PA biosynthetic pathway from spermine, and its structural isomer thermospermine (tSpm), into spermidine and then putrescine. Here, we have studied the involvement of PA back-conversion in Arabidopsis salinity tolerance. AtPAO5 is the Arabidopsis PAO gene member most transcriptionally induced by salt stress. Two independent loss-of-function mutants (atpao5-2 and atpao5-3) were found to exhibit constitutively higher tSpm levels, with associated increased salt tolerance. Using global transcriptional and metabolomic analyses, the underlying mechanisms were studied. Stimul…

0106 biological sciences0301 basic medicineTranscription GeneticArabidopsis thalianaPhysiologyArabidopsisSperminePlant ScienceSodium Chloride01 natural scienceschemistry.chemical_compoundGene Expression Regulation PlantLoss of Function MutationArabidopsisPolyaminesMetabolitesArabidopsis thalianaPoliaminesAbscisic acidPrincipal Component AnalysisbiologyAgricultural SciencesSalt ToleranceMetabòlitsmetabolomicsPhenotypeBiochemistryMultigene FamilyMetabolomeCitric Acid CycleSalsCyclopentanes03 medical and health sciencesStress PhysiologicalOxylipinsRNA MessengerIonssalt toleranceArabidopsis ProteinsGene Expression ProfilingSodiumHydrogen PeroxideAgriculture Forestry and Fisheriesbiology.organism_classificationSpermidineGene Ontology030104 developmental biologychemistrythermosperminePutrescineSpermineSaltsOxidoreductases Acting on CH-NH2 Group DonorsTranscriptomejasmonatesPolyaminePolyamine oxidaseAbscisic Acid010606 plant biology & botany
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Arginase induction represses gall development during clubroot infection in Arabidopsis.

2012

Arginase induction can play a defensive role through the reduction of arginine availability for phytophageous insects. Arginase activity is also induced during gall growth caused by Plasmodiophora brassicae infection in roots of Arabidopsis thaliana; however, its possible role in this context has been unclear. We report here that the mutation of the arginase-encoding gene ARGAH2 abrogates clubroot-induced arginase activity and results in enhanced gall size in infected roots, suggesting that arginase plays a defensive role. Induction of arginase activity in infected roots was impaired in the jar1 mutant, highlighting a link between the arginase response to clubroot and jasmonate signaling. C…

0106 biological sciencesClubrootArabidopsis thalianaPhysiologyPyridinesArabidopsisplantPlant SciencePlasmodiophorida01 natural sciencesPlant RootsCallogenesisPlant Epidermischemistry.chemical_compoundJasmonateArabidopsisPlant TumorsGallArabidopsis thalianaJasmonateAmino AcidsComputingMilieux_MISCELLANEOUSchemistry.chemical_classification0303 health sciencesJasmonic acidfood and beveragesGeneral MedicineCell biologyArginasePLANT SCIENCESOrgan SpecificityPlasmodiophora brassicaeEnzyme Inductionnitric-oxideCyclopentanesBiologyHydroxylationAmidohydrolasesClubroot03 medical and health sciencesAuxinBotanymedicinethalianaOxylipinsIsoleucine030304 developmental biologydiseaseArginaseArabidopsis Proteinsfungijasmonic acid[SDV.BBM.BM]Life Sciences [q-bio]/Biochemistry Molecular Biology/Molecular biologyplasmodiophora-brassicaeCell BiologyDiazonium Compoundsbiology.organism_classificationmedicine.diseaserootarginine catabolism[SDV.BV.AP]Life Sciences [q-bio]/Vegetal Biology/Plant breedingchemistryMutationidentificationaccumulation010606 plant biology & botanyPlantcell physiology
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The Sulfated Laminarin Triggers a Stress Transcriptome before Priming the SA- and ROS-Dependent Defenses during Grapevine's Induced Resistance agains…

