Search results for "Perturbation Theory"

2021-$H_0$ Odyssey: Closed, Phantom and Interacting Dark Energy Cosmologies

2021

Up-to-date cosmological data analyses have shown that \textit{(a)} a closed universe is preferred by the Planck data at more than $99\%$ CL, and \textit{(b)} interacting scenarios offer a very compelling solution to the Hubble constant tension. In light of these two recent appealing scenarios, we consider here an interacting dark matter-dark energy model with a non-zero spatial curvature component and a freely varying dark energy equation of state in both the quintessential and phantom regimes. When considering Cosmic Microwave Background data only, a phantom and closed universe can perfectly alleviate the Hubble tension, without the necessity of a coupling among the dark sectors. Accountin…

Perturbative treatment of scalar-relativistic effects in coupled-cluster calculations of equilibrium geometries and harmonic vibrational frequencies …

2007

An analytic scheme for the computation of scalar-relativistic corrections to nuclear forces is presented. Relativistic corrections are included via a perturbative treatment involving the mass-velocity and the one-electron and two-electron Darwin terms. Such a scheme requires mixed second derivatives of the nonrelativistic energy with respect to the relativistic perturbation and the nuclear coordinates and can be implemented using available second-derivative techniques. Our implementation for Hartree-Fock self-consistent field, second-order Moller-Plesset perturbation theory, as well as the coupled-cluster level is used to investigate the relativistic effects on the geometrical parameters an…

Towards the Hartree-Fock and coupled-cluster singles and doubles basis set limit: A study of various models that employ single excitations into a com…

2010

In explicitly correlated coupled-cluster singles and doubles [CCSD(F12)] calculations, the basis set incompleteness error in the double excitations is reduced to such an extent that the error in the Hartree–Fock energy and the error in the single excitations become important. Using arguments from perturbation theory to systematically truncate the coupled-cluster singles and CCSD(F12) Lagrangians, a series of coupled-cluster models are proposed and studied that reduce these basis set incompleteness errors through additional single excitations into a complementary auxiliary basis. Convergence with model and size of complementary basis is rapid and there appears to be no need to go beyond seco…

Axial, induced pseudoscalar, and pion-nucleon form factors in manifestly Lorentz-invariant chiral perturbation theory

2006

We calculate the nucleon form factors G_A and G_P of the isovector axial-vector current and the pion-nucleon form factor G_piN in manifestly Lorentz-invariant baryon chiral perturbation theory up to and including order O(p^4). In addition to the standard treatment including the nucleon and pions, we also consider the axial-vector meson a_1 as an explicit degree of freedom. This is achieved by using the reformulated infrared renormalization scheme. We find that the inclusion of the axial-vector meson effectively results in one additional low-energy coupling constant that we determine by a fit to the data for G_A. The inclusion of the axial-vector meson results in an improved description of t…

Form factors for semileptonic B -> pi and D -> pi decays from the Omnes representation

2000

We use the Omnes representation to obtain the q-squared dependence of the form factors f+ and f0 for semileptonic H -> pi decays from the elastic pi H -> pi H scattering amplitudes, where H denotes a B or D meson. The scattering amplitudes used satisfy elastic unitarity and are calculated from two-particle irreducible amplitudes obtained using tree-level heavy meson chiral perturbation theory (HMChPT). The q-squared dependences for the form factors agree with lattice QCD results when the HMChPT coupling constant, g, takes values smaller than 0.32, and confirm the milder dependence of f0 on q-squared found in sumrule calculations.

Vector meson exchange in radiative kaon decays and chiral perturbation theory

1990

7 páginas, 4 figuras,1 tabla.

Some aspects of the nonperturbative renormalization of the phi^4 model

2007

A nonperturbative renormalization of the phi^4 model is considered. First we integrate out only a single pair of conjugated modes with wave vectors +/- q. Then we are looking for the RG equation which would describe the transformation of the Hamiltonian under the integration over a shell Lambda - d Lambda < k < Lambda, where d Lambda -> 0. We show that the known Wegner--Houghton equation is consistent with the assumption of a simple superposition of the integration results for +/- q. The renormalized action can be expanded in powers of the phi^4 coupling constant u in the high temperature phase at u -> 0. We compare the expansion coefficients with those exactly calculated by the…

Perturbative treatment of spin-orbit-coupling within spin-free exact two-component theory using equation-of-motion coupled-cluster methods.

2018

A scheme is reported for the perturbative calculation of spin-orbit coupling (SOC) within the spin-free exact two-component theory in its one-electron variant (SFX2C-1e) in combination with the equation-of-motion coupled-cluster singles and doubles method. Benchmark calculations of the spin-orbit splittings in 2Π and 2P radicals show that the accurate inclusion of scalar-relativistic effects using the SFX2C-1e scheme extends the applicability of the perturbative treatment of SOC to molecules that contain heavy elements. The contributions from relaxation of the coupled-cluster amplitudes are shown to be relatively small; significant contributions from correlating the inner-core orbitals are …

SU(3)-breaking corrections to the hyperon vector coupling f1(0) in covariant baryon chiral perturbation theory

2010

Surface Hopping Dynamics Including Intersystem Crossing using the Algebraic Diagrammatic Construction Method

2017

We report an implementation for employing the algebraic diagrammatic construction to second order [ADC(2)] ab initio electronic structure level of theory in nonadiabatic dynamics simulations in the framework of the SHARC (surface hopping including arbitrary couplings) dynamics method. The implementation is intended to enable computationally efficient, reliable, and easy-to-use nonadiabatic dynamics simulations of intersystem crossing in organic molecules. The methodology is evaluated for the 2-thiouracil molecule. It is shown that ADC(2) yields reliable excited-state energies, wave functions, and spin-orbit coupling terms for this molecule. Dynamics simulations are compared to previously re…