Search results for "Solid-State"
showing 10 items of 530 documents
Synthesis of (trans-A2)BC-Type Porphyrins with Acceptor Diethoxyphosphoryl and Various Donor Groups and their Assembling in the Solid State and at In…
2019
Cover Picture: Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties (Chem. Eur. J…
2015
Single Molecule Solid State Light Emitting Electrochemical Cells with Lifetimes Superior to 3000 Hours
2008
Anionic halide···alcohol clusters in the solid state.
2014
The cationic (1,3,5-triazapentadiene)Pt(II) complexes [1](Cl)2, [2](Cl)2, [3](Br)2, and [4](Cl)2, were crystallized from ROH-containing systems (R = Me, Et) providing alcohol solvates studied by X-ray diffraction. In the crystal structures of [1-4][(Hal)2(ROH)2] (R = Me, Et), the Hal(-) ion interacts with two or three cations [1-4](2+) by means of two or three or four contacts thus uniting stacked arrays of complexes into the layers. The solvated MeOH or EtOH molecules occupy vacant space, giving contacts with [1-4](2+), and connects to the Hal(-) ion through a hydrogen bridge via the H(1O)O(1S) H atom forming, by means of the Hal(-)···HOR (Hal = Cl, Br) contact, the halide-alcohol cluster.…
Pleurotus ostreatus volatile aroma compounds identified from fruit-body and from mycelium grown in submerged and solid-state cultures
2003
Comparative analyses of volatile aroma compounds of the Pleurotus ostreatus JMO.95 fruit-body and its corresponding mycelium grown in liquid, on agar surface, or on solid support cultures have been carried out by dynamic headspace concentration using GC/MS and GC/sniffing. The aroma of the fruit-body was due essentially to the presence of octan-3-one and, in a lesser extent, to the presence of octan-3-ol. Other compounds, such as oct-l-en-3-ol, oct-l-en, 2-methylbutanol and a-pinene were also present in low concentrations. The comparison of the aromatic spectra of the fruit-body with the aromatic spectra of mycelia obtained under different culture conditions indicated that the main aromatic…
A simple protocol for extraction and detection of pyrazines produced by fungi in solid state fermentation
1992
A protocol for the extraction and detection of pyrazines produced by fungi in Solid State Fermentation that gave good recovery of these compounds was devised together with specific techniques for detection by Gas Chromatography (GC). The protocol involved solid-liquid and liquid-liquid extractions, concentration of the extracts and GC analysis. Extraction yields were measured from a model system in which synthetic pyrazines were added. Extracts were analysed with a gas chromatograph equipped with a thermo-ionic detector to allow specific pyrazine detection.
Struktūra un fotofizikālie procesi 0D un 1D InGaN kompozītu materiālos
2014
Šajā disertācijā tiek aprakstīti strukturālās un fotofizikālās MOCVD izaudzēto GaN nanovadu (NV) un InGaN kvantu punktu (KP) īpašības. Abos gadījumos ir parādīts, ka ex-situ RHEED mērījumi ir iespējami un sniedz kvalitatīvu informāciju par struktūru. Kombinācijā ar citām metodēm, pirmkārt, ir parādīts, ka nemetāliskā katalizatora veicinātā GaN NV īpašības, kad sintezēts uz GaN (0001) virsmas, atšķiras no tradicionāli iegūtajiem. Šinī gadījumā katalizators lokalizējas pie nanovadu pamatnes nevis tā galā un augšanas virziens ir atšķirīgs no kristalogrāfiskās c-ass, rezultātā iegūstot semipolārās NV struktūras. Otrkārt, InGaN kvantu punktos ir konstatēt saspiesta kristāliskā režģa struktūra au…
ChemInform Abstract: Pillar[n]arenes - A Novel, Highly Promising Class of Macrocyclic Host Molecules
2014
Review: [preparation, structure in solution and in the solid state and complexation; 100 refs.
Indefinitely stable iron(IV) cage complexes formed in water by air oxidation
2017
In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the ones obtained synthetically appear to be unstable in polar organic solvents, especially aqueous solutions, and this is what limits their studies and use. Here we describe unprecedented iron(IV) hexahydrazide clathrochelate complexes that are assembled in alkaline aqueous media from iron(III) salts, oxalodihydrazide and formaldehyde in the course of a metal-templated reaction accompanied by air oxidation…
From magnetic to nonlinear optical switches in spin-crossover complexes
2013
ISI Document Delivery No.: 109TF Times Cited: 0 Cited Reference Count: 173 Lacroix, Pascal G. Malfant, Isabelle Real, Jose-Antonio Rodriguez, Vincent Wiley-v c h verlag gmbh Weinheim Si; Various attempts to combine magnetic and nonlinear optical (NLO) properties in a molecule are reviewed, with a special focus on the possibility of interplay between the magnetic component and the quadratic (proportional to E-2) NLO response. This multidisciplinary research leads to the idea of spin-crossover-induced (SCO-induced) NLO switching and is evaluated at the synthetic level, with insights provided by computational chemistry. The need for nontraditional experimental setups to record NLO properties i…