Search results for "RECTIFICATION"
showing 10 items of 44 documents
Optical Gating of Photosensitive Synthetic Ion Channels
2011
4-oxo-4-(pyren-4-ylmethoxy) butanoic acid is used as a photolabile protecting group to show the optical gating of nanofluidic devices based on synthetic ion channels. The inner surface of the channels is decorated with monolayers of photolabile hydrophobic molecules that can be removed by irradiation, which leads to the generation of hydrophilic groups. This process can be exploited in the UV-light-triggered permselective transport of ionic species in aqueous solution through the channels. The optical gating of a single conical nanochannel and multichannel polymeric membranes is characterised experimentally and theoretically by means of current-voltage and selective permeation measurements,…
Pore structure and function of synthetic nanopores with fixed charges: tip shape and rectification properties
2011
We present a complete theoretical study of the relationship between the structure (tip shape and dimensions) and function (selectivity and rectification) of asymmetric nanopores on the basis of previous experimental studies. The theoretical model uses a continuum approach based on the Nernst-Planck equations. According to our results, the nanopore transport properties, such as current-voltage (I-V) characteristics, conductance, rectification ratio, and selectivity, are dictated mainly by the shape of the pore tip (we have distinguished bullet-like, conical, trumpet-like, and hybrid shapes) and the concentration of pore surface charges. As a consequence, the nanopore performance in practical…
Fabrication of Single Cylindrical Au-Coated Nanopores with Non-Homogeneous Fixed Charge Distribution Exhibiting High Current Rectifications
2014
We have designed and characterized a cylindrical nanopore that exhibits high electrochemical current rectification ratios at low and intermediate electrolyte concentrations. For this purpose, the track-etched single cylindrical nanopore in polymer membrane is coated with a gold (Au) layer via electroless plating technique. Then, a non-homogeneous fixed charge distribution inside the Au-coated nanopore is obtained by incorporating thiol-terminated uncharged poly(N-isopropylacrylamide) (PNIPAM) chains in series to poly(4-vinyl pyridine) (PVP) chains, which are positively charged at acidic pH values. The functionalization reaction is checked by measuring the current–voltage (I–V) curves prior …
Current rectification in a single molecule diode: the role of electrode coupling.
2015
We demonstrate large rectification ratios (> 100) in single-molecule junctions based on a metal-oxide cluster (polyoxometalate), using a scanning tunneling microscope (STM) both at ambient conditions and at low temperature. These rectification ratios are the largest ever observed in a single-molecule junction, and in addition these junctions sustain current densities larger than 10^5 A/cm^2. By following the variation of the I-V characteristics with tip-molecule separation we demonstrate unambiguously that rectification is due to asymmetric coupling to the electrodes of a molecule with an asymmetric level structure. This mechanism can be implemented in other type of molecular junctions u…
The project scheduling polyhedron: Dimension, facets and lifting theorems
1993
Abstract The Project scheduling with resource constraints can be formulated as follows: given a graph G with node set N, a set H of directed arcs corresponding to precedence relations, and a set H′ of disjunctive arcs reflecting the resource incompatibilities, find among the subsets of H′ satisfying the resource constraints the set S that minimizes the longest path in graph (N, H ∪ S). We define the project scheduling polyhedron Qs as the convex hull of the feasible solutions. We investigate several classes of inequalities with respect to their facet-defining properties for the associated polyhedron. The dimension of Qs is calculated and several inequalities are shown to define facets. For …
Biomolecular conjugation inside synthetic polymer nanopores via glycoprotein-lectin interactions
2011
We demonstrate the supramolecular bioconjugation of concanavalin A (Con A) protein with glycoenzyme horseradish peroxidase (HRP) inside single nanopores, fabricated in heavy ion tracked polymer membranes. Firstly, the HRP-enzyme was covalently immobilized on the inner wall of the pores using carbodiimide coupling chemistry. The immobilized HRP-enzyme molecules bear sugar (mannose) groups available for the binding of Con A protein. Secondly, the bioconjugation of Con A on the pore wall was achieved through its biospecific interactions with the mannose residues of the HRP enzyme. The immobilization of biomolecules inside the nanopore leads to the reduction of the available area for ionic tran…
Heat rectification in He II counterflow in radial geometries
2018
Abstract We consider heat rectification in radial flows of turbulent helium II, where heat flux is not described by Fourier's law, but by a more general law. This is different from previous analyses of heat rectification, based on such law. In our simplified analysis we show that the coupling between heat flux and the gradient of vortex line density plays a decisive role in such rectification. Such rectification will be low at low and high values of the heat rate, but it may exhibit a very high value at an intermediate value of the heat rate. In particular, for a given range of values for the incoming heat ow, the outgoing heat flow corresponding to the exchange of internal and external tem…
Electrical Pumping of Potassium Ions Against an External Concentration Gradient in a Biological Ion Channel
2013
We show experimentally and theoretically that significant currents can be obtained with a biological ion channel, the OmpF porin of Escherichia coli, using zero-average potentials as driving forces. The channel rectifying properties can be used to pump potassium ions against an external concentration gradient under asymmetric pH conditions. The results are discussed in terms of the ionic selectivity and rectification ratio of the channel. The physical concepts involved may be applied to separation processes with synthetic nanopores and to bioelectrical phenomena. (C) 2013 AIP Publishing LLC.
AN APPROACH TO CORRECTING IMAGE DISTORTION BY SELF CALIBRATION STEREOSCOPIC SCENE FROM MULTIPLE VIEWS
2012
International audience; An important step in the analysis and interpretation of video scenes for recognizing scenario is the aberration corrections introduced during the image acquisition in order to provide and correct real image data. This paper presents an approach on distortion correction based on stereoscopic self calibration from images sequences by using a multi-camera system of vision (network cameras). This approach for correcting image distortion brings an elegant and robust technique with good accuracy. Without any knowledge of shooting conditions, the camera's parameters will be estimated. For this, the image key points of interest are extracted from different overlapping views …
On the design of observers robust to load variations for synchronous converters
2015
Due to the ever growing concern on energy efficiency issues, synchronous rectification gained increasing attention in recent years. In the semiconductor industry fast controllers developed for DC-DC converters are typically based on inductor current measures. In this context system costs and performances strictly depend on the current sensor and its proper design. In this paper we present a sensorless synchronous approach based on a current observer. The same observer formulation is valid for the three standard DC-DC converters, simplifying its design for different configurations. Furthermore the designed observers are proven to be robust against load variations, the most uncertain paramete…