Search results for "SEPARATION"

showing 10 items of 865 documents

Application of gas separation membranes to detritiation systems

2002

The use of gas separation membranes in tritium removal systems has been studied to develop a new detritiation process. The main advantage of this new process is to reduce the number and/or the size of equipments in comparison to conventional detritiation systems. The objective of this study is to choose the best suited membrane for this application. The hydrogen or its isotopes recovery performance of several commercial hollow fiber organic membranes has been analyzed thanks to three devices. Experiments are performed with small quantities of hydrogen gas or deuterium gas or tritium gas in the range representative of the radioactive contamination level in tritium handling gloveboxes. A math…

HydrogenGeneral Chemical Engineeringchemistry.chemical_element02 engineering and technology[SPI.MAT] Engineering Sciences [physics]/Materials01 natural sciences7. Clean energy010305 fluids & plasmasIsotope separationlaw.inventionMembrane technology[SPI.MAT]Engineering Sciences [physics]/Materialslaw0103 physical sciencesGeneral Materials ScienceGas separationProcess engineeringComputingMilieux_MISCELLANEOUSWater Science and TechnologyTritium illuminationChromatographybusiness.industryChemistryMechanical EngineeringGeneral Chemistry021001 nanoscience & nanotechnologyMembraneDeuterium13. Climate actionScientific method0210 nano-technologybusiness
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The operating cost of an anaerobic membrane bioreactor (AnMBR) treating sulphate-rich urban wastewater

2014

The objective of this study was to evaluate the operating cost of an anaerobic membrane bioreactor (AnMBR) treating sulphate-rich urban wastewater (UWW) at ambient temperature (ranging from 17 to 33 degrees C). To this aim, energy consumption, methane production, and sludge handling and recycling to land were evaluated. The results revealed that optimising specific gas demand with respect to permeate volume (SGDp) and sludge retention time (for given ambient temperature conditions) is essential to maximise energy savings (minimum energy demand: 0.07 kW h m(-3)). Moreover, low/moderate sludge productions were obtained (minimum value: 0.16 kg TSS kg(-1) CODRemoved), which further enhanced the…

INGENIERIA HIDRAULICAEnergy demandIndustrial-scale hollow-fibre membranesOperating costTreated waterAnaerobic membrane bioreactor (AnMBR)Environmental engineeringFiltration and SeparationAnaerobic membrane bioreactorEnergy consumptionMethaneAnalytical ChemistryEnergy consumptionchemistry.chemical_compoundWastewaterVolume (thermodynamics)chemistryEnvironmental scienceSulphate-rich urban wastewaterOperating costTECNOLOGIA DEL MEDIO AMBIENTE
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Model-based automatic tuning of a filtration control system for submerged anaerobic membrane bioreactors (AnMBR)

2014

This paper describes a model-based method to optimise filtration in submerged AnMBRs. The method is applied to an advanced knowledge-based control system and considers three statistical methods: (1) sensitivity analysis (Morris screening method) to identify an input subset for the advanced controller; (2) Monte Carlo method (trajectory-based random sampling) to find suitable initial values for the control inputs; and (3) optimisation algorithm (performing as a supervisory controller) to re-calibrate these control inputs in order to minimise plant operating costs. The model-based supervisory controller proposed allowed filtration to be optimised with low computational demands (about 5min). E…

INGENIERIA HIDRAULICAEngineeringMonte Carlo methodFiltration and SeparationBiochemistrylaw.inventionControl theorylawGeneral Materials ScienceSensitivity (control systems)Physical and Theoretical ChemistryControl systemProcess engineeringTECNOLOGIA DEL MEDIO AMBIENTESpargingFiltrationOperating costDowntimebusiness.industryModel-based automatic tuningControl engineeringControl systembusinessSubmerged anaerobic membrane bioreactorsModel filtrationJournal of Membrane Science
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A filtration model applied to submerged anaerobic MBRs (SAnMBRs)

2013

The aim of this study was to develop a model able to correctly reproduce the filtration process of submerged anaerobic MBRs (SAnMBRs). The proposed model was calibrated and validated in a SAnMBR demonstration plant fitted with industrial-scale hollow-fibre membranes. Three suspended components were contemplated in the model: total solids concentration; dry mass of cake on the membrane surface; and dry mass of irreversible fouling on the membrane surface. The model addressed the following physical processes: the build-up and compression of the cake layer during filtration; cake layer removal using biogas sparging to scour the membrane; cake layer removal during back-flushing; and the consoli…

