Search results for "Spectral"
showing 10 items of 3116 documents
Stroboscopic detection of nuclear resonance in an arbitrary scattering channel
2015
The theory of heterodyne/stroboscopic detection of nuclear resonance scattering is developed, starting from the total scattering matrix as a product of the matrix of the reference sample and the sample under study. This general approach holds for any dynamical scattering channel. The forward channel, which is discussed in detail in the literature, reveals the speciality that electronic scattering causes only an energy independent diminution of the intensity. For all other channels, complex resonance line shapes in the heterodyne/stroboscopic spectra - as a result of interference of electronic and nuclear scattering - is encountered. The grazing incidence case is evaluated and described in d…
Conformational mobility of thianthrene-5-oxide.
2005
[reaction: see text] Data on the apparent dipole moment of thianthrene-5-oxide (1) and (1)H NMR spectra in different solvents support the conformational mobility of 1, which flaps between two limit boat conformations with the sulfinyl group in pseudoequatorial and pseudoaxial positions, respectively. The conformational equilibrium of 1 occurs too fast for the (1)H NMR (500 MHz) time-scale even at -130 degrees C, and the equilibrium constant has not been determined. The apparent dipole moments of 1 in n-hexane and 1,4-dioxane and the (1)H NMR spectra of 1 and the model compounds cis- and trans-thianthrene-5,10-dioxides (2) and thianthrene (5) in different solvents and at various temperatures…
13C NMR, 1H NMR and IR spectra of a series of monochloroesters of aliphatic short chain carboxylic acids
1981
Abstract 13 C chemical shifts for 14 isomeric monochloroesters of aliphatic carboxylic acids from propanoic acid to hexanoic acid have been determined. Comparisons are made with the literature values for methyl monochloro-octanoate isomers. Substituent effects for all positions are given. Characteristic IR absorption bands are presented and comparisons are made with regard to the isomeric structure. Connections are suggested between observed trends in IR absorption frequencies and some “abnormal” chlorine substituent effects on 13 C chemical shifts. 1 H NMR spectra of these compounds are considered.
Overionization in X-ray spectra: a new paradigm for Mixed-Morphology SNRs
2011
Mixed-morphology SNRs are characterized by a shell-like radio emission, a centrally peaked X-ray morphology, and by interaction with molecular clouds. Many models have been proposed to explain these peculiar remnants, but their physical origin is still unclear. The recent discovery of over-ionized (i. e. recombining) ejecta in 3 mixed-morphology SNRs has dramatically challenged all the previous models and opened up new, unexpected scenarios. I review the main properties of these remnants and their peculiar X-ray spectral properties. I also discuss the hydrodynamic model developed to explain the presence of over-ionized ejecta in W49B and present a list of open issues that still need to be c…
K-band spectroscopy of IGR J16358-4726 and IGR J16393-4643: two new symbiotic X-ray binaries
2009
Symbiotic X-ray Binaries (SyXBs) are a recently discovered subclass of Low Mass X-ray Binaries. Their growing number makes them an important evolutionary channel of X-ray Binaries. Our goal is to perform spectral analysis and classification of the proposed counterparts to IGR J16358-4726 and IGR J16393-4643 and to establish their nature as X-ray systems. We used the ESO/UT1 ISAAC spectrograph to observe the proposed counterparts to the two sources, obtaining K-band medium resolution spectra (R = 500) with a S/N > 140. Data reduction was performed with the standard procedure. We classified them by means of comparison with published atlases. We performed SED fitting in order to refine the …
Correlated optical/X-ray variability in the high-mass X-ray binary SAX J2103.5+4545
2009
SAX J2103.5+4545 is the Be/X-ray binary with the shortest orbital period. It shows extended bright and faint X-ray states that last for a few hundred days. The main objective of this work is to investigate the relationship between the X-ray and optical variability and to characterise the spectral and timing properties of the bright and faint states. We have found a correlation between the spectral and temporal parameters that fit the energy and power spectra. Softer energy spectra correspond to softer power spectra. That is to say, when the energy spectrum is soft the power at high frequencies is suppressed. We also present the results of our monitoring of the Halpha line of the optical cou…
A broadband spectral analysis of 4U 1702-429 using XMM-Newton and BeppoSAX data
2018
Most of the X-ray binary systems containing neutron stars classified as Atoll sources show two different spectral states, called soft and hard. Moreover, a large number of these systems show a reflection component relativistically smeared in their spectra, which gives information on the innermost region of the system. Our aim is to investigate the poorly studied broadband spectrum of the low mass X-ray binary system 4U 1702-429, which was recently analysed combining XMM-Newton and INTEGRAL data. The peculiar value of the reflection fraction brought us to analyse further broadband spectra of 4U 1702-429. We re-analysed the spectrum of the XMM-Newton/INTEGRAL observation of 4U 1702-429 in the…
Unveiling pure-metal ejecta X-ray emission in supernova remnants through their radiative recombination continuum
2020
Spectral analysis of X-ray emission from ejecta in supernova remnants (SNRs) is hampered by the low spectral resolution of CCD cameras, which creates a degeneracy between the best-fit values of abundances and emission measure. The combined contribution of shocked ambient medium and ejecta to the X-ray emission complicates the determination of the ejecta mass and chemical composition, leading to big uncertainties in mass estimates and it can introduce a bias in the comparison between the observed ejecta composition and the yields predicted by explosive nucleosynthesis. We explore the capabilities of present and future spectral instruments with the aim of identifying a spectral feature which …
A possible jet precession in the periodic quasar B0605-085
2010
The quasar B0605-085 (OH 010) shows a hint for probable periodical variability in the radio total flux-density light curves. We study the possible periodicity of B0605-085 in the total flux-density, spectra and opacity changes in order to compare it with jet kinematics on parsec scales. We have analyzed archival total flux-density variability at ten frequencies (408 MHz, 4.8 GHz, 6.7 GHz, 8 GHz, 10.7 GHz, 14.5 GHz, 22 GHz, 37 GHz, 90 GHz, and 230 GHz) together with the archival high-resolution very long baseline interferometry data at 15 GHz from the MOJAVE monitoring campaign. Using the Fourier transform and discrete autocorrelation methods we have searched for periods in the total flux-de…
The unusual multiwavelength properties of the gamma-ray source PMN J1603-4904
2013
We investigate the nature and classification of PMNJ1603-4904, a bright radio source close to the Galactic plane, which is associated with one of the brightest hard-spectrum gamma-ray sources detected by Fermi/LAT. It has previously been classified as a low-peaked BL Lac object based on its broadband emission and the absence of optical emission lines. Optical measurements, however, suffer strongly from extinction and the absence of pronounced short-time gamma-ray variability over years of monitoring is unusual for a blazar. We are combining new and archival multiwavelength data in order to reconsider the classification and nature of this unusual gamma-ray source. For the first time, we stud…