Search results for "SCAVENGERS"

showing 10 items of 85 documents

The contribution of hydrogen peroxide to the radiosensitizing effect of gold nanoparticles

2019

Abstract Plasmid DNA in aerated aqueous solution is used as a probe to determine whose of the reactive oxygen species (ROS) generated after absorption of ultra-soft X-rays (USX) take part in biomolecule damage in the presence and in absence of Gold Nano-Particles (GNP) and specific scavengers. Citrate-coated GNPs with core sizes of 6, 10 and 25 nm are synthetized and characterized, especially in terms of plasmon band shift, ζ-potential and hydrodynamic radii (respectively 9, 21 and 30 nm). We confirm the radiosensitizing effect of GNP and show that the SSB number per plasmid increases when, for a same mass of gold element, the core size of the gold nanoparticles decreases. Hydroxyl radicals…

Radiation-Sensitizing AgentsFormatesRadicalMetal Nanoparticles02 engineering and technologyPhotochemistry01 natural sciencesCitric AcidMetalchemistry.chemical_compoundColloid and Surface ChemistryPyruvic Acid0103 physical sciences[CHIM]Chemical SciencesMoleculeDimethyl SulfoxideDNA Breaks Single-StrandedParticle SizeTromethaminePhysical and Theoretical ChemistryHydrogen peroxideComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationReactive oxygen speciesQuenching (fluorescence)Aqueous solution010304 chemical physicsHydroxyl RadicalX-RaysFree Radical ScavengersHydrogen PeroxideSurfaces and InterfacesGeneral Medicine021001 nanoscience & nanotechnologySolutionschemistryColloidal goldvisual_artvisual_art.visual_art_mediumGold0210 nano-technologyPlasmidsBiotechnologyColloids and Surfaces B: Biointerfaces
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Free radical scavenging abilities of flavonoids as mechanism of protection against mutagenicity induced by tert-butyl hydroperoxide or cumene hydrope…

2003

Mutagenicity induced by tert-butyl hydroperoxide (BHP) or cumene hydroperoxide (CHP) in Salmonella typhimurium TA102 was effectively reduced by flavonols with 3',4'-hydroxyl groups such as fisetin, quercetin, rutin, isoquercitrin, hyperoxide, myricetin, myricitrin, robinetin, and to a lesser extent also by morin and kaempferol (ID50=0.25-1.05 micromol per plate). With the exception of isorhamnetin, rhamnetin, morin, and kaempferol, closely similar results were obtained with both peroxides. Hydrogenation of the double bond between carbons 2 and 3 (dihydroquercetin, dihydrorobinetin) as well as the additional elimination of the carbonyl function at carbon 4 (catechins) resulted in a loss of a…

Salmonella typhimuriumFree RadicalsHealth Toxicology and MutagenesisMedicinal chemistrychemistry.chemical_compoundFlavonolstert-ButylhydroperoxideBenzene DerivativesGeneticsButylated hydroxytolueneIsorhamnetinFlavonoidschemistry.chemical_classificationDose-Response Relationship DrugDeferoxamine mesylateHydroxyl RadicalMutagenicity TestsAntimutagenic AgentsFree Radical ScavengersHydrogen PeroxideOxidantsBiochemistrychemistryCumene hydroperoxidetert-Butyl hydroperoxideMyricetinQuercetinMutation Research/Genetic Toxicology and Environmental Mutagenesis
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Differential effects of cysteine and methionine residues in the antioxidant activity of human serum albumin

2005

Antioxidant properties of human serum albumin (HSA) may explain part of its beneficial role in various diseases related to free radical attack. In the present study, the antioxidant role of Cys and Met was studied by copper-mediated oxidation of human low density lipoproteins and by free radical-induced blood hemolysis which essentially assessed metal-chelating and free radical scavenging activities, respectively. Mild conditions were set up to specifically modify Cys and Met residues by N-ethylmaleimide (NEM) and chloramine T treatments, respectively. We found that Met and Cys accounted for 40-80% of total antioxidant activity of HSA. Copper binding to HSA was decreased by about 50% with c…

Time FactorsAntioxidantFree Radicalsmedicine.medical_treatmentDithionitrobenzoic AcidHemolysisBiochemistryAntioxidantsTosyl Compoundschemistry.chemical_compoundMethioninemedicineHumansChelationCysteineSerum AlbuminMethionineDose-Response Relationship DrugChloraminesFree Radical ScavengersGeneral MedicineFree radical scavengerHuman serum albuminmedicine.diseaseHemolysisLipoproteins LDLOxygenOxidative StresschemistryBiochemistryEthylmaleimideChloramine-TOxidation-ReductionCopperPhenanthrolinesProtein Bindingmedicine.drugCysteineFree Radical Research
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Respiratory syncytial virus inhibits ciliagenesis in differentiated normal human bronchial epithelial cells: effectiveness of N-acetylcysteine.