2018

Grapevine (Vitis vinifera) is susceptible to many pathogens which cause significant losses to viticulture worldwide. Chemical control is available, but agro-ecological concerns have raised interest in alternative methods, especially in triggering plant immunity by elicitor treatments. The β-glucan laminarin (Lam) and its sulfated derivative (PS3) have been previously demonstrated to induce resistance in grapevine against downy mildew (Plasmopara viticola). However, if Lam elicits classical grapevine defenses such as oxidative burst, pathogenesis-related (PR)-proteins and phytoalexin production, PS3 triggered grapevine resistance via a poorly understood priming phenomenon. The aim of this st…

0106 biological sciencesbeta-Glucanslcsh:MedicineCropsCyclopentanes01 natural sciencesBiochemistryFruitsAgricultural ProductionIntegrated ControlGene Expression Regulation PlantStress Physiological[SDV.BV]Life Sciences [q-bio]/Vegetal BiologyPlant ImmunityVitisOxylipinslcsh:ScienceBiologyGlucansComputingMilieux_MISCELLANEOUSDisease ResistancePlant Diseases2. Zero hungerMultidisciplinaryCell DeathPlant Biochemistrylcsh:R010401 analytical chemistryCell MembraneCrop DiseasesCorrectionAgricultureOrganic FarmingSustainable Agriculture0104 chemical sciences[SDV.BV.PEP]Life Sciences [q-bio]/Vegetal Biology/Phytopathology and phytopharmacyOomyceteslcsh:QPest ControlAgrochemicalsReactive Oxygen SpeciesSalicylic AcidTranscriptome010606 plant biology & botanyResearch ArticleSignal TransductionPLoS ONE
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Oleocanthal exerts antitumor effects on human liver and colon cancer cells through ROS generation

2017

The beneficial health properties of the Mediterranean diet are well recognized. The principle source of fat in Mediterranean diet is extra-virgin olive oil (EVOO). Oleocanthal (OC) is a naturally occurring minor phenolic compound isolated from EVOO, which has shown a potent anti-inflammatory activity, by means of its ability to inhibit the cyclooxygenase (COX) enzymes COX-1 and COX-2. A large body of evidence indicates that phenols exhibit anticancer activities. The aim of the present study was to evaluate the potential anticancer effects of OC in hepatocellular carcinoma (HCC) and colorectal carcinoma (CRC) models. A panel of human HCC (HepG2, Huh7, Hep3B and PLC/PRF/5) and CRC (HT29, SW48…

0301 basic medicineCancer ResearchCarcinoma HepatocellularHepatocellular carcinomaOleocanthalExtra-virgin olive oilCellApoptosisCyclopentane Monoterpenes03 medical and health scienceschemistry.chemical_compound0302 clinical medicinePhenolsOleocanthalmedicineHumansCyclooxygenase InhibitorsViability assayOlive OilCaspaseCell ProliferationAldehydesbiologyCell growthLiver NeoplasmsApoptosiHep G2 CellsCell cycledigestive system diseasesColorectal carcinoma030104 developmental biologymedicine.anatomical_structureOncologychemistryApoptosisCell culture030220 oncology & carcinogenesisImmunologybiology.proteinCancer researchReactive oxygen specieColorectal NeoplasmsReactive Oxygen SpeciesDNA DamageInternational Journal of Oncology
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Potential Uses of Olive Oil Secoiridoids for the Prevention and Treatment of Cancer: A Narrative Review of Preclinical Studies

2021

The Mediterranean diet (MD) is a combination of foods mainly rich in antioxidants and anti-inflammatory nutrients that have been shown to have many health-enhancing effects. Extra-virgin olive oil (EVOO) is an important component of the MD. The importance of EVOO can be attributed to phenolic compounds, represented by phenolic alcohols, hydroxytyrosol, and tyrosol, and to secoiridoids, which include oleocanthal, oleacein, oleuropein, and ligstroside (along with the aglycone and glycosidic derivatives of the latter two). Each secoiridoid has been studied and characterized, and their effects on human health have been documented by several studies. Secoiridoids have antioxidant, anti-inflammat…

