Search results for "Silicon"
showing 10 items of 1391 documents
The influence of the tape-casting process parameters on the geometric characteristics of SiC tapes
1998
Abstract The production process of the tape-casting technique applied to the production of porous ceramic membranes, suitable for the separation of different chemical species, has been explored, with emphasis on the influence of the operative parameters on the macrogeometric characteristics of the manufactured ceramic porous tapes. The effects of the slurry casting rate, the doctor blade height and the mean particle diameter have been studied and the results reported. The characterization analyses indicate the degree of reliability of this technique to produce planar SiC components and the importance of the particle size in enhancing the structural homogeneity. A study on the variance analy…
The Use of Silicones as Extractants of Biologically Active Substances from Vegetable Raw Materials
2021
Based on theoretical studies, the authors of this paper propose the use of cosmetic organosilicon polymers (commonly called silicones) for the extraction of a complex of biologically active substances contained in vegetable raw materials. It is important to note that the biological molecules do not interact with the organosilicones and, therefore, their properties are not altered after the extraction. In this work, we investigate the efficiency of several polyorganosiloxanes as extractants of vegetable raw materials (Calendula Officialis L. and Artemisia Absinthium L.) useful for the preparation of cosmetic emulsions. Specifically, the extraction studies were conducted by using polyorganosi…
On the Variability of the Temperature Coefficients of mc-Si Solar Cells with Irradiance
2016
Abstract The temperature sensitivity of silicon solar cells is in general assumed to be constant with irradiance in PV forecasting models, although it has been demonstrated experimentally that this is not true. In this study a theoretical model is established that describes the variation of the temperature coefficients of a silicon solar cell as a function of the irradiance. It is shown that the temperature sensitivity of the solar cell efficiency is decreasing with the irradiance and that the main reason for this behavior comes from the increase of the open-circuit voltage with light intensity. Moreover, a dependency of the cell's ideality factor on the irradiance has to be assumed to rece…
ChemInform Abstract: Synthesis of Sesquiterpenes via Silicon-Guided Rearrangement of Epoxydecalins
2009
A survey of the rearrangement of methyldecalins via C-5 carbocation intermediates, with special attention to the silicon-guided rearrangement of epoxydecalins is provided. A TMS group properly posi...
Characterization of acrylic resins used for restoration of artworks by pyrolysis-silylation-gas chromatography/mass spectrometry with hexamethyldisil…
2006
A procedure based on the technique of the pyrolysis-GC/MS has been applied, in this work, in order to determine the composition of synthetic acrylic resins employed in artworks. The method is based on the on line derivatization of these resins using hexamethyldisilazane (HMDS). Results obtained have been compared with those others from direct pyrolysis and in situ thermally assisted hydrolysis and methylation with tetramethylammonium hydroxide (TMAH). Sensitivity using HMDS as derivatising reagent is found similar to that from direct pyrolysis and methylation with TMAH. Better resolution of the most representative peaks has been also obtained. Additionally, this method reduces the formation…
Growth of thin films of single-chain magnets on functionalized silicon surfaces
2018
A one-pot strategy for the direct growth of continuous and regular thin films of a neutral oxamato-bridged heterobimetallic chain, synthesized from Co2+ nitrate and the tetramethylammonium salt of the anionic copper(II) complex (Me4N)2[Cu(2,6-Et2pa)2]·6H2O (1) (2,6-Etpa = N-2,6-diethylphenyloxamate) over Si(111) surfaces functionalized with carboxylic acid terminating groups has been developed. Variation of the growth conditions can provide important differences in the morphology of the obtained films when working in H2O at 20 °C. An anisotropic growth of 1-D fibers is observed under stoichiometric conditions (Co2+/1 = 1:1), while an isotropic growth of 3-D particles occurs for an excess of…
Influence of spectral composition on the temperature coefficients of solar cells from Elkem Solar
2014
The temperature coefficients of solar cells from two different feedstocks — a compensated silicon, the Elkem Solar Silicon (ESS®), and polysilicon - under full and selective parts of the light spectrum are presented based on results obtained using a AAA sun simulator. These results are of particular interest in understanding the possible causes behind the better temperature coefficients usually observed for ESS® compared to polysilicon solar cells when measured with a full AM1.5 spectrum. The optical filtered lights from four different regions of the spectrum have been used to examine the influence of temperature coefficients on the spectral composition. ESS® solar cells showed considerable…
Fabrication and Characterization of Polymeric Optical Waveguides Using Standard Silicon Processing Technology
2005
We report the fabrication and characterization of a rib polymeric waveguide having a thick layer of oxidized porous silicon as an innovative solution for the lower cladding. The waveguide was fabricated using standard silicon substrates and Si-based technology. The multimodal guiding structure has a polymethylmetacrylate (PMMA) core and the innovative lower cladding was obtained by thermal oxidation of a porous silicon layer. The waveguide does not have the upper cladding. Propagation loss measurements were performed at 1.48 /spl mu/m using the cut-back method. We obtained propagation loss of about 1.7 dB/cm, confirming the possibility to use the porous silicon oxide as the lower cladding l…
Tin-based mesoporous silica for the conversion of CO2 into dimethyl carbonate.
2011
Sn-based SBA-15 was prepared by reacting di-n-butyldimethoxystannane with SBA-15 pretreated with trimethylchlorosilane (TMCS) to cap the external hydroxyl groups. Small-angle X-ray diffraction (SXRD), infrared spectroscopy (IR), nitrogen adsorption/desorption, transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and inductively coupled plasma atomic emission (ICP-AES) measurements allow us to propose that the organotin species are located within the pore channels of the mesoporous host. This novel material catalyzes selectively the coupling of CO(2) with methanol to dimethyl carbonate (DMC). The reaction time-conversion dependence shows that a turnover number (TON) of 1…
Effect of some additives on the reactions in fly ASH-Ca(OH)2system
2004
Differential thermal analysis and thermogravimetry were used to evaluate the effect of some additives, such as CaSO4, CaCl2 and silica fume amorphous silica from ferrosilicon synthesis on the mechanism and kinetics of reactions occurring in fly ash-Ca(OH)2 system. The accelerating role of these additives was demonstrated from the data relating to Ca(OH)2 consumption in hydrated pastes, determined by TG measurements.