Search results for "SILS"
showing 10 items of 241 documents
Synthesis, characterization and ethylene polymerization by metallasilsesquioxane
2013
Soluble complexes of group (IV) metallocenes anchored on a substituted polyhedral oligomeric silsesquioxane trisilanol support were prepared and characterized. These catalyst precursors formulated as [M(O^O^O)X] are found to be active in polymerization of ethylene at high temperature in combination with ethylaluminum sesquichloride (Et3Al2Cl3, EASC) as co-catalyst. The polyethylene obtained by these catalysts is linear, crystalline and displays narrow dispersity. The unique low molecular weight PE formed in this reaction exhibits properties comparable to commercial micronized PE waxes that have potential industrial applications in surface coating and ink formulations. Copyright © 2013 John …
Charles Darwin and the Origin of Life
2009
When Charles Darwin published The Origin of Species 150 years ago he consciously avoided discussing the origin of life. However, analysis of some other texts written by Darwin, and of the correspondence he exchanged with friends and colleagues demonstrates that he took for granted the possibility of a natural emergence of the first life forms. As shown by notes from the pages he excised from his private notebooks, as early as 1837 Darwin was convinced that “the intimate relation of Life with laws of chemical combination, & the universality of latter render spontaneous generation not improbable”. Like many of his contemporaries, Darwin rejected the idea that putrefaction of preexisting organ…
Decreasing Phanerozoic extinction intensity as a consequence of Earth surface oxygenation and metazoan ecophysiology
2021
The decline in background extinction rates of marine animals through geologic time is an established but unexplained feature of the Phanerozoic fossil record. There is also growing consensus that the ocean and atmosphere did not become oxygenated to near-modern levels until the mid-Paleozoic, coinciding with the onset of generally lower extinction rates. Physiological theory provides us with a possible causal link between these two observations-predicting that the synergistic impacts of oxygen and temperature on aerobic respiration would have made marine animals more vulnerable to ocean warming events during periods of limited surface oxygenation. Here, we evaluate the hypothesis that chang…
Zur Geschichte der nacheiszeitlichen Umwelt und der Kulturpflanzen im Land Brandenburg
2018
International audience; The results of pollenanalytical and archaeobotanical studies presented here show the development of veg-etation in the state of Brandenburg, which was characterized by the climate and the associated natural spread of plants as well as the use of the resource forest by man.The plant food of humans was first obtained by gathering and, since the beginning of permanent settle-ment in the Neolithic period, mainly by means of agriculture. The cultivation of plants continued over the millennia, with most archaeological cultures showing their typical inventory of crops. The dynamics of these developments require further research, as there are still many spatial and temporal …
Zinc isotopes in Late Pleistocene fossil teeth from a Southeast Asian cave setting preserve paleodietary information
2020
Significance Dietary habits, especially meat consumption, represent a key aspect in the behavior and evolution of fossil hominin species. Here, we explore zinc (Zn) isotope ratios in tooth enamel of fossil mammals. We show discrimination between different trophic levels and demonstrate that Zn isotopes could prove useful in paleodietary studies of fossil hominin, or other mammalian species, to assess their consumption of animal versus plant resources. We also demonstrate the high preservation potential of pristine diet-related Zn isotope ratios, even under tropical conditions with poor collagen preservation, such as the studied depositional context in Southeast Asia. However, assessing the …
La cuisine d’une maison de maître du Haut-Empire à Grand (Vosges)
2013
During excavations conducted in 2011 in Grand (Vosges), a domus dating from the 2nd century and the first half of the 3rd was uncovered. Among the well-preserved vestiges a kitchen was identified with its cooking installations still in situ. These consisted of a hearth, a raised cooking platform and an oven. The kitchen was probably in use for both the residential and the servant’s quarters of the domus. The sediments linked to the use of the kitchen yielded numerous organic remains and pottery sherds dating from the 3rd century. These finds document, at least partially, the kitchenware in use, diet and waste management practices in use in this household. The kitchen stands out as a place t…
A fossil sea urchin from the Celtic site Goincet in the Forez (Poncins, dép. Loire) and a perspective at the meaning of ovum anguinum
2014
Dieser Artikel behandelt die neue Entdeckung eines versteinerten Seeigels in einem archäologischen Fundkontext. Das Exemplar weist die notwendigen Charakteristika auf, um seine Art und seine vermutete Herkunft genauer bestimmen zu können. Der fossile Seeigel wurde wahrscheinlich aus einer Entfernung von mehreren Hundert Kilometern herbeigebracht. Es wird auch sein archäologischer Kontext untersucht, der sich im Bereich einer Straße in einer protourbanen Besiedlung befindet. Die archäologische Schicht mit dem Seeigel wird an das Ende des 1. Jahrhunderts v. Chr. datiert. Weiterhin wurde eine forschungsgeschichtliche Bilanz der Funde von versteinerten Seeigeln in ihrem vorkeltischen, keltische…
Integrated stratigraphy of the Oxfordian global stratotype section and point (GSSP) candidate in the Subalpine Basin (SE France).
2014
44 pages; International audience; An integrated biostratigraphic approach, based on ammonites, calcareous nannofossils, dinoflagellates, combined with sedimentology, carbon-isotope and physical stratigraphy, is proposed for the Subalpine Basin (Thuoux and Saint-Pierre d'Argençon sections). Within the expanded marl deposits of the Terres Noires Fm., the Callovian-Oxfordian boundary is particularly well defined by ammonite taxa from different families (i.e. Cardioceratidae, Oppeliidae, Aspidoceratidae and Perisphinctidae), calcareous nannoplankton (first occurrence of large-sized Stephanolithion bigotii) and dinoflagellate cysts (first occurrence of Wanaea fimbriata). This precise biostratigr…
POSS nanostructures in catalysis
2020
Polyhedral oligomeric silsesquioxanes (POSS) are organic-inorganic hybrid molecules piquing the interest of researchers thanks to their synergistic features. The great versatility of POSS nanostructures arises from the easy tunability of peripheral organic moieties combined with the high thermal and chemical stability of the inner inorganic core. In this review, we highlight the use of POSS nanostructures as molecular precursors for the synthesis of homogeneous and heterogeneous catalysts able to promote many processes including alkene epoxidation, C-C bond formation, CO2 conversion, "click reactions", hydrogenation, and ethylene polymerisation, among others. In this scenario, POSS units fo…
Synthesis of Defined Poly(silsesquioxane)s: Fast Polycondensation of Trialkoxysilanes in a Continuous-Flow Microreactor
2009
The polycondensation of trialkoxysilanes to PSSQs in a microreactor setup is demonstrated. While continuous-flow processes involving microreactors found various applications in chain growth polymerization, their influence on step-growth polymerization is less explored, and the polycondensation of multifunctional monomers has not been studied in detail. We found significantly increased yields and a decreased polydispersity of the obtained polymers in comparison to the batch process. By variation of the residence time molecular weights could be adjusted reproducibly ranging from M n =1900 to 11000 g · mol -1 . Thus, the microreactor setup offers for the first time the possibility to synthesiz…