2012

Persistent respiratory syncytial virus (RSV) infections have been associated with the exacerbation of chronic inflammatory diseases, including chronic obstructive pulmonary disease (COPD). This virus infects the respiratory epithelium, leading to chronic inflammation, and induces the release of mucins and the loss of cilia activity, two factors that determine mucus clearance and the increase in sputum volume. These alterations involve reactive oxygen species-dependent mechanisms. The antioxidant N-acetylcysteine (NAC) has proven useful in the management of COPD, reducing symptoms, exacerbations, and accelerated lung function decline. NAC inhibits RSV infection and mucin release in human A54…

Viral DiseasesPulmonologyChronic Obstructive Pulmonary Diseaseslcsh:MedicineMucin 5ACVirus ReplicationAcetylcysteinePulmonary Disease Chronic ObstructiveTubulinRespiratory systemlcsh:ScienceCells CulturedMultidisciplinaryInterleukin-13Microscopy VideoCell DifferentiationForkhead Transcription FactorsFree Radical Scavengersrespiratory systemHost-Pathogen InteractionLower Respiratory Tract InfectionsInfectious Diseasesmedicine.anatomical_structureInterleukin 13Medicinemedicine.symptomResearch Articlemedicine.drugDrugs and DevicesInflammationBronchiRespiratory Syncytial Virus InfectionsBiologyMicrobiologyAntiviral AgentsUpper Respiratory Tract InfectionsmedicineHumansCiliaBiologyInflammationRespiratory Syncytial Virus InfectionA549 cellMucinlcsh:RImmunityEpithelial CellsAxonemal DyneinsEpitheliumAcetylcysteineGene Expression RegulationRespiratory Syncytial Virus HumanRespiratory InfectionsImmunologyRespiratory epitheliumlcsh:QPLoS ONE
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N-3 fatty acids modulate antioxidant status in diabetic rats and their macrosomic offspring.

2006

We investigated the role of dietary n-3 polyunsaturated fatty acids (n-3 PUFA) in the modulation of total antioxidant status in streptozotocin (STZ)-induced diabetic rats and their macrosomic offspring. Female wistar rats, fed on control diet or n-3 PUFA diet, were rendered diabetic by administration of five mild doses of STZ on day 5 and were killed on days 12 and 21 of gestation. The macrosomic (MAC) pups were killed at the age of 60 and 90 days. Lipid peroxidation was measured as the concentrations of plasma thiobarbituric acid reactive substances (TBARS), and the total antioxidant status was determined by measuring (i) plasma oxygen radical absorbance capacity (ORAC), (ii) plasma vitami…

Vitaminmedicine.medical_specialtyAntioxidantErythrocytesOxygen radical absorbance capacityEndocrinology Diabetes and Metabolismmedicine.medical_treatmentPregnancy in DiabeticsMedicine (miscellaneous)Ascorbic AcidThiobarbituric Acid Reactive SubstancesAntioxidantsDiabetes Mellitus ExperimentalFetal MacrosomiaLipid peroxidationchemistry.chemical_compoundPregnancyInternal medicineFatty Acids Omega-3TBARSmedicineDiabetes MellitusAnimalsVitamin ERats WistarVitamin Achemistry.chemical_classificationGlutathione PeroxidaseNutrition and DieteticsVitamin CTriglycerideChemistrySuperoxide DismutaseFatty AcidsFree Radical ScavengersLipidsRatsEndocrinologyAnimals NewbornDiabetes Mellitus Type 2FemaleLipid PeroxidationBiomarkersPolyunsaturated fatty acidInternational journal of obesity (2005)
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Tunisian tomato by-products, as a potential source of natural bioactive compounds.

2016

Consumption of tomato and tomato products is positively related to the reduction in cardiovascular disease and several types of cancer, thanks to the presence of natural compounds, such as antioxidants. Peels and seeds fractions of tomato, collected after industrial processing in Tunisian industries, were analysed for nutritional and antioxidants composition in perspective of its utilisation. Proximate composition, fatty acids profile, carotenoids, such as lycopene and beta-carotene, polyphenols contents, demonstrated the good potential of these residual products as a source of natural compounds, useful for food and nutraceuticals applications.

antioxidantTunisiaFood Handling020209 energy02 engineering and technologyPlant ScienceBiochemistryAntioxidantsAnalytical Chemistrychemistry.chemical_compound0404 agricultural biotechnologyNutraceuticalLycopeneSolanum lycopersicumPicratesSettore BIO/10 - BiochimicaBotany0202 electrical engineering electronic engineering information engineeringFood IndustryPotential sourceFood scienceCarotenoidchemistry.chemical_classificationBiological ProductsMedicine (all)Organic ChemistryBiphenyl CompoundsFatty Acidsfood and beveragesPolyphenolsSettore AGR/15 - Scienze E Tecnologie Alimentari04 agricultural and veterinary sciencesFree Radical ScavengersTomato productsProximate composition040401 food scienceCarotenoidscarotenoidLycopenepolyphenolchemistryPolyphenolFruitSeedsComposition (visual arts)fatty acidNatural product research
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Investigations Concerning the Correlation of COX-1 Inhibitory and Hydroxyl Radical Scavenging Activity

