Search results for "SITES"

Reinforcement Efficiency of Cellulose Microfibers for the Tensile Stiffness and Strength of Rigid Low-Density Polyurethane Foams

2020

Rigid low-density closed-cell polyurethane (PU) foams are widely used in both thermal insulation and structural applications. The sustainability of PU foam production can be increased by using bio-based components and fillers that ensure both enhanced mechanical properties and higher renewable material content. Such bio-based foams were produced using polyols derived from rapeseed oil and microcrystalline cellulose (MCC) fibers as filler. The effect of MCC fiber loading of up to 10 wt % on the morphology, tensile stiffness, and strength of foams has been evaluated. For estimation of the mechanical reinforcement efficiency of foams, a model allowing for the partial alignment of filler fibers…

Calorimetry: a Valuable Tool for Emerging Smart Nanomaterials

2012

It is well known that calorimetry is a powerful technique to determine the complete energetics (standard free energy, enthalpy and entropy) of interaction processes. We are now assisting to the increment of the use of nano-calorimetry, which appears rather versatile because it can evidence weak interactions quickly and accurately and, furthermore, needs very small amounts of material. Unfortunately, over the years the calorimetry has been applied to restricted fields so that it has been underemployed in studying smart nanomaterials (polypseudorotaxanes, polymeric aggregates, surface functionalized nanoparticles, nanocomposites, etc.) to which a tremendous scientific interest has been recent…

Influence of M23C6 carbides on the heterogeneous strain development in annealed 420 stainless steel

2020

Understanding the local strain enhancement and lattice distortion resulting from different microstructure features in metal alloys is crucial in many engineering processes. The development of heterogeneous strain not only plays an important role in the work hardening of the material but also in other processes such as recrystallization and damage inheritance and fracture. Isolating the contribution of precipitates to the development of heterogeneous strain can be challenging due to the presence of grain boundaries or other microstructure features that might cause ambiguous interpretation. In this work a statistical analysis of local strains measured by electron back scatter diffraction and …

Natural anti-oxidants immobilized onto carbon nanotubes for thermo-oxidation resistant polymer-based nanocomposites

2014

A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification

2017

International audience; A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.

Design, Synthesis and Biological Evaluation of Novel Pyrazolo[1,2,4]triazolopyrimidine Derivatives as Potential Anticancer Agents

2021

Three novel pyrazolo-[4,3-e][1,2,4]triazolopyrimidine derivatives (1, 2, and 3) were designed, synthesized, and evaluated for their in vitro biological activity. All three compounds exhibited different levels of cytotoxicity against cervical and breast cancer cell lines. However, compound 1 showed the best antiproliferative activity against all tested tumor cell lines, including HCC1937 and HeLa cells, which express high levels of wild-type epidermal growth factor receptor (EGFR). Western blot analyses demonstrated that compound 1 inhibited the activation of EGFR, protein kinase B (Akt), and extracellular signal-regulated kinase (Erk)1/2 in breast and cervical cancer cells at concentrations…

Phylogeny, epidemiology and microhabitat preferences of lungworms (Pseudaliidae) in cetaceans from teh Western Mediterranean

2023

A pesar de tener una cierta reputación negativa, los parásitos pueden ofrecer una información importante sobre sus hospedadores, habiendo sido reconocidos como herramientas valiosas en varios estudios que investigan el comportamiento (Balbuena y Raga 1991), la salud (Aznar et al. 2005; Gkafas et al. 2020), la dieta (Dailey y Otto 1982), la migración (Ten et al. 2022), la estructura social (Balbuena et al. 1995) o la discriminación de stocks de cetáceos (Aznar et al. 1995). Los helmintos que parasitan a los cetáceos se pueden separar en cuatro grupos distintos: acantocéfalos (20 spp.), cestodos (38 spp.), digeneos (54 spp.) y nematodos (62 spp.). De éstos, los nematodos son los más diversos …

Comparaison ergonomique de deux systèmes de recherche d'information

2009

Etude expérimentale avec 56 participants. Comparaison des temps de recherche d'information et mesure de la charge cognitive dans le cadre d'une tâche de recherche d'information dans deux sites internet fictifs d'agence immobilière. L'un des sites est dit "classique" et l'autre dispose d'une possibilité de prévisualisation des pages web grace à un bouton dédié de la souris. Les résultats montrent que le système dit "transparent" est beaucoup plus efficace dans cette expérience y compris pour les publics les plus âgés.

Retracted Article: Differential detection and quantification of cyclic AMP and other adenosine phosphates in live cells

2017

A new naphthol-based rhodamine derivative (NpRD) has been developed for the selective and differential detection of adenosine 3′,5′-cyclic monophosphate (cAMP) and adenosine phosphates (APs) (ATP, ADP, and AMP) from other nucleotides. The simple detection and quantification of cAMP in human blood cells and in other samples based on the ‘turn on’ fluorescence properties of this chemosensor through colorimetry or fluorometry makes it unique for probable application in high throughput screening.

Self-assembly of an iron(ii)-based M5L6 metallosupramolecular cage

2011

A pentanuclear M(5)L(6) coordination cage is self-assembled in solution from a rigid linear heteroditopic phen-tpy ligand and an iron (II) salt.