Search results for "RAMAN"
showing 10 items of 1328 documents
Ar CVD metodi sintezētu dimanta kristālu Ramana spektroskopija
2021
Bakalaura darba ietvaros tika apgūti Ramana spektrometra darbības principi, kā arī tika apgūta prasme mērīt un apstrādāt ar Ramana spektrometru pētāma materiāla Ramana spektru, tādējādi analizējot attiecīgā materiāla īpašības un to iespējamu pielietojumu. CVD dimanta kristālu paraugiem, kas tika audzēti uz Si pamatnes disku virsmām, tika izmērīti un savstarpēji salīdzināti Ramana spektri gan paraugu virsmas mikroskopisko telpisko defektu tuvumā, gan attālumā no tiem. Pēc iegūto joslu novietojumiem Ramana spektros tika analizēta šo defektu izcelsme, kā arī ietekme uz parauga īpašībām. Tika pētīta korelācija starp iegūtiem Ramana spektru parametriem – joslas pusplatumu un joslas pozīciju. Tik…
Correlative Raman-Electron-Light (CREL) Microscopy Analysis of Lipid Droplets in Melanoma Cancer Stem Cells.
2022
Among all neoplasms, melanoma is characterized by a very high percentage of cancer stem cells (CSCs). Several markers have been proposed for their identification, and lipid droplets (LDs) are among them. Different techniques are used for their characterization such as mass spectrometry, imaging techniques, and vibrational spectroscopies. Some emerging experimental approaches for the study of LDs are represented by correlative light–electron microscopy and by correlative Raman imaging–scanning electron microscopy (SEM). Based on these scientific approaches, we developed a novel methodology (CREL) by combining Raman micro-spectroscopy, confocal fluorescence microscopy, and SEM coupled with an…
Electron Irradiation Effects on Single‐Layer MoS 2 Obtained by Gold‐Assisted Exfoliation
2022
International audience; Mechanical exfoliation assisted by gold is applied to obtain good quality large lateral size single-layer MoS2. The effects of 2.5 MeV electron irradiation are investigated at room temperature on structural and electronic features by Raman and microluminescence spectroscopy. The exciton recombination emission in the direct bandgap of single-layer MoS2 is affected during irradiation starting from the minimum explored dose of 1 kGy. At higher doses, Raman bands show no relevant modifications whereas the exciton emission is quenched, suggesting that irradiation-induced point defects affect exciton dynamics.
Non-linear interactions of femtosecond laser pulses with graphene : photo-oxidation, imaging and photodynamics
2017
This thesis presents a study focused on interactions of femtosecond laser pulses with graphene, a one atom thick carbon membrane. Graphene, which exhibits exceptional electronic and optoelectronic properties, could provide considerable advantage over current silicon-based electronics. Graphene alone, being semi-metal, is not sufficient for electronic applications, but requires modification. For this, a set of methods for modifying and measuring the properties of graphene was developed. With the perspective of making graphene a suitable component for electronics, optoelectronics or photonics, ultrashort laser pulses were used for drawing patterns on graphene. The procedure modifies graphene …
Dielectrophoretic trapping and Raman spectroscopy of fluorescent oligonucleotides
2016
Nanotiede kasvaa edelleen tutkimusalana nopeasti, ja sille löytyy lukematon määrä sovelluskohteita. Sen vahvuutena on poikkitieteellisyys fysiikan, kemian ja biologian kesken, jotka kaikki tutkivat atomitason ilmiöitä. Näiden ilmiöiden tutkiminen ja soveltaminen vaatii paljon erilaisia, sofistikoituneita menetelmiä ja työkaluja, joilla voidaan valmistaa ja karakterisoida erilaisia nanopartikkeleita ja -rakenteita. Joissain tapauksissa vaaditaan jopa yksittäisten molekyylien tai atomien manipulointia nanometritasolla. DNA on yksi mielenkiintoisista nanotieteen tutkimuskohteista. Se on elämän kannalta merkittävä molekyyli, sillä se pitää sisällään elävän organismin rakenteellisen ohjeen. DNA:…