INGENIERIA HIDRAULICAIndustrial-scale hollow-fibre membranesFiltration modelFoulingChemistryEnvironmental engineeringFiltration and SeparationTotal dissolved solidsPulp and paper industryBiochemistryResistance-in-series-basedMembraneBiogasSubmerged anaerobic MBRGeneral Materials ScienceLayer removalPhysical and Theoretical ChemistryMembrane surfaceAnaerobic exerciseSpargingTECNOLOGIA DEL MEDIO AMBIENTE
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Advanced control system for optimal filtration in submerged anaerobic MBRs (SAnMBRs)

2013

The main aim of this study was to develop an advanced controller to optimise filtration in submerged anaerobic MBRs (SAnMBRs). The proposed controller was developed, calibrated and validated in a SAnMBR demonstration plant fitted with industrial-scale hollow-fibre membranes with variable influent flow and load. This 2-layer control system is designed for membranes operating sub-critically and features a lower layer (on/off and PID controllers) and an upper layer (knowledge-based controller). The upper layer consists of a MIMO (multiple-input-multiple-output) control structure that regulates the gas sparging for membrane scouring and the frequency of physical cleaning (ventilation and back f…

INGENIERIA HIDRAULICAIndustrial-scale hollow-fibre membranesFoulingKnowledge-based controllerEnvironmental engineeringPID controllerFiltration and SeparationEnergy savingsBiochemistrylaw.inventionAdvanced control systemMembraneControl theorylawControl systemSubmerged anaerobic MBRVentilation (architecture)Environmental scienceGeneral Materials SciencePhysical and Theoretical ChemistrySpargingFiltrationTECNOLOGIA DEL MEDIO AMBIENTE
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Multi‐residue extraction to determine organic pollutants in mussel hemolymph

2021

This study assesses the extraction of eleven pharmaceuticals, five pesticides, five perfluoroalkyl substances, and two illicit drugs in hemolymph from (Mytilus Galloprovincialis). Four extraction procedures using Phree™ Phospholipid Removal cartridges were tested using different volumes of methanol (400 and 600 μL) and acetonitrile (300 and 450 μL). The pollutants were determined by high-performance liquid chromatography–tandem mass spectrometry. The use of methanol gave several problems during the extraction procedure, such as longer times and sample loss. Three methods (acetonitrile 300 and 450 μL; and methanol 600 μL) were validated. Recoveries at three concentration levels (5, 50, and 1…

Illicit drugsFiltration and Separation010501 environmental sciencesMass spectrometry01 natural sciencesAnalytical Chemistrychemistry.chemical_compoundHemolymphHemolymphAnimalsSolid phase extractionPesticidesAcetonitrile0105 earth and related environmental sciencesDetection limitSolid-phase extractionFluorocarbonsChromatographyIllicit Drugs010401 analytical chemistryExtraction (chemistry)Pesticide0104 chemical sciencesPerfluoroalkyl substanceschemistryPharmaceuticalsEnvironmental PollutantsMethanolJournal of Separation Science
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Combination of advanced oxidation processes and active carbons adsorption for the treatment of simulated saline wastewater

2016

Abstract In the present work, an integrated process combining three different technologies, i.e. heterogeneous photocatalysis, homogeneous ozonation and adsorption on granular activated carbon (GAC) was used for the treatment of a synthetic solution simulating saline wastewater. The synergistic effects between the different methods enhance the oxidation rate of the organic compounds in the integrated process, so that its use may result sustainable. It has been found that a relatively low oxidation rate is sufficient to obtain the highest synergy between the three technologies and to maximize the performances. In particular, coupling ozonation and photocatalysis resulted in 20% enhancement i…

ImaginationChemical substancemedia_common.quotation_subjectFiltration and Separation02 engineering and technology010501 environmental sciences01 natural sciencesAnalytical Chemistrylaw.inventionAdvanced oxidation processes Active carbon adsorption Ozonation Photocatalysis Saline wastewaterReaction rateAdsorptionMagazinelawSettore CHIM/01 - Chimica Analitica0105 earth and related environmental sciencesmedia_commonSettore ING-IND/24 - Principi Di Ingegneria ChimicaChemistryEnvironmental engineering021001 nanoscience & nanotechnologyWastewaterChemical engineeringPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyScience technology and societySeparation and Purification Technology
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A central role for Notch in effector CD8(+) T cell differentiation.

