Search results for "Phase"

Metal ion-promoted activation of amino acid esters of carbohydrates in the synthesis of peptides

1992

Abstract Carbohydrate esters 1 and 2 of N-protected amino acids are activated by coordination of metal ions and subjected to aminolysis by amino acid esters 3 to form peptides 4 .

Coupled petrological-geodynamical modeling of a compositionally heterogeneous mantle plume

2018

Abstract Self-consistent geodynamic modeling that includes melting is challenging as the chemistry of the source rocks continuously changes as a result of melt extraction. Here, we describe a new method to study the interaction between physical and chemical processes in an uprising heterogeneous mantle plume by combining a geodynamic code with a thermodynamic modeling approach for magma generation and evolution. We pre-computed hundreds of phase diagrams, each of them for a different chemical system. After melt is extracted, the phase diagram with the closest bulk rock chemistry to the depleted source rock is updated locally. The petrological evolution of rocks is tracked via evolving chemi…

In Situ Heating TEM Study of Onion-like WS2 and MoS2 Nanostructures Obtained via MOCVD

2007

We report on the in situ heating transmission electron microscopy (TEM) study of WS2 and MoS2 nanoparticles obtained from metal–organic chemical vapor deposition (MOCVD). The general behavior of MoS2 and WS2 is similar: Round, amorphous particles in the pristine sample transform to hollow, onion-like particles upon annealing. A second type of particle with straight layers exhibits only minor changes. A significant difference between both compounds could be demonstrated in their crystallization behavior. The results of the in situ heating experiments are compared to those obtained from an ex situ annealing process under Ar.

Thin-layer chromatography of phenoxyacetic acid herbicides

1981

Power quality effects on the measurement of reactive power in three-phase power systems in the light of the IEEE Standard 1459–2000.

2007

Reactive power is a very important quantity in electric power systems since it affects the efficiency of these systems. Also, capacitive loads can produce over-voltages in electric transformers by Ferranti effect, which produces bad power quality, so it is necessary to measure the reactive power correctly. In this paper reactive phenomena in three-phase power systems with unbalanced voltages are expressed and measured in the light of the IEEE Std 1459-2000. For analyzing the reactive phenomena the positive-sequence fundamental frequency instantaneous reactive power is used. By comparing the expressions of this instantaneous power in three-phase systems with unbalanced voltages with those co…

The beta-decay of95Rb and97Rb

1983

Theβ-decay of 377 ms95Rb and 168ms97Rb has been thoroughly investigated by means ofγ-ray, conversion electron andβ-delayed neutron spectroscopy. More than 97% of theβ-decay to particle-bound states has been placed in level schemes of95Sr and97Sr. High-resolution neutron spectroscopic studies have allowed to extend the knowledge of the excitation spectra up to 9 MeV, respectively 10 MeV. The density of neutron-unbound levels in95Sr and97Sr has been derived from peak stripping analyses of the neutron spectra. Beta-strength functions (S β(E)) have been investigated in detail. They indicate that Gamow-Tellerβ-decay of both precursors is dominated by nuclear structure. The discovered pronounced …

Health-related quality of life (HRQOL) in patients (pts) with advanced gastric cancer/gastroesophageal junction cancer (GC/GEJC) or esophageal adenoc…

2021

4066 Background: CheckMate 649 (NCT02872116) is a randomized, open label phase 3 study in first line (1L) GC/GEJC/EAC. Prespecified interim results showed statistically significant improvement in overall survival (OS) and progression-free survival (PFS) for N+C vs C in all randomized pts and pts whose tumors expressed programmed death-ligand 1 combined positive score (CPS) ≥ 5. We present interim HRQOL results for CPS ≥ 5 pts, included as exploratory in the study. Methods: HRQOL was assessed using EQ-5D-3L (EQ-5D) and Functional Assessment of Cancer Therapy–Gastric Cancer (FACT-Ga). Assessments were performed at baseline (BL), every 6 weeks during treatment, and during follow-up. Change fr…

Characterization of Crystalline Structure and Morphology of Ga<sub>2</sub>O<sub>3</sub> Thin Film Grown by MOCVD Technique

2016

Growth of gallium oxide thin film was realized with MOCVD on (0001) sapphire substrate. Structural and compositional properties of thin film were studied employing trimethylgallium and water as precursors, carrier gases were H2 and N2. Obtained film is polycrystalline and predominantly consisted of (201) oriented β-Ga2O3. Sample exhibited blue luminescence which is attributed to oxygen vacancies. H2 gas proved to have beneficial effect on film quality and overall growth process.

Continuum Monte Carlo simulation of phase transitions in rod-like molecules at surfaces

1994

Stiff rod-like chain molecules with harmonic bond length potentials and trigonometric bond angle potentials are used to model Langmuir monolayers at high densities. One end of the rod-like molecules is strongly bound to a flat two-dimensional substrate which represents the air-water interface. A ground-state analysis is performed which suggests phase transitions between phases with and without collective uniform tilt. Large-scale off-lattice Monte Carlo simulations over a wide temperature range show in addition to the tilting transition the presence of a strongly constrained melting transition at high temperatures. The latter transition appears to be related to two-dimensional melting of th…

Measurement of the D→K−π+ strong phase difference in ψ(3770)→D0D¯0

2014

Abstract We study D 0 D ¯ 0 pairs produced in e + e − collisions at s = 3.773 GeV using a data sample of 2.92 fb−1 collected with the BESIII detector. We measured the asymmetry A K π CP of the branching fractions of D → K − π + in CP-odd and CP-even eigenstates to be ( 12.7 ± 1.3 ± 0.7 ) × 10 − 2 . A K π CP can be used to extract the strong phase difference δ K π between the doubly Cabibbo-suppressed process D ¯ 0 → K − π + and the Cabibbo-favored process D 0 → K − π + . Using world-average values of external parameters, we obtain cos δ K π = 1.02 ± 0.11 ± 0.06 ± 0.01 . Here, the first and second uncertainties are statistical and systematic, respectively, while the third uncertainty arises …