Search results for "Spinning"

Green and Integrated Wearable Electrochemical Sensor for Chloride Detection in Sweat

2022

Wearable sensors for sweat biomarkers can provide facile analyte capability and monitoring for several diseases. In this work, a green wearable sensor for sweat absorption and chloride sensing is presented. In order to produce a sustainable device, polylactic acid (PLA) was used for both the substrate and the sweat absorption pad fabrication. The sensor material for chloride detection consisted of silver-based reference, working, and counter electrodes obtained from upcycled compact discs. The PLA substrates were prepared by thermal bonding of PLA sheets obtained via a flat die extruder, prototyped in single functional layers via CO2 laser cutting, and bonded via hot-press. The effect of co…

Effect of the dissolution time into an acid hydrolytic solvent to tailor electrospun nanofibrous polycaprolactone scaffolds

2017

[EN] The hydrolysis of the polycaprolactone (PCL) as a function of the dissolution time in a formic/acetic acid mixture was considered as a method for tailoring the morphology of nanofibrous PCL scaffolds. Hence the aim of this research was to establish a correlation between the dissolution time of the polymer in the acid solvent with the physicochemical properties of the electrospun nanofibrous scaffolds and their further service life behaviour. The physico-chemical properties of the scaffolds were assessed in terms of fibre morphology molar mass and thermal behaviour. A reduction of the molar mass and the lamellar thickness as well as an increase of the crystallinity degree were observed …

Analisi della frequenza cardiaca e della concentrazione di lattato ematico in soggetti sovrappeso allenati con uno specifico protocollo di spinning.

2006

Spectroscopic and conformational properties of size-fractions separated from a lignite humic acid

2007

Abstract A lignite humic acid (HA) was fractionated by preparative high performance size-exclusion chromatography (HPSEC) in seven different size-fractions. The size-fractions were characterized by cross polarization (CP) magic angle spinning (MAS) 13 C NMR spectroscopy and a further analytical HPSEC elution under UV and fluorescence detection. The alkyl hydrophobic components mainly distributed in the largest molecular-size-fraction, whereas the amount of oxidized carbons increased with decreasing size of fractions. Cross polarization time ( T CH ) and proton spin-lattice relaxation time in the rotating frame ( T 1 ρ (H)) were measured from variable contact time (VCT) experiments. The bulk…

High Speed Stereovision Setup for Position and Motion Estimation of Fertilizer Particles Leaving a Centrifugal Spreader

2014

EA SPE GEAPSI; International audience; A 3D imaging technique using a high speed binocular stereovision system was developed in combination with corresponding image processing algorithms for accurate determination of the parameters of particles leaving the spinning disks of centrifugal fertilizer spreaders. Validation of the stereo-matching algorithm using a virtual 3D stereovision simulator indicated an error of less than 2 pixels for 90% of the particles. The setup was validated using the cylindrical spread pattern of an experimental spreader. A 2D correlation coefficient of 90% and a Relative Error of 27% was found between the experimental results and the (simulated) spread pattern obtai…

A Straightforward Approach to Multifunctional Graphene

2019

Graphene has been covalently functionalized through a one-pot reductive pathway using graphite intercalation compounds (GICs), in particular KC8 , with three different orthogonally protected derivatives of 4-aminobenzylamine. This novel multifunctional platform exhibits excellent bulk functionalization homogeneity (Hbulk ) and degree of addition while preserving the chemical functionalities of the organic addends through different protecting groups, namely: tert-butyloxycarbonyl (Boc), benzyloxycarbonyl (Cbz) and phthalimide (Pht). We have employed (temperature-dependent) statistical Raman spectroscopy (SRS), X-ray photoelectron spectroscopy (XPS), magic angle spinning solid state 13 C NMR …

Proton Conducting Electrospun Sulfonated Polyether Ether Ketone-Graphene Oxide Composite Membranes

2017

[EN] A series of novel composite membranes, based on sulfonated poly(ether ketone) (SPEEK) with a graphene oxide (GO) layer, were prepared. One contained a GO layer sandwiched between the SPEEK-polyvinyl alcohol (PVA) matrix (SPEEK/PVA@GO), and another deposited thin layers of GO on the nanofibers of SPEEK-polyvinyl butyral (PVB), with both sandwiched in the phase matrix of SPEEK-PVA (SPEEK/PVA@GO-NF). Various nanofiber thicknesses were studied by varying the electrospinning time. The prepared composite membranes with different nanofiber thicknesses were characterized by scanning electron microscopy, water uptake, ionic exchange capacity, thermogravimetric analysis, mechanical properties an…

Understanding the physicochemical properties of olive kernel to be used as a potential tool in the development of phenol-formaldehyde wood adhesive

2015

Abstract During olive oil production process, a great number of by-products are generated, including olive kernel. These by-products can be used for the development of new products for use in many different industrial applications. The evaluation of the physicochemical properties of these by-products constitutes a key factor in evaluating the potential reutilization of olive oil by-products. In the present study, the physicochemical properties of olive kernel were analyzed. Fourier transform infrared spectroscopy (FT-IR), cross-polarization magic angle spinning 13 C nuclear magnetic resonance (CP/MAS 13 C NMR), Brunauer, Emmett and Teller (BET), scanning electron microscopy (SEM) and thermo…

Nexus of Electrospun Nanofibers and Additive Processing—Overview of Wearable Tactical Gears for CBRNE Defense

2021

Due to complex nature of twenty-first century battlefield, soldiers must perform multiple tasks to protect nations while maintaining their own safety. Advances in technological innovations are critical to support such functionalities to enhance safety and security. Using nexus of electrospinning and additive processing, we present how recent developments can be used to produce new generation of protective fabrics with integrative force protection, sensing/detection of chemical, biological, radiological, nuclear, and high yield explosives (CBRNE), and biomedical functionalities. Although electrospinning has been in use for some time, the special blends and configurations of nanofibers, as de…

Electrospun Poly(ethylene-co-vinyl alcohol)/Graphene Nanoplatelets Composites of Interest in Intelligent Food Packaging Applications

2018

Graphene nanoplatelets (GNPs) were synthetized from graphite powder and, thereafter, embedded in poly(ethylene-co-vinyl alcohol) (EVOH) fibers by electrospinning in the 0.1&ndash