Search results for "RFA"
showing 10 items of 11106 documents
Vibronic Model for Intercommunication of Localized Spins via Itinerant Electron
2019
In this article, we propose a vibronic pseudo Jahn–Teller model for partially delocalized mixed-valence molecules aimed to describe the magnetic coupling between the localized spins mediated by the delocalized electron. The simplest partially delocalized system that retains the main studied features is assumed to consist of a one-electron mixed-valence dimer, which is connected to the two terminal magnetic ions. The model involves the following key interactions: electron transfer in the spin-delocalized subsystem of a mixed-valence molecule, which is mimicked by a dimeric unit, coupling of the itinerant electrons with the molecular vibrations, and isotropic magnetic exchange between the loc…
Plasmonic nanosensors reveal a height dependence of MinDE protein oscillations on membrane features
2018
6 p.-4 fig.
Functionalized halloysite nanotubes: Efficient carrier systems for antifungine drugs
2018
Abstract Halloysite-cyclodextrin hybrid was employed as carrier for sustained release of clotrimazole for vaginal or buccal treatment of Candidiasis. The nanocarrier was obtained by functionalization of halloysite surface with cyclodextrin moieties by means of microwave irradiation, with the final goal to obtain a scaffold for the covalent linkage of cysteamine hydrochloride. The interaction between clotrimazole and the pristine components, namely cyclodextrin and halloysite, was thoroughly investigated by several techniques such as DSC, TGA, UV–vis spectroscopy and some adsorption studies were, also, carried out. The release of the antifungine molecule was finally investigated in a medium …
Self-assembled multivalent (SAMul) ligand systems with enhanced stability in the presence of human serum
2019
Self-assembled cationic micelles are an attractive platform for binding biologically-relevant polyanions such as heparin. This has potential applications in coagulation control, where a synthetic heparin rescue agent could be a useful replacement for protamine, which is in current clinical use. However, micelles can have low stability in human serum and unacceptable toxicity profiles. This paper reports the optimi- sation of self-assembled multivalent (SAMul) arrays of amphiphilic ligands to bind heparin in competitive conditions. Specifically, modification of the hydrophobic unit kinetically stabilises the self-assembled nanostructures, preventing loss of binding ability in the presence of…
Teaching clinical reasoning and decision-making skills to nursing students: Design, development, and usability evaluation of a serious game
2016
Background\ud \ud Serious games (SGs) are a type of simulation technology that may provide nursing students with the opportunity to practice their clinical reasoning and decision-making skills in a safe and authentic environment. Despite the growing number of SGs developed for healthcare professionals, few SGs are video based or address the domain of home health care.\ud \ud Aims\ud \ud This paper aims to describe the design, development, and usability evaluation of a video based SG for teaching clinical reasoning and decision-making skills to nursing students who care for patients with chronic obstructive pulmonary disease (COPD) in home healthcare settings.\ud \ud Methods\ud \ud A prototy…
Granulites and Palaeoproterozoic lower crust of the Baidarik Block, Central Asian Orogenic Belt of NW Mongolia
2017
Abstract Mafic granulite xenoliths are hosted by garnetiferous charnockites in the Archaean to Palaeoproterozoic Bumbuger Complex of northwestern Mongolia, one of the exotic basement terranes in the Central Asian Orogenic Belt. These rocks crystallized at ca. 1850 Ma under granulite-facies conditions (800 ± 27 °C, 6.8 ± 0.6 kbar) in the lower crust and were partly retrogressed to amphibolite-facies during ascent to higher crustal levels as a result of strong deformation resulting in northwest-trending isoclinal folds. The mafic xenoliths are likely derived from gabbroic protoliths, and geochemical, Hf-in-zircon and Nd whole-rock isotopic data suggest these rocks to have originated from pare…
Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke
2019
In order to contribute to the decarbonization of the economy, efficient alternatives to coal and coke should be found not only in the power sector but also in the industrial sectors (like steel, silicon and manganese production) in which coal and coke are used as a reductant and for steel production also as a fuel. To this aim many research works have been focused on the development of a coke substitute based on woody biomass and known as “biocarbon”. There are still barriers to overcome, among them: the biocarbon low density, poor mechanical strength and high reactivity. In this paper a new biocarbon production methodology is proposed, based on: pyrolysis at 600 °C, densification (using py…
Impact of accumulated dust particles' charge on the photovoltaic module performance
2016
Abstract This work is focused on analysing effect of accumulated dust particles' charge on PV module performance. In the Dundee University's laboratory, dust particles have been created through epoxy powder and charged by using corona and tribo-electric charging methods by varying the charge levels of the accumulated dust particles. The PV module output has analysed for finding a relation between charge levels of the accumulated dust particles and its output voltage. Obtained experimental results have shown that charge level of accumulated dust particles on PV module's have significant impact on its output and dust particle accumulations are not associated with panel tilt angle.
Experimental Investigation into the Effect of Pyrolysis on Chemical Forms of Heavy Metals in Sewage Sludge Biochar (SSB), with Brief Ecological Risk …
2021
Experimental investigations were carried out to study the effect of pyrolysis temperature on the characteristics, structure and total heavy metal contents of sewage sludge biochar (SSB). The changes in chemical forms of the heavy metals (Zn, Cu, Cr, Ni, Pb and Cd) caused by pyrolysis were analyzed, and the potential ecological risk of heavy metals in biochar (SSB) was evaluated. The conversion of sewage sludge into biochar by pyrolysis reduced the H/C and O/C ratios considerably, resulting in stronger carbonization and a higher degree of aromatic condensation in biochar. Measurement results showed that the pH and specific surface area of biochar increased as the pyrolysis temperature increa…
Optimization of photovoltaic solar power plant locations in northern Chile
2017
The optimization of photovoltaic solar power plants location in Atacama Desert, Chile, is presented in this study. The study considers three objectives: (1) Find sites with the highest solar energy potential, (2) determine sites with the least impact on the environment, and (3) locate the areas which produce small social impact. To solve this task, multi-criteria decision analyses (MCDAs) such as analytical hierarchy process and ordered weighted averaging were applied in a GIS environment. In addition, survey results of social impacts were analyzed and included into the decision-making process, including landscape values. The most suitable sites for solar energy projects were found near roa…