2014

Activated CD8(+) T cells choose between terminal effector cell (TEC) or memory precursor cell (MPC) fates. We found that the signaling receptor Notch controls this 'choice'. Notch promoted the differentiation of immediately protective TECs and was correspondingly required for the clearance of acute infection with influenza virus. Notch activated a major portion of the TEC-specific gene-expression program and suppressed the MPC-specific program. Expression of Notch was induced on naive CD8(+) T cells by inflammatory mediators and interleukin 2 (IL-2) via pathways dependent on the metabolic checkpoint kinase mTOR and the transcription factor T-bet. These pathways were subsequently amplified d…

ImmunologyNotch signaling pathwayMice TransgenicCell SeparationBiologyAdaptive ImmunityCD8-Positive T-LymphocytesEffector cellLymphocyte ActivationReal-Time Polymerase Chain ReactionArticlememoryMiceOrthomyxoviridae InfectionsCell surface receptorT-Lymphocyte SubsetsTransduction GeneticPrecursor cellImmunology and AllergyCytotoxic T cellAnimalsGeneticsReceptors NotchEffectorCell DifferentiationFlow CytometryAdoptive TransferTEC3. Good healthCell biologyMice Inbred C57BLeffectorCD8 T cellMPCInfluenza A virusinflammationTranscriptomeCD8Nature immunology
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Benign, preinvasive and invasive ductal breast lesions. A comparative study with quantitative techniques: morphometry, image- and flow cytometry.

1999

The histological distinction between ductal hyperplasia of the breast, atypical ductal hyperplasia and ductal carcinoma in situ is difficult and subjective. To gain a better understanding of these lesions, we performed a comparative study comprising 20 cases of ductal hyperplasia without atypia, 20 cases of ductal hyperplasia with atypia, and 30 cases of ductal carcinoma in situ (well-, moderately- and poorly-differentiated), using quantitative techniques: image cytometry analysis, morphometry and DNA analysis, and DNA flow cytometry. Our results confirm that the mean nuclear area and volume progressively decreased from ductal carcinoma in situ to ductal hyperplasia without atypia. The diff…

In situPathologymedicine.medical_specialtyBreast NeoplasmsCell SeparationPathology and Forensic MedicineFlow cytometryAtypiaImage Processing Computer-AssistedMedicineHumansDuctal Hyperplasiaskin and connective tissue diseasesneoplasmsDNA Image CytometryImage CytometryCell NucleusPloidiesintegumentary systemmedicine.diagnostic_testbusiness.industryCarcinoma Ductal BreastCell BiologyDNA NeoplasmDuctal carcinomaHyperplasiamedicine.diseaseFlow Cytometrybody regionsImage CytometryFemalebusinessPrecancerous ConditionsCarcinoma in SituPathology, research and practice
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Screening of oxazepine indole enantiomers by means of high performance liquid chromatography with imprinted polymer stationary phase.

2004

Chromatographic enantiomer separations of different oxazepine indole derivatives were performed using a molecularly imprinted polymer. A 5aR,12R,13S-trans-6,6-dimethyl-12,13-dihydro-6H-5a, 1 3-methanoindolo[2,1-b][1,3]naphthoxazepine-12-carboxamide enantiomerderivative was used as a template and the resultant polymer has shown enantiomer recognition for series of template related compounds. The mechanistic description of the chiral discrimination process is scrutinised, comparing the discrimination between the different conformations and substituents of the oxazepine indoles.

Indole testchemistry.chemical_classificationModels MolecularMolecularly imprinted polymerFiltration and SeparationStereoisomerismPolymerHigh-performance liquid chromatographyAnalytical Chemistrychemistry.chemical_compoundOxazepineschemistryStationary phaseOrganic chemistryOxazepineIndicators and ReagentsEnantiomerMolecular imprintingChromatography High Pressure LiquidJournal of separation science
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