Search results for "Phase"

Triacylglycerol Analysis in Human Milk and Other Mammalian Species: Small-Scale Sample Preparation, Characterization, and Statistical Classification …

2015

In this work, a method for the separation of triacylglycerols (TAGs) present in human milk and from other mammalian species by reversed-phase high-performance liquid chromatography using a core–shell particle packed column with UV and evaporative light-scattering detectors is described. Under optimal conditions, a mobile phase containing acetonitrile/n-pentanol at 10 °C gave an excellent resolution among more than 50 TAG peaks. A small-scale method for fat extraction in these milks (particularly of interest for human milk samples) using minimal amounts of sample and reagents was also developed. The proposed extraction protocol and the traditional method were compared, giving similar results…

Pharmaceuticals in processing of municipal sewage sludge studied by grab and passive sampling

2018

Abstract Concentrations of pharmaceuticals, consisting of four anti-inflammatory and one antiepileptic drug, were studied in the aqueous and solid phase of municipal sewage sludge, collected from a wastewater treatment plant (WWTP) in central Finland. The samples included untreated municipal sludge from the biological wastewater treatment, digested sludge and sludge before and after composting. First, samples were taken as grab samples to study the bioavailable part in aqueous phase but also the part in solid fraction. Later, the long-term concentrations were studied by passive sampling with styrene divinylbenzene-reverse phase sulfonated (SDB-RPS) disks. In the untreated solid sludge, the …

Preconcentration and speciation analysis of mercury : 3D printed metal scavenger-based solid-phase extraction followed by analysis with inductively c…

2021

A selective method for preconcentration and determination of methylmercury (MeHg) and inorganic mercury (iHg) in natural water samples at the ng L−1 level has been developed. The method involves adsorption of Hg species into a 3D printed metal scavenger and sequential elution with acidic thiourea solutions before ICP-MS determination. Experimental parameters affecting the preconcentration of MeHg and iHg such as the sample matrix, effect of the flow rate on adsorption, eluent composition, and elution mode have been studied in detail. The obtained method detection limits, considering the preconcentration factors of 42 and 93, were found to be 0.05 ng L−1 and 0.08 ng L−1 for MeHg and iHg, res…

Rhombi-chain Bose-Hubbard model: Geometric frustration and interactions

2018

We explore the effects of geometric frustration within a one-dimensional Bose-Hubbard model using a chain of rhombi subject to a magnetic flux. The competition of tunnelling, self-interaction and magnetic flux gives rise to the emergence of a pair-superfluid (pair-Luttinger liquid) phase besides the more conventional Mott-insulator and superfluid (Luttinger liquid) phases. We compute the complete phase diagram of the model by identifying characteristic properties of the pair-Luttinger liquid phase such as pair correlation functions and structure factors and find that the pair-Luttinger liquid phase is very sensitive to changes away from perfect frustration (half-flux). We provide some propo…

Spurious source generation in mapping from noisy phase-self-calibrated data

2008

Phase self-calibration (or selfcal) is an algorithm often used in the calibration of interferometric observations in astronomy. Although a powerful tool, this algorithm presents strong limitations when applied to data with a low signal-to-noise ratio. We analyze the artifacts that the phase selfcal algorithm produces when applied to extremely noisy data. We show how the phase selfcal may generate a spurious source in the sky from a distribution of completely random visibilities. This spurious source is indistinguishable from a real one. We numerically and analytically compute the relationship between the maximum spurious flux density generated by selfcal from noise and the particulars of th…

Psychosocial Intervention: A Jornada de uma Revista Rumo a Qualidade Científica, Visibilidade e Internacionalização

2015

AbstractThis paper describes the journey that the journal Psychosocial Intervention began in 2011, with the aim of increasing its scientific quality and broadening its reach. Founded in 1992, Psychosocial Intervention began a new phase in 2011, with the advent of a new Editor-in-Chief, editorial team, and editorial policy. At that point, strategic decisions were made in the areas of editorial and review practices, language, and dissemination of the journal, which resulted in a publication of higher quality and broader reach. The description of the journey undertaken by Psychosocial Intervention is presented with the hope that this experience may be useful to scholars, scientific organizatio…

Suppression of phase ambiguity in digital holography by using partial coherence or specimen rotation

2008

In this paper we present two approaches for extracting the surface profile as well as obtaining 3D imaging of near field objects by usage of partial coherence and digital holography. In the first approach a light source with given temporal partial coherence is used to illuminate a near field object. The reflected light is interfered with the reference source. By computing the local contrast of the generated fringes one may estimate the 3D topography and the profile of the object. This approach extracts the 3D information from a single image, and its accuracy does not depend on triangulation angle like in fringe projection methods. The second approach is tomography based. There we illuminate…

Fine Mapping of Gene Ordering by Elongated Chromosome Methods

2006

Publisher Summary Fluorescence in situ hybridization (FISH) can be used to localize specific DNA sequences on metaphase chromosomes, interphase nuclei, and experimentally extended DNA or chromatin fibers. Depending on the hybridization target, FISH techniques show widely different levels of DNA resolution. Mechanically stretched or elongated chromosomes fill the resolution gap between metaphase FISH and fiber FISH, allowing the rapid and straightforward ordering and localization of clones along the length of an entire chromosome with a 100- to 200-kb resolution. Although various genome projects have provided very high-resolution physical maps of human and important animal genomes, FISH is s…

2019

Ankle plantar flexor muscles are active in the stance phase of walking to propel the body forward. Increasing walking speed requires increased plantar flexor excitation, frequently assessed using surface electromyography (EMG). Despite its popularity, validity of surface EMG applied on shank muscles is mostly unclear. Thus, we examined the agreement between surface and intramuscular EMG at a range of walking speeds. Ten participants walked overground at slow, preferred, fast, and maximum walking speeds (1.01 ± 0.13, 1.43 ± 0.19, 1.84 ± 0.23, and 2.20 ± 0.38 m s-1, respectively) while surface and fine-wire EMG activities of flexor hallucis longus (FHL), soleus (SOL), medial gastrocnemius (MG…

Modular Solid-Phase Synthesis of Antiprotozoal Barnesin Derivatives

2020

Here, we applied and optimized a solid support (SP)-based Horner-Wadsworth-Emmons reagent to prepare SP-bound vinylogous amino acids. Subsequent SP-based peptide synthesis, global deprotection, and chemical modifications yielded 14 lipodipeptides carrying vinylogous amino acids, including the natural product barnesin A (1). Biological evaluation revealed that several synthesized derivatives show micromolar to nanomolar inhibitory activity against papain-like cysteine proteases, human cathepsin L, and rhodesain.