Search results for "RPE"

showing 10 items of 2566 documents

New Triterpenoid and Ergostane Glycosides from the Leaves of Hydrocotyle umbellata L.

2011

Two new triterpenoid glycosides, together with two new ergostane glycosides, umbellatosides A–D (1–4, resp.), have been isolated from the leaves of Hydrocotyle umbellata L. Their structures were established by 2D-NMR spectroscopic techniques (1H,1H-COSY, TOCSY, NOESY, HSQC, and HMBC) and mass spectrometry as 3β,22β-dihydroxy-3-O-[α-L-rhamnopyranosyl-(12)-β-D-glucuronopyranosyl]olean-12-en-28-oic acid 28-O-β-D-glucopyranosyl ester (1), 3-O-[α-L-rhamnopyranosyl-(12)-β-D-glucuronopyranosyl]oleanolic acid 28-O-β-D-glucopyranosyl ester (2), (3β,11α,26)-ergosta-5,24(28)-diene-3,11,26-triol 3-O-(β-D-glucopyranosyl)-11-O-(α-L-rhamnopyranosyl)-26-O-β-D-glucopyranoside (3), and (3β,11α,21,26)-ergosta…

chemistry.chemical_classificationErgostanebiologyStereochemistryOrganic ChemistryGlycosideHydrocotyle umbellataMass spectrometrybiology.organism_classificationBiochemistryCatalysisInorganic ChemistryTerpenechemistry.chemical_compoundTriterpenoidchemistryDrug DiscoveryOrganic chemistryPhysical and Theoretical ChemistryOleanolic acidTwo-dimensional nuclear magnetic resonance spectroscopyHelvetica Chimica Acta
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Ruminant fat volatiles as affected by diet. A review.

2006

Volatile compounds in meat have been widely studied for their favourable or undesirable effects on meat flavour, or for their potential use in tracing the animal feeding system. To date, the chemical mechanisms causing the appearance of volatile compounds in meat have been largely understood. Several variables are involved in the accumulation of volatiles in animal tissues and among them animal diet plays a key role. The purpose of the present review is to highlight the effects of different dietary regimes (concentrate, green grass and fat-enriched diets) on the appearance of fat volatile compounds in ruminant meat. Grain-based diets induce greater accumulations in meat of branched-chain fa…

chemistry.chemical_classificationFlavourfood and beveragesBiologybiology.organism_classificationTerpenechemistry.chemical_compoundchemistryRuminantGrazingPhenolsFood scienceFood SciencePolyunsaturated fatty acidMeat science
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13C NMR spectra of eudesmanolides I—eudesman-12,6-olides

1987

The 13C NMR spectra of 26 eudesmanolides of natural and synthetic origin have been measured, including the naturally occurring sesquiterpene lactones artemisin, torrentin, rothin-A and rothin-B and several semi-synthetic eudesman-12,6-olides obtained from artemisin. The chemical shift values of the different compounds are compared and the effects of the substituents are discussed.

chemistry.chemical_classificationGeneral ChemistryNuclear magnetic resonance spectroscopyCarbon-13 NMRSesquiterpeneSpectral linechemistry.chemical_compoundArtemisinechemistryProton NMROrganic chemistryChemical solutionGeneral Materials ScienceLactoneMagnetic Resonance in Chemistry
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Sesquiterpene lactones from Artemisia lucentica

1997

Abstract The aerial parts of Artemisia lucentica yielded, in addition to several known compounds, a bicyclic monoterpene ketone, two germacranolides, an eudesmanolide, a 10- epi neudesmanolide, a 2-norelemanolide and three bisabolene derivatives. The stereochemistry of a germacranolide, described as 2α-hydroxyartemorin in a previous investigation of the species, has now been corrected and the compound has been renamed lucentolide.

chemistry.chemical_classificationGermacranolideKetoneBicyclic moleculebiologyChemistryStereochemistryMonoterpenePlant ScienceGeneral MedicineHorticultureSesquiterpenebiology.organism_classificationBiochemistrychemistry.chemical_compoundOrganic chemistryArtemisiaBisaboleneMolecular BiologyLactonePhytochemistry
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A novel germacranolide-aminoacid adduct dimer from centaurea aspera

