Search results for "Polar"

Time-domain-induced polarization: Full-decay forward modeling and 1D laterally constrained inversion of Cole-Cole parameters

2012

Time-domain-induced polarization has significantly broadenedits field of reference during the last decade, from mineralexploration to environmental geophysics, e.g., for clay and peatidentification and landfill characterization. Though, insufficientmodeling tools have hitherto limited the use of time-domaininducedpolarization for wider purposes. For these reasons, anew forward code and inversion algorithm have been developedusing the full-time decay of the induced polarization response,together with an accurate description of the transmitter waveformand of the receiver transfer function, to reconstruct thedistribution of the Cole-Cole parameters of the earth. The accuratemodeling of the tra…

Polarizabilities of small annulenes from Cholesky CC2 linear response theory

2004

Using recently developed algorithms based on Cholesky decomposition of two-electron integrals to compute response properties at the correlated level, the static and dynamic (at 589 nm) polarizabilities of [4n + 2]-annulenes (n = 1, 2, 3, 4) have been calculated. The results show that the perpendicular component increases along the series linearly with the number of double bonds. The in-plane static polarizability is also increasing linearly with the area of the aromatic ring in the case of the delocalized species. However, linearity is lost for the localized conformations and for the dynamic polarizability. (C) 2004 Elsevier B.V. All rights reserved.

Theoretical analysis of hole self-trapping in ionic solids: Application to the KCl crystal.

1993

A method for the calculation of the hole self-trapping (ST) energy in ionic crystals is proposed. It combines model-Hamiltonian and quantum-chemical approaches. An artificial path for the ST process has been suggested containing (a) a free hole not interacting with the lattice vibrations; (b) a free-hole wave packet localized in a small crystal volume in the form of the real ST state, all crystal ions being in their perfect lattice positions; (c) the final ST state of the hole, accompanied with a corresponding lattice relaxation, including strong displacements of ions belonging to the hole region. Some intermediate states might be adopted between (a) and (b) in order to simplify the calcula…

Total angular momenta of even-parity autoionizing levels and odd-parity high-lying levels of atomic uranium

2002

Using three-step resonance ionization spectroscopy, over 200 even-parity autoionizing (AI) levels of atomic uranium, including Rydberg series converging to the second lowest ionic level (6L 11/2o), were observed in the 49 930–51 200 cm−1 energy range. Total angular momenta (J values) of these levels were determined by a polarization combination method as well as a method based on the J-momentum selection rule. Using the AI levels of which J values were determined unambiguously, unique J values were also assigned for about 70 high-lying odd-parity levels. The observed J-dependence on autoionization linewidth is interpreted as being due to a centrifugal potential barrier.

Coherent Light Harvesting through Strong Coupling to Confined Light

2018

When photoactive molecules interact strongly with confined light modes, new hybrid light–matter states may form: the polaritons. These polaritons are coherent superpositions of excitations of the molecules and of the cavity photon. Recently, polaritons were shown to mediate energy transfer between chromophores at distances beyond the Forster limit. Here we explore the potential of strong coupling for light-harvesting applications by means of atomistic molecular dynamics simulations of mixtures of photoreactive and non-photo-reactive molecules strongly coupled to a single confined light mode. These molecules are spatially separated and present at different concentrations. Our simulations sug…

Polarization-sensitive population trapping in an optically pumped laser

1994

Control of the high harmonic generation spectra by changing the molecule-laser field relative orientation

2010

The time dependent Schrodinger equation of a homonuclear diatomic molecule in the presence of a linearly polarized laser field is numerically solved by means of a split-operator parallel code. The calculations are carried out by assuming a single active electron model with fixed nuclei; a simplified two-dimensional model of the system is used. The highly nonlinear response of the electron wave function to the laser electric field stimulates the molecule to emit electromagnetic radiation consisting of a wide plateau of odd harmonics of the laser field. It is shown that the emitted spectrum can be finely controlled by changing the angle between the laser electric field and the molecular axis;…

Imperfect symmetry breaking

2018

By considering a nonlinear resonator driven by an elliptically polarized beam, we study experimentally the robustness of spontaneous symmetry breaking to controlled asymmetries. In particular, we reveal that different asymmetries can balance each other.

Polar coordinates in Taekwondo

2016

[EN] In observational methodology, inter‐relational behaviors are relevant for coaches and athletes to know which behaviors are dependent or inexistent while others occur.

Asymmetric balance in symmetry breaking

2020

Spontaneous symmetry breaking is central to our understanding of physics and explains many natural phenomena, from cosmic scales to subatomic particles. Its use for applications requires devices with a high level of symmetry, but engineered systems are always imperfect. Surprisingly, the impact of such imperfections has barely been studied, and restricted to a single asymmetry. Here, we experimentally study spontaneous symmetry breaking with two controllable asymmetries. We remarkably find that features typical of spontaneous symmetry breaking, while destroyed by one asymmetry, can be restored by introducing a second asymmetry. In essence, asymmetries are found to balance each other. Our st…