Search results for "Smut"

showing 10 items of 493 documents

Heterovalent BiIII/PbII ionic substitution in one-dimensional trimethylsulfoxonium halide pseudo-perovskites (X = I, Br)

2021

We report on the synthesis and characterization of novel lead and bismuth hybrid (organic-inorganic) iodide and bromide pseudo-perovskites (ABX3) containing the trimethylsulfoxonium cation (CH3)3SO+ (TMSO) in the A site, Pb/Bi in the B site, and Br or I as X anions. All of these compounds are isomorphic and crystallize in the orthorhombic Pnma space group. Lead-based pseudo-perovskites consist of one-dimensional (1D) chains of face-sharing [PbX6] octahedra, while in the bismuth-based ones, the chains of [BiX6] are interrupted, with one vacancy every third site, leading to a zero-dimensional (0D) local structure based on separated [Bi2I9]3- dimers. Five solid solutions for the iodide with di…

Electronic structureMaterials scienceBand gapHalideIonic bondingchemistry.chemical_elementElectronic structurePositive ionPerovskiteIonBismuthPhysical and Theoretical ChemistryPerovskite (structure)Design for testabilityX ray powder diffractionSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsEnergy gapCrystallographyGeneral EnergychemistryDensity functional theoryorganic-inorganic materialDensity functional theoryDefectBismuth
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Design, assembly and characterization of silicide-based thermoelectric modules

2016

ID: 1143 In: Energy conversion and management, 13-21. Summary: Highlights•Novel silicide-based thermoelectric modules were experimentally investigated.•The modules produced high power of 1.04 W at 405 °C and 3.24 W at 735 °C.•An estimated module efficiency of 5.3% represent the highest reported for silicide systems.AbstractSilicides have attracted considerable attention for use in thermoelectric generators due mainly to low cost, low toxicity and light weight, in contrast to conventional materials such as bismuth and lead telluride. Most reported work has focused on optimizing the materials properties while little has been done on module testing. In this work we have designed and tested mod…

Energy storageThermoelectric equipment02 engineering and technology7. Clean energyThermal expansionBismuthchemistry.chemical_compoundDegradationMagnesium silicideHigher manganese silicideSilicide0202 electrical engineering electronic engineering information engineeringHigher manganese silicidesMagnesiumThermo-Electric materialsThermal expansion mismatchDirect energy conversion[CHIM.MATE]Chemical Sciences/Material chemistryThermoelectric materialsMagnesium silicides[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryConversion directeFuel TechnologyThermal expansionSilicidesMaterials scienceMaximum power principleCharacterization020209 energyEnergy Engineering and Power Technologychemistry.chemical_elementMagnesium silicideThermoelectric moduleThermo-electric modulesElectronic engineering[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM]Chemical SciencesManganeseRenewable Energy Sustainability and the EnvironmentEquivalent circuitsThermoelectricityEngineering physicsLead tellurideThermoelectric generatorCross-section areaNuclear Energy and EngineeringchemistryEnergy transferConventional materialsÉnergieMaterials propertiesThermoelectric generatorsMaterials testing
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Decay Heat Removal and Transient Analysis in Accidental Conditions in the EFIT Reactor

2008

The development of a conceptual design of an industrial-scale transmutation facility (EFIT) of several 100 MW thermal power based on accelerator-driven system (ADS) is addressed in the frame of the European EUROTRANS Integral Project. In normal operation, the core power of EFIT reactor is removed through steam generators by four secondary loops fed by water. A safety-related decay heat removal (DHR) system provided with four independent inherently safe loops is installed in the primary vessel to remove the decay heat by natural convection circulation under accidental conditions which are caused by a loss-of-heat sink (LOHS). In order to confirm the adequacy of the adopted solution for decay…

EngineeringNatural convectionNuclear transmutationArticle Subjectbusiness.industryNuclear engineeringMechanical engineeringThermal power stationTransient analysisNatural circulationNuclear Energy and EngineeringConceptual designlcsh:Electrical engineering. Electronics. Nuclear engineeringDecay heatADS EFIT Reactor Transient Analysis SIMMER-III codebusinessReactor pressure vessellcsh:TK1-9971Settore ING-IND/19 - Impianti Nucleari
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The measurement programme at the neutron time-of-flight facility n_TOF at CERN