1991

Abstract The novel germacronolide-valine adduct dimer 1 has been isolated from aerial parts of Centaurea aspera var. aspera . Its structure has been determined by spectroscopic methods.

chemistry.chemical_classificationGermacranolideStereochemistryDimerfungiOrganic ChemistryNuclear magnetic resonance spectroscopySesquiterpeneBiochemistryAdductchemistry.chemical_compoundchemistryDrug DiscoveryCentaurea asperaLactoneTetrahedron Letters
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Sesquiterpene lactones from iranian Artemisia species

1993

Abstract The aerial parts of Artemisia turcomanica and A. deserti yielded two new germacranolides, a new guaianolide, and several known mono- and sesquiterpenes.

chemistry.chemical_classificationGermacranolidebiologyChemistryArtemisia desertiMonoterpenePlant ScienceGeneral MedicineHorticultureSesquiterpenebiology.organism_classificationBiochemistrychemistry.chemical_compoundBotanyArtemisiaSpectral analysisArtemisia turcomanicaMolecular BiologyLactonePhytochemistry
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Sesquiterpene lactones fromArtemisia barrelieri

1991

Abstract Extraction of aerial parts of Artemisia barrelieri and chromatographic separation yielded a new germacranolide, two new monocyclic sesquiterpenes and a novel germacranolide dimer, together with several known compounds.

chemistry.chemical_classificationGermacranolidebiologyStereochemistryPlant ScienceGeneral MedicineArtemisia barrelieriHorticultureSesquiterpenebiology.organism_classificationBiochemistrychemistry.chemical_compoundChromatographic separationchemistryAnthemideaeOrganic chemistryMolecular BiologyLactonePhytochemistry
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Sesquiterpene lactones from Centaurea sphaerocephala ssp. sphaerocephala

1994

Abstract Aerial parts of Centaurea sphaerocephala ssp. sphaerocephala furnished sesquiterpene lactones commonly found in Centaurea species as well as a new germacranolide and a new elemadienolide.

chemistry.chemical_classificationGermacranolidebiologyStereochemistryPlant ScienceGeneral MedicineHorticulturebiology.organism_classificationSesquiterpeneBiochemistrychemistry.chemical_compoundchemistryCentaureaOrganic chemistryMolecular BiologyLactonePhytochemistry
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Sesquiterpene lactones and dihydroflavonols from Andryala and Urospermum species

1994

Abstract The aerial parts of two Andryala species yielded several guaianolides and guaianolide glycosides, three of them being new. The aerial parts of Urospermum dalechampii yielded several known germacranolides and the new dihydroflavonol 3- O -methyltaxifolin.

chemistry.chemical_classificationGermacranolidebiologyUrospermum dalechampiiStereochemistryGlycosidePlant ScienceGeneral MedicineHorticultureSesquiterpeneAndryalabiology.organism_classificationBiochemistrychemistry.chemical_compoundchemistryBotanyUrospermumUrospermum picroidesMolecular BiologyLactonePhytochemistry
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Isolation of Alkaloids from Cultured Hybrid Cells of Rauwolfia serpentina*Rhazya stricta.

1996

Two monoterpenoid indole alkaloids and four β-carbolines were isolated from a hydrid cell suspension culture generated from two Apocynaceous plants, Rauwolfia serpentina Benth. and Rhazya stricta Decaisne. This indicates that the function of alkoloid biosynthesis is retained after hybrid formation and that alkaloids not previously detected in the parental plants or cell cultures are formed.

chemistry.chemical_classificationIndole alkaloidbiologyApocynaceaeChemistryAlkaloidMonoterpeneGlycosideGeneral ChemistryGeneral MedicinePharmacognosyRhazya strictabiology.organism_classificationCell cultureDrug DiscoveryBotanyheterocyclic compoundsChemical and Pharmaceutical Bulletin
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