Search results for "RAMAN"
showing 10 items of 1328 documents
Optical phonon modes of wurtzite InP
2013
Optical vibration modes of InP nanowires in the wurtzite phase were investigated by Raman scattering spectroscopy. The wires were grown along the [0001] axis by the vapor-liquid-solid method. The A1(TO), E2h, and E1(TO) phonon modes of the wurtzite symmetry were identified by using light linearly polarized along different directions in backscattering configuration. Additionally, forbidden longitudinal optical modes have also been observed. Furthermore, by applying an extended 11-parameter rigid-ion model, the complete dispersion relations of InP in the wurtzite phase have been calculated, showing a good agreement with the Raman experimental data.
Magnetic-field-enhanced outgoing excitonic resonance in multi-phonon Raman scattering from polar semiconductors
1996
A combined scattering mechanism involving the states of free electron-hole pairs (exciton continuum) and discrete excitons as intermediate states in the multi-phonon Raman scattering leads to (1) a strong increase of the scattering efficiency in the presence of a high magnetic field and to (2) an outgoing excitonic resonance: the two features are not compatible when only free pairs (leading to a strong increase of the scattering efficiency under the applied magnetic field) or discrete excitons (resulting in the outgoing resonance at the excitonic gap) are taken into account.
Anomalous thermalization of nonlinear optical waves
2010
We report theoretically and experimentally an anomalous thermalization process characterized by an irreversible evolution of the waves towards a novel family of equilibrium states of a fundamental different nature than the standard thermodynamic equilibrium state.
Resonant Raman scattering in self-assembledGaN∕AlNquantum dots
2006
Self-assembled $\mathrm{Ga}\mathrm{N}∕\mathrm{Al}\mathrm{N}$ quantum dots have been investigated by means of Raman scattering. A resonant enhancement of the Raman peaks has been observed when the excitation is tuned above the GaN band-gap energy. The polar mode nature, either quasiconfined or interfacial, has been assigned after comparing with the polar optical modes of spheroidal dots calculated within the framework of the anisotropic dielectric continuum model. The built-in strain of the GaN dots induced a substantial blueshift of the nonpolar ${E}_{2H}$ Raman mode frequency. A theoretical model that analyzes the three-dimensional strain distribution in the quantum dots has been employed …
Resonant hyper-Raman scattering in semiconductors: Excitonic effects
1999
Abstract A theoretical model of resonant hyper-Raman scattering involving two incident photons of frequency ωL is developed. The model is valid for energies 2ℏωL around the absorption edge of the semiconductor, and takes into account Wannier excitons as intermediate states in the scattering process. Both deformation potential and Frohlich interaction are included in the model: It is found that Frohlich-mediated scattering is a dipole-allowed process, in contrast to one-phonon Raman scattering, where the Frohlich mechanism is dipole-forbidden. We have performed numerical calculations of the resonance profile (hyper-Raman cross-section versus 2ℏωL) and applied our model to materials with dipo…
Jahn-Teller effect in the phonon properties of defective SrTiO3from first principles
2012
the Jahn–Teller effect occurs, thus reducing the cubic symmetry of a perfect crystal and leading to the appearance of both Raman- and infrared-active vibrational modes. The calculated phonon densities of states and group-theoretical analysis of defect-induced phonon frequencies were used for the interpretation of the relevant experimental data, once defect-induced local modes are identified. The temperature dependence of the Vo formation energy based on the calculated Gibbs free energy was also compared with experiments, and the phonon contribution therein estimated.
Some comments on fluctuating-elasticity and local oscillator models for anomalous vibrational excitations in glasses
2011
Abstract An overview is given on the present status of the theoretical description of vibrational spectra of glasses, as seen by inelastic neutron, X-ray and light (Raman) scattering. Using the language of Green's/response functions the merits and shortcomings of a local oscillator and a generalized elasticity-theory point of view are discussed. It is pointed out that in both cases the interaction of phonons with disorder-induced irregularities leads to Rayleigh scattering (mean free path l ∝ ω − 4 ) at low enough frequencies and temperatures. In disordered solids at ambient temperature the Rayleigh scattering is usually masqued by Akhiezer-like anharmonic scattering l ∝ ω − 2 , but it can …
Excitonic model for second-order resonant Raman scattering.
1994
A theoretical model for second-order resonant Raman scattering is presented. The effect of Coulomb interaction between electrons and holes is fully taken into account in the framework of the effective-mass approximation. By introducing discrete and continuous excitonic intermediate states in the Raman process, an explicit expression for the Raman scattering efficiency is given for long-range Fr\"ohlich electron-phonon interaction. The model developed can be used to evaluate Raman profiles around the resonant region. A closed-form expression for all matrix elements of the exciton-phonon interaction is obtained once the Coulomb problem for the relative electron-hole motion is separated in sph…
Phonon properties of the spinel oxideMgTi2O4with theS=1/2pyrochlore lattice
2003
We study the phonon dynamics of ${\mathrm{MgTi}}_{2}{\mathrm{O}}_{4}$ spinel by measuring the Raman and infrared reflectivity spectra in a wide frequency $(100--3000{\mathrm{cm}}^{\ensuremath{-}1})$ and temperature (10 K--300 K) range. The reflectivity spectra are analyzed by a fitting procedure based on a model which includes both Drude and phonon oscillator contributions to the dielectric constant. The phonon assignment is done from comparison between experimental data and shell model lattice dynamical calculations. We find two infrared-active ${F}_{1u}$ symmetry modes superimposed on the free carrier continuum, and four Raman-active modes of ${1A}_{1g},$ ${1E}_{g},$ and ${2F}_{2g}$ symme…
Behavior of one-magnon frequency in antiferromagneticNicMg1−cOsolid solutions
2005
The one-magnon scattering was studied in antiferromagnetic ${\mathrm{Ni}}_{c}{\mathrm{Mg}}_{1\ensuremath{-}c}\mathrm{O}$ solid solutions. We observed unpredicted behavior of both temperature and composition dependences of one-magnon excitation energies. First, the abrupt change of the one-magnon frequency by $7--8\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$ occurs between $c=0.98$ and $c=0.9$ in the limit of $T\ensuremath{\rightarrow}0\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. Second, upon increasing temperature, the one-magnon energy for highly diluted nickel oxide vanishes significantly below the N\'eel temperature.