Search results for "Spectroscopy"

The polarization dependence of x‐ray photoelectron yield of a Au photocathode

1994

We report a measurement of the total photoelectron yield of gold as a function of the incident x‐ray polarization. Polarized x rays with energies of 2.5, 2.7, and 4.0 keV were used to excite a gold photocathode at a glancing incidence angle between 5° and 50°. Contrary to a previous report, we found no measurable polarization dependence for all three x‐ray energies. We conclude that the modulation factor, i.e., the fractional change of the total yield when the polarization state is varied, is less than 4%.

Local Structure of Supported Keggin and Wells-Dawson Heteropolyacids and Its Influence on the Catalytic Activity

2019

[EN] Keggin [PW12O40]3– and Wells–Dawson [P2W18O62]6– heteropolyanions are nanosized transition-metal-oxygen clusters belonging to the heteropolyacids (HPAs) family. They are widely used as catalysts due to their high Brønsted acidity, and their dispersion on solid supports favors the accessibility to their acid sites generally increasing the catalytic activity. A series of binary materials composed of Keggin or Wells–Dawson HPAs and SiO2, TiO2, and ZrO2 have been prepared by impregnation or solvothermal methods. Remarkable differences have been found in the catalytic activities among the unsupported and supported HPAs. These differences have been correlated in the past to the structural ch…

Investigation of phthalocyanine crystals exposed to NO2 ambient gas

2002

Crystals of free base phthalocyanine (H2pc) and its unsubstituted metal derivatives Mpc (where M=Ni, Cu, Zn, Pb, and pc=C32H16N8 2−=phthalocyanine ligand) were examined after being exposed to NO2 ambient gas. Scanning electron microscopy (SEM) supported by X-ray microprobe analysis (EDAX), UV–Vis and FTIR spectroscopy as well as X-ray powder diffractometry (XRD) were applied to study the crystals chemistry and surface morphology. The NO2 molecules were found to penetrate the crystal unit which led to the breakdown of the phthalocyanine macrocycle. The surface of the doped crystals has been scaled and covered by a layer composed predominantly of phthalimide. Despite vacuum desorption, it has…

Local structure studies of SrTi16O3and SrTi18O3

2014

In this work we report on the local structure of Ti in SrTi 16 O3 (STO16) and SrTi 18 O3 (STO18) investigated in the low temperature range (6‐300K) by extended x-ray absorption fine structure and x-ray absorption near edge structure (XANES) spectroscopy at Ti K-edge and by optical second harmonic generation (SHG). By comparing XANES of STO16 and STO18 we have identified the isotopic effect which produces at T < 100K a noticeable difference in the measured mean square relative displacements (MSRD) of Ti‐O1 bonds: while STO16 follow the expected Einstein-like behavior, for STO18 we have measured an increase of MSRD values with decreasing temperature. This is an indication of an increasing off…

Large 256-Pixel X-ray Transition-Edge Sensor Arrays With Mo/TiW/Cu Trilayers

2015

We describe the fabrication and electrical characterization of 256-pixel X-ray transition-edge sensor (TES) arrays intended for materials analysis applications. The processing is done on 6-in wafers, providing capabilities on a commercial scale. TES films were novel proximity coupled Mo/TiW/Cu trilayers, where the thin TiW layer in between aims to improve the stability of the devices by preventing unwanted effects such as Mo/Cu interdiffusion. The absorber elements were electrodeposited gold of thickness 2 μm. The single-pixel design discussed here is the so-called Corbino geometry. Most design goals were successfully met, such as the critical temperature, thermal time constant, and transit…

X-ray Spectroscopy of (Ba,Sr,La)(Fe,Zn,Y)O3-δIdentifies Structural and Electronic Features Favoring Proton Uptake

2020

Mixed protonic–electronic conducting oxides are key functional materials for protonic ceramic fuel cells. Here, (Ba,Sr,La)(Fe,Zn,Y)O3−δ perovskites are comprehensively investigated by X-ray spectroscopy (in oxidized and reduced states). Extended X-ray absorption fine structure shows that Zn,Y doping strongly increases the tendency for Fe–O–Fe buckling. X-ray absorption near-edge spectroscopy at the Fe K-edge and X-ray Raman scattering at the O K edge demonstrate that both iron and oxygen states are involved when the samples are oxidized, and for the Zn,Y doped materials, the hole transfer from iron to oxygen is less pronounced. This can be correlated with the observation that these material…

Microscopic defects and impurity analyses of multicrystalline silicon solar cells from different manufacturing routes

2013

It is important to fully understand the physical behavior of solar cells made by materials from alternative process routes. Solar cells from Elkem Solar Grade Silicon and standard polysilicon have been investigated with light beam induced current and electroluminescence imaging. The low efficiency regions have been further analyzed by Scanning Electron Microscopy under different imaging modes. It was found that cell regions of low performance had undergone plastic deformations resulting in the creation of crystalline defects appearing as subgrain patterns. Similar patterns were observed in both ESS™ and standard polysilicon. Energy-dispersive X-ray spectroscopy (EDS) and electron backscatte…

Hard-X-ray-induced excited-spin-state trapping.

2007

Time-dependent current-voltage characteristics of Al/p-CdTe/Pt x-ray detectors

2012

Current-voltage (I-V) characteristics of Schottky Al/p-CdTe/Pt detectors were investigated in dark and at different temperatures. CdTe detectors with Al rectifying contacts, very appealing for high resolution x-ray and gamma ray spectroscopy, suffer from bias-induced polarization phenomena which cause current increasing with the time and severe worsening of the spectroscopic performance. In this work, we studied the time-dependence of the I-V characteristics of the detectors, both in reverse and forward bias, taking into account the polarization effects. The I-V measurements, performed at different time intervals between the application of the bias voltage and the measurement of the current…

Quantitative molecular plating of large-area 242Pu targets with improved layer properties

2015

Abstract For measurements of the neutron-induced fission cross section of 242Pu, large-area (42 cm2) 242Pu targets were prepared on Ti-coated Si wafers by means of constant current density molecular plating. Radiochemical separations were performed prior to the platings. Quantitative deposition yields (>95%) were determined for all targets by means of alpha-particle spectroscopy. Layer densities in the range of 100–150 μg/cm2 were obtained. The homogeneity of the targets was studied by radiographic imaging. A comparative study between the quality of the layers produced on the Ti-coated Si wafers and the quality of layers grown on normal Ti foils was carried out by applying scanning electron…