Search results for "Phosphates"

showing 10 items of 273 documents

Influence of therapeutic and toxic doses of neuroleptics and antidepressants on energy metabolism of the isolated perfused rat brain.

1973

The isolated perfused rat brain was used for a comparative study of the effects of promazine, imipramine, monodesmethyl promazine and desipramine on cerebral energy metabolism. After perfusion for 30 min or 1 h the brain levels of the following substrates and metabolites were estimated: P-creatine, creatine, ATP, ADP, AMP, glycogen, glucose, glucose-6-P, fructose diphosphate, dihydroxyacetone-P, pyruvate, lactate, α-ketoglutarate, and ammonia. Drug concentrations of 5·10−6 M and 10−5 M in the perfusion medium caused a significant decrease of glucose-6-P alone. When the drug concentration was raised to a toxic range (10−4 M), reflected in the EEG by the pattern of secondary discharges, an ac…

Malemedicine.medical_specialtyImipraminePhosphocreatineBiologyPharmacologyCreatineImipramineAcetonechemistry.chemical_compoundOrganophosphorus CompoundsAmmoniaInternal medicineDesipramineTriosesmedicineAnimalsGlycolysisPyruvatesPromazinePromazinePharmacologyGlycogenDose-Response Relationship DrugDesipramineFructosephosphatesGlucosephosphatesBrainFructoseElectroencephalographyGeneral MedicineRibonucleotidesCreatineAntidepressive AgentsRatsPerfusionEndocrinologyGlucoseTranquilizing AgentschemistryLactatesKetoglutaric AcidsEnergy MetabolismPerfusionGlycolysismedicine.drugNaunyn-Schmiedeberg's archives of pharmacology
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Effect of acidosis on lipid peroxidation in brain slices.

1991

Acidification of the incubation medium markedly increased lipid peroxidation of cortical brain slices. Lactic acidosis caused a more extensive lipid peroxidation than did phosphoric acidosis (+35% at pH 6 and +81% at pH 5), probably due to the rapid diffusion of the protonated form of lactic acid across cell membranes. These results support the hypothesis that free radical mechanisms may be involved in the cytotoxicity of acidosis.

Malemedicine.medical_specialtyIn Vitro TechniquesPhosphatesLipid peroxidationchemistry.chemical_compoundSlice preparationInternal medicinemedicineAnimalsCytotoxicityMolecular BiologyIncubationAcidosisCerebral CortexChemistryGeneral NeuroscienceBrainRats Inbred StrainsMetabolismHydrogen-Ion Concentrationmedicine.diseaseLactic acidRatsKineticsEndocrinologyBiochemistryLactic acidosisLactatesNeurology (clinical)Lipid Peroxidationmedicine.symptomAcidosisDevelopmental BiologyBrain research
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Effects of glucocorticoid excess on the sensitivity of glucose transport and metabolism to insulin in rat skeletal muscle.

1997

This study examines the mechanisms of glucocorticoid-induced insulin resistance in rat soleus muscle. Glucocorticoid excess was induced by administration of dexamethasone to rats for 5 days. Dexamethasone decreased the sensitivity of 3-O-methylglucose transport, 2-deoxyglucose phosphorylation, glycogen synthesis and glucose oxidation to insulin. The total content of GLUT4 glucose transporters was not decreased by dexamethasone; however, the increase in these transporters in the plasma membrane in response to insulin (100 m-units/litre) was lessened. In contrast, the sensitivity of lactate formation to insulin was normal. The content of 2-deoxyglucose in the dexamethasone-treated muscle was …

Malemedicine.medical_specialtyMonosaccharide Transport Proteinsmedicine.medical_treatmentBlotting WesternGlucose-6-PhosphateMuscle ProteinsDeoxyglucoseBiochemistryDexamethasonechemistry.chemical_compoundInsulin resistanceInternal medicineHexokinasemedicineFructosediphosphatesAnimalsInsulinGlycolysisLactic AcidPhosphorylationRats WistarGlycogen synthaseMuscle SkeletalMolecular BiologyGlucocorticoidsHexokinaseGlucose Transporter Type 4biologyInsulinGlucose transporterCell BiologyMetabolismmedicine.diseaseRatsEndocrinologyGlucosechemistrybiology.protein3-O-MethylglucoseGLUT4GlycogenResearch Article
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Control of glycolysis in vertebrate skeletal muscle during exercise

1996

The gastrocnemius muscle of the frog (Rana temporaria) has a high capacity for anaerobic glycolysis from glycogen. Glycolytic metabolites and effectors of phosphofructokinase, particularly the hexose bisphosphates, were followed in muscle during exercise (swimming between 5 s and 5 min), recovery (rest for up to 2 h after 5 min of swimming), and repeated exercise (swimming for up to 60 s after 2 h of recovery). Glycogen phosphorylase and phosphofructokinase were swiftly activated with exercise. The hexose bisphosphates followed markedly different time courses. Fructose 1,6-bisphosphate was transiently increased in both exercise and repeated exercise. This appears to be an effect rather tha…