2008

The aim was to study the COX-1 inhibiting efficacy in context with hydroxyl radical scavenging properties of compounds bearing a carboxylic acid and ester function, respectively. In general, the acids are more potent radical scavengers than the corresponding esters but there is no clear correlation with their COX-1 inhibiting potencies. A feasible scavenging mechanism of carboxylic acids is discussed.

chemistry.chemical_classificationHydroxyl RadicalRadicalCarboxylic acidPharmaceutical ScienceContext (language use)Free Radical ScavengersInhibitory postsynaptic potentialStructure-Activity Relationshipchemistry.chemical_compoundchemistryDrug DiscoveryCyclooxygenase 1AnimalsOrganic chemistryCattleCyclooxygenase InhibitorsHydroxyl radicalScavengingArchiv der Pharmazie
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Contact probe voltammetry for in situ monitoring of the reactivity of phenolic tomato (Solanum lycopersicum L.) compounds with ROS

2015

The application of an in situ electrochemical contact probe methodology for monitoring reactivity of antioxidant polyphenolic compounds in tomato fruits is described. Upon electrochemical generation of reactive oxygen species (ROS), characteristic voltammetric responses were recorded for compounds resulting from the reaction of such species with tomato compounds. This suggests that new electrochemically oxidizable compounds are generated from the oxidation of highly reactive polyphenolic compounds with ROS. Therefore, an evaluation of the antioxidant capacity of such species could be made from voltammetric data for different tomato varieties.

chemistry.chemical_classificationReactive oxygen speciesAntioxidantbiologyPlant ExtractsChemistrymedicine.medical_treatmentfood and beveragesFree Radical Scavengersbiology.organism_classificationElectrochemistryAnalytical Chemistrychemistry.chemical_compoundSolanum lycopersicumPhenolsPolyphenolFruitElectrochemistrymedicineOrganic chemistryReactivity (chemistry)PhenolsSolanumReactive Oxygen SpeciesVoltammetryTalanta
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N-acetylcysteine protects against age-related increase in oxidized proteins in mouse synaptic mitochondria.

1997

Since it has been proposed that oxidized protein accumulation plays a critical role in brain aging, we have investigated the effect of a thiolic antioxidant on protein carbonyl content in synaptic mitochondria from female OF-1 mice. At 48 weeks of age, a control group was fed standard food pellets and another group received pellets containing 0.3% (w/w) of N-acetylcysteine. A 24-week treatment resulted in a significant decrease in protein carbonyl content in synaptic mitochondria of the N-acetylcysteine-treated animals as compared to age-matched controls.

medicine.medical_specialtyAgingAntioxidantmedicine.medical_treatmentProtein Carbonyl ContentMice Inbred StrainsMitochondrionBiologyAcetylcysteinechemistry.chemical_compoundMiceInternal medicineAge relatedmedicineAnimalsSulfhydryl CompoundsMolecular BiologyBrain agingchemistry.chemical_classificationNeuronsGeneral NeuroscienceGlutathioneFree Radical ScavengersGlutathioneAcetylcysteineMitochondriaEndocrinologychemistryBiochemistrySynapsesThiolFemaleNeurology (clinical)Oxidation-ReductionDevelopmental Biologymedicine.drugBrain research
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Oxidative tissue damage after phacoemulsification: influence of ophthalmic viscosurgical devices.

2003

To quantify the oxidative tissue damage after phacoemulsification, correlate the damage to the energy applied, and investigate the influence of ophthalmic viscosurgical devices (OVDs).Department of Ophthalmology, University of Mainz, Mainz, Germany.The study comprised 130 eyes operated on by 1 surgeon using the same phacoemulsification machine. Some eyes received an OVD before phacoemulsification and some did not. Energy values were expressed as phaco time; that is, ultrasound (US) time (seconds) after conversion to 100% phaco power. Patients were grouped as follows: Group 1, phaco time less than 20 seconds and no OVD; Group 2, phaco time 20 to 40 seconds and no OVD; Group 3, phaco time mor…

medicine.medical_specialtyLipid Peroxidesgenetic structuresFree Radicalsmedicine.medical_treatmentSodium hyaluronateAqueous humorLactoseMethylcelluloseThiobarbituric Acid Reactive SubstancesAqueous Humorchemistry.chemical_compoundPostoperative ComplicationsOphthalmologyTissue damageOxazinesMedicineHumansHyaluronic AcidAgedPhacoemulsificationbusiness.industryUltrasoundPhacoemulsificationFree Radical ScavengersSensory SystemsOphthalmologyOxidative StresschemistrySurgeryLipid PeroxidationbusinessJournal of cataract and refractive surgery
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