0301 basic medicineSettore MED/09 - Medicina InternaSettore CHIM/10 - Chimica Degli AlimentiMediterranean dietAnti-Inflammatory AgentsReviewDiet MediterraneanAntioxidantsCyclopentane Monoterpeneslcsh:Chemistrychemistry.chemical_compound0302 clinical medicineGlucosidesNeoplasmsIridoidslcsh:QH301-705.5SpectroscopyTraditional medicineGeneral MedicinePhenylethyl AlcoholComputer Science Applications030220 oncology & carcinogenesissecoiridoidsIridoid GlucosidesAntineoplastic AgentsoleocanthalCatalysisInorganic Chemistry03 medical and health sciencesPhenolsOleuropeinOleocanthalmedicineAnimalsHumanscanceroleaceinPhysical and Theoretical ChemistryOlive OilMolecular BiologyPyransAldehydesOrganic ChemistryCancermedicine.diseaseTyrosol030104 developmental biologyAglyconelcsh:Biology (General)lcsh:QD1-999chemistryoleuropeinligstrosideHydroxytyrosolOlive oilInternational Journal of Molecular Sciences
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Novel functionalized cispentacin derivatives. Synthesis of 1,2,3-triazole-substituted 2-aminocyclopentanecarboxylate stereoisomers

2008

Four 1,2,3-triazole-substituted ethyl 2-amino-3-hydroxycyclopentanecarboxylate diastereomers (3,4-disubstituted cispentacins) with a cyclopentane skeleton were prepared in enantiomerically pure form from racemic β-lactam 7 via enzymatic ring opening, epoxidation and selective ring opening of the oxirane ring with sodium azide. The formation of the 1,2,3-triazole ring system involved click chemistry: 1,3-dipolar cycloaddition of the corresponding 4-substituted azidocarboxylates with diethyl acetylenedicarboxylate.

123-TriazoleChemistryStereochemistryOrganic ChemistryDiastereomerCispentacinRing (chemistry)CatalysisCycloadditionInorganic Chemistrychemistry.chemical_compoundClick chemistrySodium azidePhysical and Theoretical ChemistryCyclopentaneTetrahedron: Asymmetry
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Densities, Viscosities, and Refractive Indices of the Binary Systems Methyl tert-Butyl Ether + 2-Methylpentane, + 3-Methylpentane, + 2,3-Dimethylpent…

2000

This paper reports experimental densities, viscosities, and refractive indices of the binary systems methyl tert-butyl ether (MTBE) + 2-methylpentane, + 3-methylpentane, + 2,3-dimethylpentane, and + 2,2,4-trimethylpentane over the entire range of composition, at 298.15 K and atmospheric pressure. Excess molar volumes and viscosity deviations were evaluated from the experimental data. These excess or derived properties were fitted to the Redlich−Kister equation to estimate the binary interaction parameters. The experimental values of viscosity have been compared to values predicted by means of the GC−UNIMOD model.

2-MethylpentaneGeneral Chemical EngineeringAnalytical chemistryGeneral ChemistryGroup contribution methodchemistry.chemical_compoundViscosityMolar volumechemistryOrganic chemistryBinary system224-TrimethylpentaneMethyl tert-butyl ether3-MethylpentaneJournal of Chemical & Engineering Data
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CCDC 1901895: Experimental Crystal Structure Determination

2023

Related Article: Antti J. Neuvonen, Dimitris Noutsias, Filip Topić, Kari Rissanen, Tamás Földes, Imre Pápai, Petri M. Pihko|2019|J.Org.Chem.|84|15009|doi:10.1021/acs.joc.9b01980

2-[({2-[2-({[35-bis(trifluoromethyl)phenyl]carbamoyl}amino)-4-(trifluoromethyl)phenoxy]-23-dihydro-1H-inden-1-yl}carbamothioyl)amino]-NN-dimethylcyclohexan-1-aminium fluoride cyclopentane unknown solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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