Search results for "STEP"
showing 10 items of 509 documents
Comments on “Measurement of dimensionless Chezy coefficient in step-pool reach (Case study of Dizin River in Iran)” by Torabizadeh A., Tahershamsi A.…
2018
This paper is a comment on a previous published paper.
Synthesis of fluorinated allylic amines: Reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides with fluorinated imines
2007
A new synthesis of fluorinated allylamines through the reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides (as vinyl anion equivalents) with imines and imino esters has been described. The process includes a TBAF-mediated fragmentation of 2-(trimethylsilyl)ethyl sulfones to afford the desired allylic amines. When the reaction is performed with the corresponding sulfoxides, the fragmentation takes place under the addition conditions, affording the final products in a single step. (C) 2007 Elsevier B.V. All rights reserved.
Synthesis of No-Carrier-Added 4-[18F]Fluorophenol from 4-Benzyloxyphenyl-(2-thienyl)iodonium Bromide
2011
4-[(18)F]Fluorophenol is a versatile synthon for the synthesis of more complex radiopharmaceuticals bearing a 4-[(18)F]fluorophenoxy moiety. In order to prepare 4-[(18)F]fluorophenol in no-carrier-added (n.c.a.) form only a nucleophilic labelling method starting from [(18)F]fluoride is suitable. In this paper a new, two step radiosynthesis starting from 4-benzyloxyphenyl-(2-thienyl)iodonium bromide and [(18)F]fluoride with subsequent deprotection is described, yielding n.c.a. [(18)F]fluorophenol in 34 to 36% radiochemical yield.
The mechanism of formamide hydrolysis in water from ab initio calculations and simulations.
2005
The neutral hydrolysis of formamide in water is a suitable reference to quantify the efficiency of proteolytic enzymes. However, experimental data for this reaction has only very recently been obtained and the kinetic constant determined experimentally is significantly higher than that predicted by previous theoretical estimations. In this work, we have investigated in detail the possible mechanisms of this reaction. Several solvent models have been considered that represent a considerable improvement on those used in previous studies. Density functional and ab initio calculations have been carried out on a system which explicitly includes the first solvation shell of the formamide molecule…
Ancestry and demography and descendants of Iron Age nomads of the Eurasian Steppe
2017
During the 1st millennium before the Common Era (BCE), nomadic tribes associated with the Iron Age Scythian culture spread over the Eurasian Steppe, covering a territory of more than 3,500 km in breadth. To understand the demographic processes behind the spread of the Scythian culture, we analysed genomic data from eight individuals and a mitochondrial dataset of 96 individuals originating in eastern and western parts of the Eurasian Steppe. Genomic inference reveals that Scythians in the east and the west of the steppe zone can best be described as a mixture of Yamnaya-related ancestry and an East Asian component. Demographic modelling suggests independent origins for eastern and western g…
Introductory Quantum Physics Courses using a LabVIEW multimedia module
2007
We present the development of a LabVIEW multimedia module for introductory Quantum Physics courses and our experience in the use of this application as an educational tool in learning methodologies. The program solves the Time Dependent Schrodinger Equation for arbitrary potentials. We describe the numerical method used for solving this equation, as well as some mathematical tools employed to reduce the calculation time and to obtain more accurate results. As an illustration, we present the evolution of a wave packet for three different potentials: the repulsive barrier potential, the repulsive step potential, and the harmonic oscillator. This application has been successfully integrated in…
NUMERICAL ALGORITHMS
2013
For many systems of differential equations modeling problems in science and engineering, there are natural splittings of the right hand side into two parts, one non-stiff or mildly stiff, and the other one stiff. For such systems implicit-explicit (IMEX) integration combines an explicit scheme for the non-stiff part with an implicit scheme for the stiff part. In a recent series of papers two of the authors (Sandu and Zhang) have developed IMEX GLMs, a family of implicit-explicit schemes based on general linear methods. It has been shown that, due to their high stage order, IMEX GLMs require no additional coupling order conditions, and are not marred by order reduction. This work develops a …
Un nouvel invariant des algèbres de Lie et des super-algèbres de Lie quadratiques
2011
In this thesis, we defind a new invariant of quadratic Lie algebras and quadratic Lie superalgebras and give a complete study and classification of singular quadratic Lie algebras and singular quadratic Lie superalgebras, i.e. those for which the invariant does not vanish. The classification is related to adjoint orbits of Lie algebras o(m) and sp(2n). Also, we give an isomorphic characterization of 2-step nilpotent quadratic Lie algebras and quasi-singular quadratic Lie superalgebras for the purpose of completeness. We study pseudo-Euclidean Jordan algebras obtained as double extensions of a quadratic vector space by a one-dimensional algebra and 2-step nilpotent pseudo-Euclidean Jordan al…
A comparison of two indirect methods for estimating average levels of gene flow using microsatellite data.
1999
We compare the performance of Nm estimates based on FST and RST obtained from microsatellite data using simulations of the stepwise mutation model with range constraints in allele size classes. The results of the simulations suggest that the use of microsatellite loci can lead to serious overestimations of Nm, particularly when population sizes are large (N5000) and range constraints are high (K20). The simulations also indicate that, when population sizes are small (N/= 500) and migration rates are moderate (Nm approximately 2), violations to the assumption used to derive the Nm estimators lead to biased results. Under ideal conditions, i.e. large sample sizes (ns/= 50) and many loci (nl/=…
Inter-Relations among Motivation, Self-Perceived Use of Strategies and Academic Achievement in Science: A Study with Spanish Secondary School Students
2020
The relationship between motivation and the use of learning strategies is a focus of research in order to improve students&rsquo