Search results for "Porosity"
showing 10 items of 599 documents
Microporous Triptycene‐Based Affinity Materials on Quartz Crystal Microbalances for Tracing of Illicit Compounds
2019
Triptycene-based organic molecules of intrinsic microporosity (OMIMs) with extended functionalized π-surfaces are excellent materials for gas sorption and separation. In this study, the affinities of triptycene-based OMIM affinity materials on 195 MHz high-fundamental-frequency quartz crystal microbalances (HFF-QCMs) for hazardous and illicit compounds such as piperonal and (-)-norephedrine were determined. Both new and existing porous triptycene-based affinity materials were investigated, resulting in very high sensitivities and selectivities that could be applied for sensing purposes. Remarkable results were found for safrole - a starting material for illicit compounds such as ecstasy. A …
Reactive transport modelling of carbonate cementation in a deep saline aquifer, the Middle Jurassic Oolithe Blanche Formation, Paris Basin, France.
2016
10 pages; International audience; The Oolithe Blanche Formation (Bathonian, Middle Jurassic) is one of the deep saline aquifers of the Paris Basin in France. The spatial distribution of its reservoir properties (porosity, permeability, tortuosity, etc.) is now better known with relatively homogeneous properties, except for some levels in the central part of the basin, where permeability exhibits higher values. This spatial distribution has been correlated with diagenetic events (variability of cementation) and palaeo-fluid flow circulation phases leading to variable cementation. In this paper, numerical simulations of reactive transport are performed. They provide a preliminary quantitative…
The effect of microscale pore structure on matrix diffusion—a site-specific study on tonalite
1997
Abstract The matrix diffusion of non-sorbing tracers was studied in rocks from the Syyry area, Central Finland (SY1). The effect of alteration and weathering on rock matrix porosity and on the available pore space, which affects diffusivity, are discussed. The main rock type in the crystalline bedrock of Syyry is a slightly foliated, gray tonalite with mica gneiss inclusions as well as minor, more mafic inclusions. The total porosity and the spatial porosity distribution and microstructure of the rocks were investigated using infiltration of carbon- 14-methylmethacrylate, electron microscopy and Hg-porosimetry. The laboratory-scale diffusion experiments were performed using (1) the out-leac…
Influence of microporosity distribution on the mechanical behavior of oolithic carbonate rocks.
2015
Abstract The mechanical behavior of oolithic carbonate rocks was investigated for selected rocks with two different microstructural attributes: uniform (UP) and rimmed (RP) distribution of microporosity within ooids. These oolithic carbonate rocks are from the Oolithe Blanche formation, a deep saline aquifer in the Paris Basin, and a possible target for CO2 sequestration and geothermal production. Samples of similar physical properties (porosity, grain diameter, cement content) but different microporosity textures were deformed under triaxial configuration, in water saturated conditions, at 28 MPa of confining pressure, 5 MPa of pore pressure and at a temperature of 55 °C. During the experi…
Natural gas hydrate investigations by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM)
2008
[1] We report the 3D microstructure analyses of natural gas hydrates sampled from Gulf of Mexico. The samples were characterized by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM) using the ‘TOMCAT’ beam line at the Swiss Light Source (SLS). The SRXCTM demonstrates its applicability to unlock some microscopic features of the marine hydrates, in particular of crystallite size and grain boundary network. The gas hydrate domains are surrounded by a network of pores of typically a few micrometers, which are largely due to decomposition. Out of the SRXCTM data, the porosity, total volume of the voids, the void surface area and number of the total gas-filled voids have been calcu…
From Norway Spruce Bark to Carbon Foams : Characterization, and Applications
2020
Fresh bark from spruce Picea abies was milled and extracted with hot water. The extracts were purified in a number of steps in order to get tannin-extracts pure enough to prepare tannin-based carbon foams. The chemical composition of the extracts were analyzed. The foams were maturated and thermally treated to obtain desired properties, such as specific surface area, porosity, and compressive strength. It was possible to produce carbon foams even if they contained carbohydrate impurities. Differences in the properties of the carbon foams such as compressive strength, specific surface areas, and pore size distributions might be related to the compositions of the extracts. The foams were fina…
The cork viewed from the inside
2015
International audience; Cork is the natural material stripped from the outer bark of cork oak. It is still the most used stopper to seal wine bottles and to preserve wine during storage. Cork stoppers are sorted in different classes according to apparent defects, named lenticels, which can be related to the cork macroporosity. The more lenticels there are, the worst cork quality is. The present work aims at investigating defects analysis of cork stoppers from two classes by comparing images recorded by digital photography and neutron imaging. Surface analysis of defects obtained from photography leads to more surface defects in class 4 (6.7%) than in class 0 (4.1%). Neutron radiography and …
Assessing the influence of fieldshaper material on magnetic pulse welded interface of Al/Cu joints
2019
Abstract Fieldshaper (FS) is a widely used component in magnetic pulse forming and welding to improve the efficiency of the process. It enables to increase the magnetic pressure experienced by the workpieces during forming and welding. Recent developments in this subject focuses to increase the life time of the fieldshaper and to improve the efficiency by introducing shape optimized designs. In this study, we compare the efficiency of four fieldshapers made of Cuprofor, Siclanic, CuBe2 and Steel. The main focus is given to the effect of material properties while the same geometry was considered for those four fieldshapers. The same welding conditions (discharge voltage of 6kV and air gap of…
The open metastable structure of a collapsible sand: fabric and bonding
2015
This paper deals with the compositional and textural characteristics determining open metastable structures in the pleistocenic sand outcropping in the Agrigento district (Sicily). The aim of the study was to individuate the bonding types occurring between grains that could generate matric suction phenomena. The composition and microfabric were characterised by means of granulometry, porosimetry, permeability, optical and ESEM-EDS microscopy, thermogravimetry and XR diffractometry, electric conductivity, and ionic chromatography. The data thus acquired show that the skeleton of the sand is constituted mostly by bioclasts and microfossils, calcite and quartz monocrystalline grains. Moreover,…
Characterization of the porous structure of Chilean volcanic soils by nitrogen adsorption and mercury porosimetry
2004
Pore volume, specific surface area (SSA), and total intragranular porosity (TIP) of Chilean soils derived from volcanic materials were studied. Soil samples involving the 0-15 and 15-30 cm depth of virgin and cultivated Collipulli (Ultisol) and Diguillin (Andisol) soils at two particle size fractions (<1 mm and <2 µm) were considered. From mercury porosimetry and N2 adsorption, mainly mesopores (pore diameter, dpore, about 10 nm) were determined for <1 mm Collipulli samples. Diguillin <1 mm soil shows macroporosity with dpore from 70 nm to 7000 nm. The clay fraction of Collipulli has macropores (dpore from 2000 nm to 40000 nm) and mesopores (dpore from 3 nm to 23 nm), while for Diguillin cl…