Analysis of Caffeine, Sweeteners, and Other Additives in Beverages by Vibrational Spectroscopy
2001
This chapter presents a review of the scientific literature on the use of vibrational spectroscopy, near-infrared (NIR), mid-infrared (mid-IR), and Raman, for the analysis of caffeine, sweeteners, and other additives in beverages and related products. Direct analysis procedures of coffee and tea, for both classification according to precedence or variety and quantitative determination of caffeine, are available. For beverage analysis, caffeine has been determined by direct attenuated total reflection (ATR) measurement or by transmission spectroscopy in the mid-IR region after extraction with chloroform. Different strategies have been employed for the analysis of sweeteners in beverages and …
The role of hydrochlorofluorocarbon densifiers in the formation of clathrate hydrates in deep boreholes and subglacial environments
2007
AbstractClear evidence for the formation of mixed clathrate hydrates of air and hydrochlorofluorocarbon densifier (known as HCFC-141b, sometimes also called R-141b) is found by means of synchrotron X-ray diffraction and Raman spectroscopy on a sample recovered from the bottom of the EPICA Dronning Maud Land deep borehole in Antarctica. Subglacial water (SGW) appears to have reacted with the drilling liquid to build a large lump of clathrate hydrate. The hydrate growth may well have been accelerated by the stirring of the SGW–densifier mixture during drilling. Moreover, dissolved air in the SGW appears to have participated in the formation of mixed hydrates of air and HCFC-141b as evidenced …
The nature of black stains in Lascaux Cave, France, as revealed by surface-enhanced Raman spectroscopy
2011
We used surface-enhanced Raman spectroscopy to investigate the chemical composition of the black stains threatening the rock-art paintings of Lascaux Cave, Montignac, France. The stains are mainly composed of melanin from the fungus Ochroconis sp. and the faecal pellets of the collembolan Folsomia candida. Surface-enhanced Raman spectroscopy is a useful technique for revealing the structure of unknown macromolecules in cultural heritage research. Copyright © 2011 John Wiley & Sons, Ltd.
Graphene oxide and Fumed silica graphene oxide nanocomposites modification by thermal treatments
2014
In the present study we investigate post synthesis thermal treatments up to 400 °C of graphene oxide (GrO) prepared from commercial graphite and of GrO–silica nanocomposites prepared by a solution of commercial Fumed silica nanoparticles (average diameter 7 nm or 40 nm) and the GrO. The thermal treatments were carried out in air, vacuum or He atmosphere to highlight tunable changes. Two GrO batches with small differences in the D (~1350 cm–1) and G (~1580 cm–1) Raman bands have been employed to evaluate effects depending on preparation. Thermal effects have been monitored through the Raman spectroscopy focusing on D, G and 2D (2500–3500 cm–1) bands spectral ranges. The experiments evidenced…
Suspended graphene device fabrication
2016
Tämän pro gradu -tutkielman aiheena oli tutkia itsekantavien grafeeninäytteiden valmistusta. Grafeeni syntetisoitiin kaasufaasikasvatuksella ilmakehän paineessa kupariohutkalvoille. Kupariohutkalvot valmistattiin käyttämällä elektronisuihkuhöyrystystä. Projektin aikana synteesiprosessia parannettiin optimoimalla synteesiparametreja. Syntetisoinnin jälkeen grafeeninäytteet siirrettiin piinitridikalvoille, joihin oli valmistettu reikiä. Viimeinen vaihe siirrossa on PMMA tukikerroksen poisto grafeenin päältä, jota tutkittiin käyttämällä kahta eri menetelmää. Näistä ensimmäinen menetelmä oli lämpökäsittely ja toinen kriittisen pisteen kuivaus PMMA:n asetoniin liuottamisen jälkeen. Näytteet kuva…