Malemedicine.medical_specialtyPhysiologyPhosphofructokinase-1Physical ExertionRana temporariaBiologychemistry.chemical_compoundGlycogen phosphorylasePhysiology (medical)Internal medicinemedicineAnimalsGlycolysisHexosephosphatesExercise physiologyMuscle SkeletalGlycogenSkeletal muscleHindlimbEnzyme Activationmedicine.anatomical_structureEndocrinologychemistryBiochemistryAnaerobic glycolysisGlycolysisAnaerobic exerciseGlycogenPhosphofructokinaseAmerican Journal of Physiology-Regulatory, Integrative and Comparative Physiology
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Calcium-enriched bread for treatment of uremic hyperphosphatemia

2004

Abstract Objective To assess phosphate-binding efficacy of a new food product, bread with unusually high calcium content (Ca-bread). Design and setting A randomized parallel group trial in the university hospital outpatient dialysis unit. Patients Fifty-three randomly selected uremic patients who met the following inclusion criteria: (1) required maintenance hemodialysis treatment, (2) were not to receive vitamin D throughout the study, (3) were nondiabetic, and (4) were diagnosed with hyperphosphatemia. Intervention Fifty-three patients were randomized into 2 groups: control group (n = 26), which received calcium acetate as a phosphate binder throughout the study, and Ca-bread group (n = 2…

Malemedicine.medical_specialtymedicine.drug_classmedicine.medical_treatmentElemental calciumMedicine (miscellaneous)chemistry.chemical_elementAcetatesCalciumPhosphatesHyperphosphatemiachemistry.chemical_compoundAnimal scienceRenal DialysismedicineVitamin D and neurologyHumansUremiaNutrition and Dieteticsbusiness.industrydigestive oral and skin physiologyfood and beveragesBreadCalcium CompoundsMiddle Agedmedicine.diseasePhosphateDiet RecordsSurgeryPhosphate binderCalcium DietarychemistryNephrologyFood FortifiedCalcium CompoundsPatient CompliancePhosphorus DietaryCalciumFemaleHemodialysisbusinessJournal of Renal Nutrition
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Sunscreen Products as Emerging Pollutants to Coastal Waters

2013

A growing awareness of the risks associated with skin exposure to ultraviolet (UV) radiation over the past decades has led to increased use of sunscreen cosmetic products leading the introduction of new chemical compounds in the marine environment. Although coastal tourism and recreation are the largest and most rapidly growing activities in the world, the evaluation of sunscreen as source of chemicals to the coastal marine system has not been addressed. Concentrations of chemical UV filters included in the formulation of sunscreens, such as benzophehone 3 (BZ-3), 4-methylbenzylidene camphor (4-MBC), TiO2 and ZnO, are detected in nearshore waters with variable concentrations along the day a…

Marine ChemistryMarine and Aquatic Scienceslcsh:MedicineHeavy MetalsOceanographyWater ChemistryAnalytical Chemistryvisual_art.visual_artistWater AnalysisWater QualityMicroalgaeWater pollutionlcsh:ScienceTitaniumMultidisciplinarySunbathingEcologyChemistryEcologyChemical OceanographyMarine EcologyChemical oceanographyZincChemistryEnvironmental chemistryvisual_artCoastal EcologyResearch ArticlePollutantsAlgal bloomPhosphatesBenzophenonesInhibitory Concentration 50Chemical AnalysisSunbathingMediterranean SeaHumansEnvironmental ChemistrySeawaterMarine ecosystemBiological oceanographyBiologyDiatomsPollutantBiological Oceanographylcsh:RKineticsSpainEarth SciencesSeawaterlcsh:QSunscreening AgentsWater Pollutants ChemicalEnvironmental Protection
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Tuning of the Mg Alloy AZ31 Anodizing Process for Biodegradable Implants

2021

Coatings were grown on the AZ31 Mg alloy by a hard anodizing process in the hot glycerol phosphate-containing electrolyte. Anodizing conditions were optimized, maximizing corrosion resistance estimated by impedance measurements carried out in Hank's solution at 37 °C. A post anodizing annealing treatment (350 °C for 24 h) allowed us to further enhance the corrosion resistance of the coatings mainly containing magnesium phosphate according to energy-dispersive X-ray spectroscopy and Raman analyses. Gravimetric measurements revealed a hydrogen evolution rate within the limits acceptable for application of AZ31 in biomedical devices. In vitro tests demonstrated that the coatings are biocompati…

