Search results for "Reflection"
showing 10 items of 645 documents
Near-field characterization of Bragg mirrors engraved in surface plasmon waveguides
2004
International audience; Surface plasmon waveguides (SPW's) are metal ridges featuring widths in the micrometer range and thicknesses of a few tens of nanometers. A focused ion beam has been used to carve microscatterers into gold SPW's and the near-field distributions around these microstructures are observed by means of photon scanning tunneling microscopy (PSTM). On the basis of near-field images, we show that a finite length periodic arrangement of narrow slits can reflect a surface plasmon mode propagating along a SPW. The reflection efficiency of the micrograting is found to depend upon the number of slits, the period of the grating, and the incident wavelength. The optimum reflection …
Are AuPdTM (T = Sc, Y and M = Al, Ga, In), Heusler Compounds Superconductors without Inversion Symmetry?
2019
Heusler compounds with 2:1:1 stoichiometry either have a centrosymmetric Cu 2 MnAl structure or an Li 2 AgSb structure without a centre of inversion. The centrosymmetry is always lost in quaternary Heusler compounds with 1:1:1:1 stoichiometry and LiMgPdSn structure. This presents the possibility of realizing non-centrosymmetric superconductors in the family of Heusler compounds. The objective of this study is to search for and investigate such quaternary derivatives of Heusler compounds, particularly with respect to superconductivity. Several compounds were identified by carrying out calculations from first principles and superconductivity was observed in experiments conducted on AuPdScAl a…
The fingerprint of Te-rich and stoichiometric Bi2Te3 nanowires by Raman spectroscopy
2016
We unambiguously show that the signature of Te-rich bismuth telluride is the appearance of three new peaks in the Raman spectra of Bi2Te3, located at 88, 117 and 137 cm−1 . For this purpose, we have grown stoichiometric Bi2Te3 nanowires as well as Te-rich nanowires. The absence of these peaks in stoichiometric nanowires, even in those with the smallest diameter, shows that they are not related to confinement effects or the lack of inversion symmetry, as stated in the literature, but to the existence of Te clusters. These Te clusters have been found in nonstoichiometric samples by high resolution electron microscopy, while they are absent in stoichiometric samples. The Raman spectra of the l…
Effect of hydroxyapatite concentration and size on morpho-mechanical properties of PLA-based randomly oriented and aligned electrospun nanofibrous ma…
2019
The growing demand for nanofibrous biocomposites able to provide peculiar properties requires systematic investigations of processing-structure-property relationships. Understanding the morpho-mechanical properties of an electrospun scaffold as a function of the filler features and mat microstructure can aid in designing these systems. In this work, the reinforcing effect of micrometric and nanometric hydroxyapatite particles in polylactic acid-based electrospun scaffold presenting random and aligned fibers orientation, was evaluated. The particles incorporation was investigated trough Fourier transform infrared spectroscopy in attenuated total reflectance. The morphology of the nanofibers …
Thermodesorption of LB-multilayers of metal stearates
1991
Thermodesorption of stearate multilayers containing different metal ions was investigated by Interference-enhanced Reflection (IeR) and Nomarsky microscopy. Heating of samples in air leads to desorption of stearyl chains and to formation of metal oxide clusters. A new approach to build controlled structures was made by preparing a surface with neighbouring hydrophobic and hydrophilic areas. It is shown that arranging inorganic particles in a predetermined way is possible.
Influence of Polyvinyl Alcohol (PVA) on PVA-Poly-N-hydroxyethyl-aspartamide (PVA-PHEA) Microcrystalline Solid Dispersion Films
2020
AbstractThis study was conducted to formulate buccal films consisting of polyvinyl alcohol (PVA) and poly-N-hydroxyethyl-aspartamide (PHEA), to improve the dissolution of the drug through the oral mucosa. Ibuprofen sodium salt was used as a model drug, and the buccal film was expected to enhance its dissolution rate. Two different concentrations of PVA (5% w/v and 7.5% w/v) were used. Solvent casting was used to prepare films, where a solution consisting of drug and polymer was cast and allowed to dry. Attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were used to investigate the pr…
Quality Control of Agrochemical Formulations by Diffuse Reflectance near Infrared Spectrometry
2008
A near infrared (NIR)-based methodology has been developed for the determination of 11 pesticides in commercially available formulations. This solvent free, fast and environmentally friendly method was based on the direct measurement of the diffuse reflectance spectra of solid samples, a hierarchical cluster classification and the use of multivariate calibration models to determine each considered active principle in agrochemicals. The proposed partial least squares (PLS) models used for quantification of each compound were built from specific calibration sets composed of nine spectra corresponding to triplicate measurements of a single well characterised commercial sample and two addition…
k-resolved electronic properties of ternary heavy fermion systems
1998
Total-scattering pair-distribution function of organic material from powder electron diffraction data.
2014
AbstractThis paper shows that pair-distribution function (PDF) analyses can be carried out on organic and organometallic compounds from powder electron diffraction data. Different experimental setups are demonstrated, including selected area electron diffraction and nanodiffraction in transmission electron microscopy or nanodiffraction in scanning transmission electron microscopy modes. The methods were demonstrated on organometallic complexes (chlorinated and unchlorinated copper phthalocyanine) and on purely organic compounds (quinacridone). The PDF curves from powder electron diffraction data, called ePDF, are in good agreement with PDF curves determined from X-ray powder data demonstrat…
Structure characterization of hard materials by precession electron diffraction and automatic diffraction tomography: 6H-SiC semiconductor and Ni1+xT…
2012
Using a combination of automated diffraction tomography and precession electron diffraction techniques, quasi-kinematical electron diffraction data sets were collected from intermetallic Ni1+xTe1 embedded nanodomains and ion-thinned specimens of 6H–SiC semiconductor. Cell parameters and space groups were found automatically from the reconstructed 3D diffraction volume. The extracted intensities were used for fast ab initio structure determination by direct methods.