2016

Neutron-induced reaction cross sections are important for a wide variety of research fields ranging from the study of nuclear level densities, nucleosynthesis to applications of nuclear technology like design, and criticality and safety assessment of existing and future nuclear reactors, radiation dosimetry, medical applications, nuclear waste transmutation, accelerator-driven systems and fuel cycle investigations. Simulations and calculations of nuclear technology applications largely rely on evaluated nuclear data libraries. The evaluations in these libraries are based both on experimental data and theoretical models. CERN’s neutron time-of-flight facility n TOF has produced a considerabl…

EngineeringNuclear transmutationQC1-999Nuclear engineering[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]7. Clean energy01 natural sciencesNuclear physicsPhysics and Astronomy (all)0103 physical sciences:Física::Electromagnetisme [Àrees temàtiques de la UPC]ddc:530Nuclear Physics - ExperimentNeutron010306 general physicsNeutrons:Energies::Energia nuclear [Àrees temàtiques de la UPC]Large Hadron Collider010308 nuclear & particles physicsbusiness.industryPhysicsNuclear dataRadioactive wasteNuclear technologyBeamlineCriticalitybusinessEPJ Web of Conferences
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A field methodology to study effects of UV radiation on fish larvae.

2003

There is a considerable lack of in situ specific information about the effects of UV-B radiation on limnic animals studied in the field. We exposed larval pike (Esox lucius L.) in two types of cuvettes (glass and quartz) placed at different depths (5 or 15 cm) to natural solar UV or to artificially enhanced UV-B (lamps on 3 h per day), simulating the scenarios for coming decades. Dose realism and comparability with earlier laboratory experiments was the main purpose, and therefore UV-B irradiances to the surface as well as underwater irradiances were directly measured. Result showed that UV-B dose rates in natural waters are low even though DOC concentration was low (4.8 mg/l) in our study …

Environmental EngineeringUltraviolet RaysPopulation DynamicsRadiationFish larvaemedicine.disease_causeRisk AssessmentAnimal sciencemedicineAnimalsHSP70 Heat-Shock ProteinsWaste Management and DisposalEsoxWater Science and TechnologyCivil and Structural EngineeringPikecomputer.programming_languagebiologyBehavior AnimalEcologySuperoxide DismutaseEcological ModelingEnvironmental factorbiology.organism_classificationPollutionRadiation effectCuvetteLarvaEsocidaeEnvironmental scienceDose ratecomputerBiomarkersEnvironmental MonitoringWater research
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Grafēna un bismuta selenīda heterostruktūru sintēze un īpašības

2018

Grafēna un bismuta selenīda heterostrūkturu sintēze un īpašības . Nečiporenko A., zinātniskie vadītāji asoc. prof. Dr.chem. Donāts Erts., Mag. chem. Margarita Baitimirova. bakalaura darbs, 31 lappuses, 13 attēli, 2 tabulas, 37 literatūras avoti, 1 pielikums. Latviešu valodā. Darbā ir veikta Bi2Se3/grafēns heterostrūkturu sintēze ar fizikālo tvaiku nogulsnēšanas metodi, kā izejas materiālu izmantojot kristālisku Bi2Se3. Darbā tika pētītas Bi2Se3 nanostruktūru veidošanas sākumstadijas uz dažādos veidos apstrādāta grafēna un vizlas. Iegūtas heterostruktūras tika analizētas ar skenējošo elektronu mikroskopu un atomspēku mikroskopu.

FIZIKĀLĀ TVAIKU NOGULSNĒŠANABISMUTA SELENĪDSĶīmijaGRAFĒNS
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Ultraplānu bismuta selenīda nanostruktūru iegūšanas metodes

2017

Ultraplānu bismuta selenīda nanostruktūru iegūšanas metodes. Biezā K., zinātniskie vadītāji - asoc. prof., Dr. ķīm., Donāts Erts, Dr. Jana Andžāne, Maģistra darbs, 49 lappuses, 25 attēli, 9 tabulas, 30 literatūras avoti, 5 pielikumi. Latviešu valodā. Bismuta selenīds ir topoloģiskais izolators, tas ir materiāls, kura lielākā daļa tilpumā ir dielektriķis, toties ārējā virsma ir vadoša. Topoloģisko īpašību uzlabošanai un tālākam praktiskajam pielietojumam svarīgi iegūt plānas nanostruktūras ar biezumu zem 10 nm, kam, savukārt, ir liela praktiska nozīme topoloģisko izolatoru fundamentālajos pētījumos un materiāla pielietojumam kā termoelektriķim. Darbā pielietotas vairākas metodes, lai iegūtu …

FIZIKĀLĀ TVAIKU NOGULSNĒŠANATERMISKĀS IZTVAICĒŠANAS METODEULTRAPLĀNAS NANOSTRUKTŪRASKODINĀŠANAS METODE AR ARGONA JONIEMBISMUTA SELENĪDSĶīmija
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Oxidative stress induces the expression of the major histocompatibility complex in murine tumor cells.