Materials scienceAnnealing (metallurgy)Surface PropertiesAlloyMagnesium Compounds02 engineering and technologyElectrolyteengineering.material010402 general chemistry01 natural sciencesbiomedicalCorrosionCell LinePhosphatesMiceCoated Materials BiocompatibleAbsorbable ImplantsMaterials TestingAlloysAnimalsGeneral Materials ScienceMg alloyElectrodesMagnesium phosphatecorrosion resistanceAnodizing021001 nanoscience & nanotechnology0104 chemical sciencesDielectric spectroscopyCorrosionSettore ING-IND/23 - Chimica Fisica Applicataelectrochemical impedance spectroscopyChemical engineeringengineeringGravimetric analysishard anodizing0210 nano-technologyResearch ArticleACS Applied Materials & Interfaces
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Core-clad phosphate glass fibers for biosensing

2019

Recently, a phosphate glass with composition 20 CaO-20 SrO-10 Na2O-50 P2O5 (mol%) was found to have good potential as a biomaterial and to possess thermal properties suitable for fiber drawing. This study opened the path towards the development of fully bioresorbable fibers promising for biosensing. In the past, this phosphate glass with CeO2 was found to increase the refractive index and the glass stability. Therefore, a new SrO-containing glass was prepared with 1 mol% of CeO2 and core fibers were drawn from it. A core-clad fiber was also processed, where the core was a Ce-doped glass and the clad undoped, to allow for total internal reflection. The mechanical properties of the core and c…

Materials scienceBioengineeringBiosensing Techniques02 engineering and technology010402 general chemistry01 natural sciencesPhosphatesPhosphate glassBiomaterialschemistry.chemical_compoundUltimate tensile strengthComposite materialPhosphoric acidTotal internal reflectionBiomaterialCerium217 Medical engineering021001 nanoscience & nanotechnologyCladding (fiber optics)0104 chemical scienceschemistryStrontiumMechanics of Materials216 Materials engineeringGlass0210 nano-technologyBiosensorRefractive indexMaterials Science and Engineering: C
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Inorganic polymeric phosphate/polyphosphate as an inducer of alkaline phosphatase and a modulator of intracellular Ca2+ level in osteoblasts (SaOS-2 …

2011

Inorganic polymeric phosphate is a physiological polymer that accumulates in bone cells. In the present study osteoblast-like SaOS-2 cells were exposed to this polymer, complexed in a 2:1 stoichiometric ratio with Ca(2+), polyP (Ca(2+) salt). At a concentration of 100 μM, polyP (Ca(2+) salt) caused a strong increase in the activity of the alkaline phosphatase and also an induction of the steady-state expression of the gene encoding this enzyme. Comparative experiments showed that polyP (Ca(2+) salt) can efficiently replace β-glycerophosphate in the in vitro hydroxyapatite (HA) biomineralization assay. In the presence of polyP (Ca(2+) salt) the cells extensively form HA crystallites, which r…

Materials scienceBiomedical EngineeringSalt (chemistry)BiochemistryCell LinePhosphatesBiomaterials03 medical and health scienceschemistry.chemical_compoundBone cellExtracellularHumansMolecular BiologySaos-2 cells030304 developmental biologychemistry.chemical_classification0303 health sciencesOsteoblastsReverse Transcriptase Polymerase Chain ReactionPolyphosphate030302 biochemistry & molecular biologyGeneral MedicinePhosphateAlkaline PhosphataseImmunohistochemistrychemistryBiochemistryEnzyme InductionBiophysicsMicroscopy Electron ScanningAlkaline phosphataseCalciumIntracellularBiotechnologySignal TransductionActa Biomater.
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Iron and lithium-iron alkyl phosphates as nanostructured material for rechargeable batteries

2018

Abstract Inorganic/organic hybrid materials composed by iron atoms bonded to an alkyl phosphate can be easily synthesized by mixing at 110 °C iron chlorides with tri-alkyl phosphates. Since structural information on these products are lacking and taking into account that lithium/iron organic hybrid materials are important in lithium ion battery technology we report here the physico-chemical characterization of different hybrid lithium/iron butylphosphates. These materials are characterized by the presence of elongated hexagonal crystals stable up to 315 °C. The insertion of lithium does not affect the local structure. Thanks to such structures the material can be electrochemically-cycled an…

Materials scienceHybrid materials; Lithium ion batteries; Tri n-butyl phosphates; Materials Science (all); Condensed Matter Physics; Mechanics of Materials; Mechanical Engineeringchemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesRedoxLithium-ion batteryIonchemistry.chemical_compoundGeneral Materials ScienceTri n-butyl phosphatesAlkylchemistry.chemical_classificationMechanical EngineeringAlkyl phosphate021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesCharacterization (materials science)chemistryChemical engineeringLithium ion batteriesMechanics of MaterialsLithiumMaterials Science (all)Hybrid materials0210 nano-technologyHybrid material
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