Search results for "Spectral resolution"
showing 10 items of 94 documents
First Specifications of a PSTM Working In the Infrared
1993
One of the most promising extension of the photon scanning tunneling microscope (PSTM) is its use as a locally resolved spectroscopic tool. The infrared (IR) spectral window offers a wide variety of interesting applications since many materials have a well-defined signature in this range. We have undertaken the experimental modifications that are necessary to operate the existing PSTM’s in the IR domain. In this work, we present preliminary data obtained with two IR light sources: an extended source (Globar type) and the free electron IR laser source (CLIO) available at LURE (Orsay). In both cases, the evanescent field has been detected with a fluoride glass optical fiber and the characteri…
Unveiling pure-metal ejecta X-ray emission in supernova remnants through their radiative recombination continuum
2020
Spectral analysis of X-ray emission from ejecta in supernova remnants (SNRs) is hampered by the low spectral resolution of CCD cameras, which creates a degeneracy between the best-fit values of abundances and emission measure. The combined contribution of shocked ambient medium and ejecta to the X-ray emission complicates the determination of the ejecta mass and chemical composition, leading to big uncertainties in mass estimates and it can introduce a bias in the comparison between the observed ejecta composition and the yields predicted by explosive nucleosynthesis. We explore the capabilities of present and future spectral instruments with the aim of identifying a spectral feature which …
Modelling spatial and spectral systematic noise patterns on CHRIS/PROBA hyperspectral data
2006
In addition to typical random noise, remote sensing hyperspectral images are generally affected by non-periodic partially deterministic disturbance patterns due to the image formation process and characterized by a high degree of spatial and spectral coherence. This paper presents a new technique that faces the problem of removing the spatial coherent noise known as vertical stripping (VS) usually found in images acquired by push-broom sensors, in particular for the Compact High Resolution Imaging Spectrometer (CHRIS). The correction is based on the hypothesis that the vertical disturbance presents higher spatial frequencies than the surface radiance. The proposed method introduces a way to…
Towards high-resolution laser ionization spectroscopy of the heaviest elements in supersonic gas jet expansion
2017
Resonant laser ionization and spectroscopy are widely used techniques at radioactive ion beam facilities to produce pure beams of exotic nuclei and measure the shape, size, spin and electromagnetic multipole moments of these nuclei. However, in such measurements it is difficult to combine a high efficiency with a high spectral resolution. Here we demonstrate the on-line application of atomic laser ionization spectroscopy in a supersonic gas jet, a technique suited for high-precision studies of the ground- and isomeric-state properties of nuclei located at the extremes of stability. The technique is characterized in a measurement on actinium isotopes around the N=126 neutron shell closure. A…
Comparison of line-by-line and band models of near-IR methane absorption applied to outer planet atmospheres
2012
Import OPTIWOS; International audience; Recent improvements in high spectral resolution measurements of methane absorption at wavenumbers between 4800 cm(-1) and 7919 cm(-1) have greatly increased the number of lines with known lower state energies, the number of weak lines, and the number of lines observed at low temperatures (Campargue, A., Wang, L, Kassi, S., Masat, M., Votava, O. [2010]. J. Quant. Spectrosc. Radiat. Trans. 111, 1141-1151; Campargue, A., Wang, L, Liu, A.W., Hu, S.M., Kassi, S. [2010]. Chem. Phys. 373, 203-210; Mondelain, D., Kassi, S., Wang, L.C. [2011]. Phys. Chem. Chem. Phys. 13, 7985-7996; Nikitin, A.V. et al. [2011a]. J. Mol. Spectrosc. 268, 93-106; Nikitin, A.V. et …
Two-dimensional nuclear magnetic resonance spectroscopy with a microfluidic diamond quantum sensor
2019
Quantum sensors based on nitrogen-vacancy centers in diamond have emerged as a promising detection modality for nuclear magnetic resonance (NMR) spectroscopy owing to their micron-scale detection volume and non-inductive based detection. A remaining challenge is to realize sufficiently high spectral resolution and concentration sensitivity for multidimensional NMR analysis of picoliter sample volumes. Here, we address this challenge by spatially separating the polarization and detection phases of the experiment in a microfluidic platform. We realize a spectral resolution of 0.65 +/- 0.05 Hz, an order-of-magnitude improvement over previous diamond NMR studies. We use the platform to perform …
Zeeman effect in sulfur monoxide: A tool to probe magnetic fields in star forming regions
2017
[Context] Magnetic fields play a fundamental role in star formation processes and the best method to evaluate their intensity is to measure the Zeeman effect of atomic and molecular lines. However, a direct measurement of the Zeeman spectral pattern from interstellar molecular species is challenging due to the high sensitivity and high spectral resolution required. So far, the Zeeman effect has been detected unambiguously in star forming regions for very few non-masing species, such as OH and CN.
Determining the Geometry of Hydrogen Bonds in Solids with Picometer Accuracy by Quantum-Chemical Calculations and NMR Spectroscopy
2005
The structure of multiply hydrogen-bonded systems is determined with picometer accuracy by a combined solid-state NMR and quantum-chemical approach. On the experimental side, advanced 1H-15N dipolar recoupling NMR techniques are capable of providing proton-nitrogen distances of up to about 250 pm with an accuracy level of +/-1 pm for short distances (i.e., around 100 pm) and +/-5 pm for longer ones (i.e., 180 to 250 pm). The experiments were performed under fast magic-angle spinning, which ensures sufficient dipolar decoupling and spectral resolution of the 1H resonance lines. On the quantum-chemical side, the structures of the hydrogen-bonded systems were computationally optimised, yieldin…
Resonance ionization schemes for high resolution and high efficiency studies of exotic nuclei at the CRIS experiment
2019
© 2019 This paper presents an overview of recent resonance ionization schemes used at the Collinear Resonance Ionization Spectroscopy (CRIS) setup located at ISOLDE, CERN. The developments needed to reach high spectral resolution and efficiency will be discussed. Besides laser ionization efficiency and high resolving power, experiments on rare isotopes also require low-background conditions. Ongoing developments that aim to deal with beam-related sources of background are presented. ispartof: Nuclear Instruments & Methods In Physics Research Section B-Beam Interactions With Materials And Atoms vol:463 pages:398-402 ispartof: location:SWITZERLAND, CERN, Geneva status: published
A gas-jet apparatus for high-resolution laser spectroscopy on the heaviest elements at SHIP
2020
© 2019 Elsevier B.V. Laser spectroscopy enables the determination of fundamental atomic and nuclear properties with high precision. In view of the low production rates of the heaviest elements, a high total efficiency is a crucial requirement for any experimental setup to be used in on-line experiments. The setup requires the use of gas stopping techniques to slow down the radionuclides of interest. In previous studies laser spectroscopy was performed inside a gas-filled stopping cell with a limited spectral resolution of a few GHz. Collisional broadening inside stopping cells ultimately limits the precision of laser spectroscopic studies and hampers in particular hyperfine spectroscopy. Th…