Search results for "SPECTRA"
showing 10 items of 3542 documents
Curve resolution procedure for isolating the spectra of unknown interferences from the sample spectrum in analyte determinations
1998
The method described is based on the selection of a wavelength in the sample spectrum that is called ‘reference wavelength’, all measured wavelengths are previously assayed in order to select this reference wavelength. Several wavelengths can be used as the reference. The interferent spectrum is calculated as a function of the interferent absorbance at this wavelength, making use of the ratio between the absorbance of the analyte at the selected wavelength and at every measured wavelength. The proposed methodology can estimate the unknown interferent spectrum from the sample and pure analyte spectra. As a quality guarantee of the estimated spectrum, its shape is also estimated in spiked sam…
Stimulated Raman and Cars Spectroscopy of ν1 and 2ν2 (A1) Bands of 12CF4
1994
Two experimental coherent Raman techniques, stimulated Raman and coherent anti-Stokes Raman spectroscopy (CARS), were employed to study the Raman spectrum of CF 4 in the 900 cm −1 region. The stimulated Raman and CARS spectra of the ν 1 band of CF 4 were recorded at high resolution. The analysis of these spectra enabled some spectroscopic constants of this band to be refined and higher order constants to be determined for the first time. The first high-resolution CARS spectrum of the 2ν 2 (A 1 ) harmonic band is also presented. The rotational transitions of this band up to J = 40 were assigned and the first set of spectroscopic constants for this sub-level were determined. These results imp…
Multichannel multiple scattering calculation ofL2,3-edge spectra ofTiO2andSrTiO3: Importance of multiplet coupling and band structure
2010
We report a theoretical study on x-ray absorption spectroscopy at the Ti-${L}_{2,3}$-edge of rutile and anatase ${\text{TiO}}_{2}$ as well as ${\text{SrTiO}}_{3}$. Using the first-principles multichannel multiple-scattering method, we obtain good agreement with experiment in all cases. We show that both multiplet-type electron correlation effects and the long-range band structure strongly influence the spectra. The differences in line shape between the three compounds are essentially a long-range effect which reflects the different crystal structures on a length scale of 1 nm.
A method for the surface reflectance retrieval from PROBA/CHRIS data over land: application to ESA SPARC campaigns
2005
The Compact High Resolution Imaging Spectrometer (CHRIS) onboard the Project for On-Board Autonomy (PROBA) platform system provides the first high spatial resolution hyper-spectral/multiangular remote sensing data from a satellite system, what represents a new source of information for Earth Observation purposes. A fully consistent radiative transfer approach is always preferred when dealing with the retrieval of surface reflectance from hyperspectral/multiangular data. However, due to the reported calibration anomalies for CHRIS data, a direct atmospheric correction based on physical radiative transfer modeling is not possible, and the method must somehow compensate for such calibration pr…
X-ray measurements of charge transfer reactions involving cold, very highly charged ions
1999
The magnetic trapping mode of the Livermore high-energy Electron Beam Ion Trap is exploited to study charge transfer reactions between cold (few eV/amu) highly charged ions and gases. By selectively puffing neutral gases and monitoring the x-ray emission, state-selective measurements of the charge transfer reaction channels are possible. The observed K-shell x-ray spectra show prominent emission from high-n levels decaying to the n = 1 ground level, which is enabled by electron capture into states with low orbital angular momentum. A comparison with modeling calculations, therefore, allows a determination of the range of principal and angular momentum quantum numbers involved in the reactio…
Positron preferential annihilation in Bi-Sb alloys
2009
We report the measurements of the positron annihilation characteristics, i.e., positron lifetime and coincidence Doppler broadening spectra performed on five Bi-Sb alloys having a Bi content between 12.5 and 81 at.%. The strong effect of the preferential annihilation of positrons with the electrons of the Bi atoms has been revealed in these alloys.
Interaction of metal ions with D-glucobenzothiazoline: isolation and characterization of the resultant products
2002
Six different metal-ion complexes of D-glucobenzothiazoline were synthesized and characterized by analytical and spectral techniques. Formation of different types of species (ML and ML2) were observed with Cu2+, Ag+, Cd2+, Hg2+, and Zn2+ ions. Existence of an anomeric mixture in the case of the Cu2+ complex is identified from the EPR spectra, and the results were further supported by the simulated spectra. The structures were proposed based on different studies.
Selective Antimicrobial Effects of Curcumin@Halloysite Nanoformulation: A Caenorhabditis elegans Study
2019
Alterations in the normal gastrointestinal microbial community caused by unhealthy diet, environmental factors, and antibiotic overuse may severely affect human health and well-being. Novel antimicrobial drug formulations targeting pathogenic microflora while not affecting or even supporting symbiotic microflora are urgently needed. Here we report fabrication of a novel antimicrobial nanocontainer based on halloysite nanotubes loaded with curcumin and protected with a dextrin outer layer (HNTs+Curc/DX) and its effective use to suppress the overgrowth of pathogenic bacteria in Caenorhabditis elegans nematodes. Nanocontainers have been obtained using vacuum-facilitated loading of hydrophobic …
Steroidal saponins from the roots of Smilax aspera subsp. mauritanica
2008
Two new steroidal saponins (1, 2) were isolated from the roots of Smilax aspera subsp. mauritanica (POIR.) ARCANG. (Liliaceae), together with the known curillin G (3), asparagoside E (4), asparoside A (5), asparoside B (6) and the phenolic compound resveratrol (7). Their structures were established mainly on the basis of 600 MHz 2D-NMR spectral data. 3 exhibited antifungal activity against the human pathogenic yeasts Candida albicans, C. glabrata and C. tropicalis (minimum inhibitory concentrations of 25, 25 and 50 microg/ml, respectively) whereas the other compounds were inactive.
Sb-implanted ZnO ultra-thin films
2017
Mild heating of the Zn(C5F6HO2)(2)center dot 2H(2)O center dot CH3(OCH2CH2)(2)OCH3 precursor allowed MOCVD deposition of ZnO films, in a low-pressure horizontal hot-wall reactor, on ITO substrates. The ZnO films were subsequently implanted with Sb ions. XRD measurements provided evidence that they consist of hexagonal, (002) and (101) oriented, crystals. UV-vis spectra showed that the transmittance of these films in the visible region is about 90%. The Sb implanted ZnO film showed a current-voltage characteristic that resembles that of a rectifying diode. This study represents the first example of Sb-implantation in ZnO films obtained by MOCVD.