Search results for "SEP"
showing 10 items of 2642 documents
Reverse electrodialysis with saline waters and concentrated brines: A laboratory investigation towards technology scale-up
2015
Abstract The use of concentrated brines and brackish water as feed solutions in reverse electrodialysis represents a valuable alternative to the use of river/sea water, allowing the enhancement of power output through the increase of driving force and reduction of internal stack resistance. Apart from a number of theoretical works, very few experimental investigations have been performed so far to explore this possibility. In the present work, two RED units of different size were tested using artificial saline solutions. The effects of feed concentration, temperature and flowrate on process performance parameters were analysed, adopting two different sets of membranes. These experiments all…
Analysis of Operational Parameters in Acid and Base Production Using an Electrodialysis with Bipolar Membranes Pilot Plant
2023
In agreement with the Water Framework Directive, Circular Economy and European Union (EU) Green Deal packages, the EU-funded WATER-MINING project aims to validate next-generation water resource solutions at the pre-commercial demonstration scale in order to provide water management and recovery of valuable materials from alternative sources. In the framework of the WATER-MINING project, desalination brines from the Lampedusa (Italy) seawater reverse osmosis (SWRO) plant will be used to produce freshwater and recover valuable salts by integrating different technologies. In particular, electrodialysis with bipolar membranes (EDBM) will be used to produce chemicals (NaOH and HCl). A novel EDBM…
Electromembrane Processes: Experiments and Modelling
2021
This Special Issue of Membranes journal focuses on electromembrane processes and is motivated by the increasing interest of the scientific community towards their characterization by experiments and modelling for several applications [...]
A Thermochromic Liquid Crystals Image Analysis technique to investigate temperature polarization in spacer-filled channels for Membrane Distillation
2013
The analysis of flow fields and temperature distributions is of paramount importance in the development and optimization of new spacer-filled channel geometries for Membrane Distillation modules. The literature reports only few studies on the experimental characterization of such channels and, to the authors’ knowledge, none of them presents local information concerning the temperature distribution on the membrane surface. In the present work, a non-intrusive experimental technique named TLC-IA-TP is presented: it is based on the use of Thermochromic Liquid Crystals (TLCs) and digital Image Analysis (IA) and it is applied here for the first time to the analysis of Temperature Polarization (…
Diffusion Dialysis for Separation of Hydrochloric Acid, Iron and Zinc Ions from Highly Concentrated Pickling Solutions
2020
Acid recovery from pickling waste solutions is an important step to enhance hot-dip-galvanizing industry process sustainability. Diffusion dialysis (DD) can be used to separate acids and heavy metals (e.g., iron and zinc) from pickling waters, promoting the circular use of such raw materials. In the present study, a laboratory scale unit operating in batch and a continuous large scale unit, both equipped with Fumasep anionic exchange membranes, were tested. Results obtained show that zinc and iron concentration affect the HCl recovery in opposite ways. Iron chlorides enhance acid recovery, while zinc chlorides considerably tend to diffuse through the membrane because of negatively charged c…
The acid–base flow battery : Sustainable energy storage via reversible water dissociation with bipolar membranes
2020
The increasing share of renewables in electric grids nowadays causes a growing daily and seasonal mismatch between electricity generation and demand. In this regard, novel energy storage systems need to be developed, to allow large-scale storage of the excess electricity during low-demand time, and its distribution during peak demand time. Acid–base flow battery (ABFB) is a novel and environmentally friendly technology based on the reversible water dissociation by bipolar membranes, and it stores electricity in the form of chemical energy in acid and base solutions. The technology has already been demonstrated at the laboratory scale, and the experimental testing of the first 1 kW pilot pla…
Performance of the first reverse electrodialysis pilot plant for power production from saline waters and concentrated brines
2016
Abstract This work reports experimental data collected for the first time on a full-scale RED pilot plant operated with natural streams in a real environment. The plant – located in the South of Italy – represents the final accomplishment of the REAPower project ( www.reapower.eu ). A RED unit equipped with almost 50 m2 of IEMs (125 cell pairs, 44x44 cm2) was tested, using both artificial and natural feed solutions, these latter corresponding to brackish water (≈0.03 M NaClequivalent) and saturated brine (4–5 M NaClequivalent). A power output up to around 40 W (i.e. 1.6 W/m2 of cell pair) was reached using natural solutions, while an increase of 60% was observed when testing the system with…
Towards 1 kW power production in a reverse electrodialysis pilot plant with saline waters and concentrated brines
2017
Abstract Reverse electrodialysis (RED) is a promising technology to extract energy from salinity gradients, especially in the areas where concentrated brine and saline waters are available as feed streams. A first pilot-scale plant was recently built in Trapani (Italy), and tested with real brackish water and brine from saltworks. The present work focuses on the scale-up of the pilot plant, reaching more than 400 m 2 of total membrane area installed and representing the largest operating RED plant so far reported in the literature. With a nominal power capacity of 1 kW, the pilot plant reached almost 700 W of power capacity using artificial brine and brackish water, while a 50% decrease in …
CFD Investigation of Spacer-Filled Channels for Membrane Distillation
2019
The membrane distillation (MD) process for water desalination is affected by temperature polarization, which reduces the driving force and the efficiency of the process. To counteract this phenomenon, spacer-filled channels are used, which enhance mixing and heat transfer but also cause higher pressure drops. Therefore, in the design of MD modules, the choice of the spacer is crucial for process efficiency. In the present work, different overlapped spacers are investigated by computational fluid dynamics (CFD) and results are compared with experiments carried out with thermochromic liquid crystals (TLC). Results are reported for different flow attack angles and for Reynolds numbers (Re) ran…
Polyactide Biodegradable Scaffolds for Tissue Engineering Applications: Phase Separation-Based Techniques
2011
One of the most reliable techniques for the preparation of biodegradable scaffolds suitable for tissue engineering applications (e.g. regeneration of wounded/damaged tissues) is based on liquid/liquid phase separation of ternary solvent/antisolvent/polymer solutions. In particular, two phase separation protocols are examined here: Thermally Induced Phase Separation (TIPS) and Diffusion Induces Phase Separation (DIPS). According to the former protocol, a thermodynamically stable polymeric ternary solution is brought below its metastability/instability point (spinodal/binodal curve) by quench in a cooling medium: under opportune conditions, a foam-like structure is formed by nucleation and 3-…