Search results for "Small-angle scattering"
showing 10 items of 66 documents
Recent developments in ultra–small angle neutron scattering techniques
1998
Abstract There is growing interest in the (nano−) scale structural analysis of condensed matter to study synthetic and biological polymers, colloids, porous materials, etc. Over the past two decades, small–angle neutron scattering (SANS), based on the availability of high fluxes of cold neutrons (wavelengths 4−20 A), has proven to be one of the most important tools for such investigations. This success is due to a fortuitous combination of several factors of cold neutrons: high bulk penetrating power, the ability to manipulate local scattering amplitudes via isotopic labeling or an appropriate choice of solvent (contrast variation), minimal radiation damage, and small absorption for most el…
On the use of grazing-incidence small-angle X-ray scattering (GISAXS) in the morphological study of ion-implanted materials.
2004
Grazing-incidence small-angle X-ray scattering has become a widely used technique for the morphological analysis of surface systems. Here it is show how this technique can be applied to a buried system, like metallic clusters in glass obtained by ion implantation. The optimization of the data-collection geometry is described as well as the details of the quantitative data analysis. An experimental example on Cu + Au-implanted glasses shows the potentiality of the technique.
Optical experiments on a crystallizing hard-sphere–polymer mixture at coexistence
2010
We report on the crystallization kinetics in an entropically attractive colloidal system using a combination of time resolved scattering methods and microscopy. Hard sphere particles are polystyrene microgels swollen in a good solvent (radius a=380nm, starting volume fraction 0.534) with the short ranged attractions induced by the presence of short polymer chains (radius of gyration rg = 3nm, starting volume fraction 0.0224). After crystallization, stacking faulted face centred cubic crystals coexist with about 5% of melt remaining in the grain boundaries. From the Bragg scattering signal we infer the amount of crystalline material, the average crystallite size and the number density of cry…
Structural and electrochemical investigation on re-cast Nafion membranes for polymer electrolyte fuel cells (PEFCs) application
2006
Abstract Starting from a 5 wt% ion power Nafion® solution and dissolving the dry residue in a suitable solvent (10 wt% solution in dimethylacetammide), re-cast Nafion films were developed for polymer electrolyte fuel cells (PEFCs) application. The used Doctor-Blade casting technique allowed to prepare scaled-up membranes comparable to the commercial Nafion ones with good mechanical resistance, thickness homogeneity and an excellent reproducibility. The differences between the re-cast membrane nanostructure and that of the commercial Nafion were investigated by synchrotron small-angle X-ray scattering. The obtained re-cast membrane shows at ambient conditions a semi-crystalline structure wit…
Small angle neutron scattering studies of critical phenomena in a three-component microemulsion
2007
Critical density fluctuations of a ``water-in-oil`` microemulsion consisting of water, benzene, and BHDC (benzyldimethyl-n-hexadecyl ammonium chloride) were observed near the phase boundary by SANS. Observed profiles were well described by product of a form factor of spherical droplets and a structure factor, consisting of a term describing the inter-droplet correlations and also an Ornstein- Zernike component describing the droplet density fluctuations. Allowance was also made fro droplet polydispersity,though the width of the distribution turned out to be very small (1-2%). Observed temperature dependence of osmotic compressibility was fitted using the crossover function proposed by Belya…
On the Line Shape of Backward Emitted Parametric X-Radiation
2002
Parametric X radiation, emitted in opposite direction of an electron which traverses a semi infinite single crystal on a hypothetical straight trajectory, features a Lorentzian line shape with extremely narrow width. However, small angle scattering of the electron in the Coulomb potential of the crystal atoms results in a stochastic change of the electron direction. The latter leads to a line broadening which can be understood essentially as a stochastic frequency modulation of the exponentially damped wave train. The line shape has been calculated analytically by well known probabilistic methods. Results are quoted for various reflections of a silicon single crystal at an electron beam ene…
Modeling techniques for analysing conformational transitions in hemocyanins by small-angle scattering of X-rays and neutrons.
2004
Neutron polarizability and the n-e scattering length
1972
Abstract It is shown that the neutron polarizability contribution to the n-e scattering length is within the present level of precision. The experimental result on this interaction is consistent with a value of the neutron polarizability similar to the proton one.
Small angle scattering from oriented latent nuclear tracks
1984
Abstract Using X-ray and neutron small-angle scattering we studied the defects in mica created by irradiation with uranium ions delivered from the UNILAC accelerator at GSI (Darmstadt, Germany). The defects are regions of reduced density and are best described as cylinders with Gaussian radial density distribution. Scaling laws are given for the time development and the energy dependence of the track parameters.
Small Angle Neutron Scattering from Systems of Interacting Particles. Modelling High Density Micellar Fluids
1992
The need for analytical solutions of the scattering equation for complex situations (polydisperse samples, scattering from non centrosymmetrical particles, etc.) has somehow escaped the attention of the workers in the Small Angle Scattering field, although it is clear that, at the level of sophistication today available for the experiments, a more rigorous approach is necessary. For quite a few years our group has been actively engaged in SANS research and has occasionally devoted its attention to develop alternative ways of data analysis based on more rigorous solutions of the scattering equation.