2001

The effect of t-butyl hydroperoxide (t-BOOH) on the induction of the Major Histocompatibility Complex (MHC) class I genes has been studied in two cell clones (B9 and G2) of the methylcholanthrene-induced murine fibrosarcoma GR9. These two clones were selected based on their different biological and biochemical behavior specially related to their tumor induction capability when injected into a BALB/c mouse. t-BOOH (0.125 mM) induced the expression of H-2 molecules in both cell clones. In B9 cell clone, in which MHC basal expression is very low or absent, t-BOOH significantly induced H-2Kd, H-2Dd and H-2Ld molecules. In G2 cell clone the expression of MHC class I genes was also enhanced by th…

FibrosarcomaCellElectrophoretic Mobility Shift AssayBiologyMajor histocompatibility complexBiochemistryMajor Histocompatibility ComplexTransactivationMiceAntigentert-ButylhydroperoxideCell CloneMalondialdehydeMHC class ImedicineTumor Cells CulturedAnimalsGlutathione PeroxidaseMice Inbred BALB CSuperoxide DismutaseMHC Class I GeneHistocompatibility Antigens Class INF-kappa BDeoxyguanosineGeneral Medicine3T3 CellsCatalaseFlow CytometryMolecular biologyGlutathioneOxidative Stressmedicine.anatomical_structureGene Expression Regulation8-Hydroxy-2'-Deoxyguanosinebiology.proteinCD8MethylcholanthreneFree radical research
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Seminal plasma biochemistry and spermatozoa characteristics of Atlantic cod (Gadus morhua L.) of wild and cultivated origin

2011

Abstract Our objectives were to compare spermatozoa activity, morphology, and seminal plasma (SP) biochemistry between wild and cultivated Atlantic cod ( Gadus morhua ). Swimming velocities of wild cod spermatozoa were significantly faster than those of cultivated males. Wild males had a significantly larger spermatozoa head area, perimeter, and length, while cultivated males had more circular heads. Total monounsaturated fatty acids and the ratio of n−3/n−6 were significantly higher in sperm from wild males, while total n−6 from cultivated males was significantly higher than the wild males. Significantly higher concentrations of the fatty acids C14:0, C16:1n−7, C18:4n−3, C20:1n−11, C20:1n−…

Fish ProteinsMaleAntioxidantPhysiologymedicine.medical_treatmentAquacultureBiochemistryFatty Acids Monounsaturatedchemistry.chemical_compoundAquacultureSemenLactate dehydrogenasemedicineAnimalsGadusMolecular Biologychemistry.chemical_classificationL-Lactate DehydrogenasebiologySuperoxide Dismutasebusiness.industryFatty AcidsOsmolar ConcentrationFatty acidbiology.organism_classificationSpermatozoaSpermAntioxidant capacityGadus morhuachemistryBiochemistryFertilizationSperm MotilityFemalelipids (amino acids peptides and proteins)Atlantic codbusinessComparative Biochemistry and Physiology Part A: Molecular & Integrative Physiology
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Mn(II) complexes of scorpiand-like ligands. A model for the MnSOD active centre with high in vitro and in vivo activity

2015

Manganese complexes of polyamines consisting of an aza-pyridinophane macrocyclic core functionalised with side chains containing quinoline or pyridine units have been characterised by a variety of solution techniques and single crystal x-ray diffraction. Some of these compounds have proved to display interesting antioxidant capabilities in vitro and in vivo in prokaryotic (bacteria) and eukaryotic (yeast and fish embryo) organisms. In particular, the Mn complex of the ligand containing a 4-quinoline group in its side arm which, as it happens in the MnSOD enzymes, has a water molecule coordinated to the metal ion that shows the lowest toxicity and highest functional efficiency both in vitro …

Fish ProteinsSaccharomyces cerevisiae ProteinsStereochemistryOryziasSaccharomyces cerevisiaeLigandsFish embryo modelsBiochemistryAntioxidantsInorganic Chemistrychemistry.chemical_compoundAntioxidant activityIn vivoCatalytic DomainPyridineSide chainEscherichia coliAnimalschemistry.chemical_classificationManganeseBacteriaLigandSuperoxide DismutaseEscherichia coli ProteinsQuinolineYeastIn vitroYeastMn(II) complexesEnzymechemistryModels ChemicalPolyazamacrocyclic scorpiandsQuinolines
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