Search results for "Scanning"
showing 10 items of 1808 documents
Real-space Wigner-Seitz Cells Imaging of Potassium on Graphite via Elastic Atomic Manipulation
2015
Atomic manipulation in the scanning tunnelling microscopy, conventionally a tool to build nanostructures one atom at a time, is here employed to enable the atomic-scale imaging of a model low-dimensional system. Specifically, we use low-temperature STM to investigate an ultra thin film (4 atomic layers) of potassium created by epitaxial growth on a graphite substrate. The STM images display an unexpected honeycomb feature, which corresponds to a real-space visualization of the Wigner-Seitz cells of the close-packed surface K atoms. Density functional simulations indicate that this behaviour arises from the elastic, tip-induced vertical manipulation of potassium atoms during imaging, i.e. el…
A Scanning Electron Microscope for Ultracold Atoms
2006
We propose a new technique for the detection of single atoms in ultracold quantum gases. The technique is based on scanning electron microscopy and employs the electron impact ionization of trapped atoms with a focussed electron probe. Subsequent detection of the resulting ions allows for the reconstruction of the atoms position. This technique is expected to achieve a much better spatial resolution compared to any optical detection method. In combination with the sensitivity to single atoms, it makes new in situ measurements of atomic correlations possible. The detection principle is also well suited for the addressing of individual sites in optical lattices.
Competition of Dzyaloshinskii-Moriya and Higher-Order Exchange Interactions in Rh/Fe Atomic Bilayers on Ir(111)
2018
Using spin-polarized scanning tunneling microscopy and density functional theory we demonstrate the occurrence of a novel type of noncollinear spin structure in $\mathrm{Rh}/\mathrm{Fe}$ atomic bilayers on Ir(111). We find that higher-order exchange interactions depend sensitively on the stacking sequence. For fcc-$\mathrm{Rh}/\mathrm{Fe}/\mathrm{Ir}(111)$, frustrated exchange interactions are dominant and lead to the formation of a spin spiral ground state with a period of about 1.5 nm. For hcp-$\mathrm{Rh}/\mathrm{Fe}/\mathrm{Ir}(111)$, higher-order exchange interactions favor an up-up-down-down ($\ensuremath{\uparrow}\ensuremath{\uparrow}\ensuremath{\downarrow}\ensuremath{\downarrow}$) s…
High-resolution scanning electron microscopy of an ultracold quantum gas
2008
Our knowledge of ultracold quantum gases is strongly influenced by our ability to probe these objects. In situ imaging combined with single-atom sensitivity is an especially appealing scenario, as it can provide direct information on the structure and the correlations of such systems. For a precise characterization a high spatial resolution is mandatory. In particular, the perspective to study quantum gases in optical lattices makes a resolution well below one micrometre highly desirable. Here, we report on a novel microscopy technique, which is based on scanning electron microscopy and allows for the detection of single atoms inside a quantum gas with a spatial resolution of better than 15…
Temperature and pressure effects on the spin state of ferric ions in the [Fe(sal2-trien)][Ni(dmit)2] spin crossover complex
2008
Abstract Thermal and pressure effects have been investigated on the [Fe(sal 2 -trien)][Ni(dmit) 2 ] spin crossover complex by means of Mossbauer spectroscopic, calorimetric, X-ray diffraction and magnetic susceptibility measurements. The complex displays a complete thermal spin transition between the S = 5 2 and S = 1 2 spin states of Fe III near 245 K with a hysteresis loop of ca. 30 K. This transition is characterised by a change of the enthalpy, Δ H HL =7 kJ/mol, entropy, Δ S HL =29 J/Kmol, and the unit cell volume, Δ V HL =15.4 A 3 . Under hydrostatic pressures up to 5.7 kbar the thermal transition shifts to higher temperatures by ca. 16 K/kbar. Interestingly, at a low applied pressure …
Towards the origin of the shear force in near-field microscopy
2001
The shear force from a gold or a graphite sample acting on an approaching near-field optical probe is studied in detail. The adiabatic and dissipative contributions to the force are clearly distinguished by monitoring the amplitude as well as the phase of the tip vibration when the tip approaches the surfaces. We also take into account that not only the damping and the resonance frequency but also the mass of the system changes when the tip approaches the surface. The relative strength of the contributions to the force varies differently but characteristically with the distance of the two samples, starting at a much larger distance in the case of graphite. The adiabatic contribution is lar…
Optical properties of biocompatible polyaniline nano-composites
2006
Abstract Polyaniline (PANI) is an electro-active polymer of great interest thanks to its outstanding physical and chemical properties which make it suitable for various applications in optics, bioelectronics, biosensors, diagnostics and therapeutic devices. Unfortunately, PANI is infusible and insoluble in most common solvents and, thus, very difficult to process. In the attempt of improving processability, yet preserving its interesting properties, PANI has been synthesized in the form of particles and dispersed into a hydrogel matrix. The synthesis of PANI–hydrogel composites proceeds via γ-irradiation of PANI dispersions as obtained by ‘in situ’ polymerization of aniline in the presence …
New methods for the determination of local residual stresses
2022
Splat solidification in thermal sprayed coatings relies on phenomena of various origins, time constants, and dimensional scales which altogether lead to complex residual stress states. As a result, in-service performance may be under or overestimated. Hence, this work aims at characterizing residual stress fields using high resolution instruments: a Raman spectrometer and a tailor-made Near-Field Scanning Microwave Microscope (NFSMM). Investigation areas are of 1 µm and 0.020 µm diameter respectively, both techniques are non-destructive and rely on electromagnetic interaction with matter.A preliminary study was conducted on sintered trigonal Cr2O3 with NFSMM as the technique is used for the…
Tracking Formation of a Lava Lake From Ground and Space: Masaya Volcano (Nicaragua), 2014-2017
2018
A vigorously degassing lava lake appeared inside the Santiago pit crater of Masaya volcano (Nicaragua) in December 2015, after years of degassing with no (or minor) incandescence. Here we present an unprecedented-long (3 years) and continuous volcanic gas record that instrumentally characterizes the (re)activation of the lava lake. Our results show that, before appearance of the lake, the volcanic gas plume composition became unusually CO 2 rich, as testified by high CO 2 /SO 2 ratios (mean: 12.2 ± 6.3) and low H 2 O/CO 2 ratios (mean: 2.3 ± 1.3). The volcanic CO 2 flux also peaked in November 2015 (mean: 81.3 ± 40.6 kg/s; maximum: 247 kg/s). Using results of magma degassing models and budg…
Peculiarities of imaging one- and two-dimensional structures in an emission electron microscope. 1. theory
2000
Local changes in work function cause deviations of the electrical microfield near a sample surface as a result of the uniform accelerating field distribution between the sample (cathode) and the extractor electrode (anode). This results in a change in the electron trajectories. As a consequence, the microscope image shows remarkable changes in position, size, intensity and lateral resolution of distinct details, which can be quantitatively described by the calculations presented here. Analysing these effects in the image gives an opportunity to determine the real lateral size of the observed structures and the distribution of local contact potentials.