Search results for "Stack"
showing 10 items of 392 documents
Ionic shortcut currents via manifolds in reverse electrodialysis stacks
2020
Abstract Reverse electrodialysis (RED) is a blue energy technology for clean and sustainable electricity harvesting from the mixing entropy of salinity gradients. Recently, many efforts have been devoted to improving the performance of RED units by developing new ion-exchange membranes and by reducing the detrimental phenomena affecting the process. Among these sources of “irreversibility”, the shortcut currents (or parasitic currents) flowing through alternative pathways may affect the process efficiency. Although such phenomena occur in several electrochemical processes (e.g. fuel cells, bipolar plate cells and vanadium redox flow batteries), they have received a poor attention in RED uni…
Lab-scale experiments on a novel acid/base electrodialytic flow battery with bipolar membranes
2021
Electrical energy storage has a key role in the development and diffusion of renewable energy technologies. The Acid/Base Flow Battery is an innovative process to store electrical energy in the form of pH and salinity gradients via electrodialytic reversible techniques based on the use of bipolar membranes. During the charge phase, the unit produces acid and alkaline solutions by applying an electric field, during the discharge phase, converts the pH gradient into electrical energy. In this work, several experimental tests were performed in a 10×10 cm2 laboratory-scale unit fed with HCl, NaOH and NaCl solutions, in order to characterize the battery and assess its performance. The effect of …
CFD analysis of the fluid flow behavior in a reverse electrodialysis stack
2012
Salinity Gradient Power by Reverse Electrodialysis (SGP-RE) technology allows the production of electricity from the different chemical potentials of two differently concentrated salty solutions flowing in alternate channels suitably separated by selective ion exchange membranes. In SGP-RE, as well as in conventional ElectroDialysis (ED) technology, the process performance dramatically depends on the stack geometry and the internal fluid dynamics conditions: optimizing the system geometry in order to guarantee lower pressure drops (DP) and uniform flow rates distribution within the channels is a topic of primary importance. Although literature studies on Computational Fluid Dynamics (CFD) a…
A Semantic Similarity Measure for the SIMS Framework
2008
The amount of currently available digital information grows rapidly. Relevant information is often spread over different information sources. An efficient and flexible framework to allow users to satisfy ef- fectively their information needs is required. The work presented in this paper describes SIMS (Semantic Information Management System), a ref- erence architecture for a framework performing semantic annotation, search and retrieval of information from multiple sources. The work pre- sented in this paper focuses on a specific SIMS module, the SIMS Semantic Content Navigator, proposing an algorithm and the related implementa- tion to calculate a semantic similarity measure inside an OWL …
Peeling of multilayer graphene creates complex interlayer sliding patterns
2015
Peeling, shearing, and sliding are important mechanical phenomena in van der Waals solids. However, theoretically they have been studied mostly using minimal periodic cells and in the context of accurate quantum simulations. Here, we investigate the peeling of large-scale multilayer graphene stacks with varying thicknesses, stackings, and peeling directions by using classical molecular dynamics simulations with a registry-dependent interlayer potential. Simulations show that, while at large scale the peeling proceeds smoothly, at small scale the registry shifts and sliding patterns of the layers are unexpectedly intricate and depend both on the initial stacking and on the peeling direction.…
Performance Analysis of Cooperative V2V and V2I Communications Under Correlated Fading
2019
Cooperative vehicular networks will play a vital role in the coming years to implement various intelligent transportation-related applications. Both vehicle-to-vehicle (V2V) and vehicle-to-infrastructure (V2I) communications will be needed to reliably disseminate information in a vehicular network. In this regard, a roadside unit (RSU) equipped with multiple antennas can improve the network capacity. While the traditional approaches assume antennas to experience independent fading, we consider a more practical uplink scenario where antennas at the RSU experience correlated fading. In particular, we evaluate the packet error probability for two renowned antenna correlation models, i.e., cons…
Sputtered SiOxNy thin films: improving optical efficiency of liquid crystal diffuser elements in multi-focal near-to-eye display architecture
2021
In this work we present reactive sputtered SiOxNy films with a variable refractive index as a convienent solution for contrast improvement of liquid crystal diffuser multi stacks in near-to-eye AR/VR displays. The focus concerns minimization of light reflections between internal structures, in particular ITO, by optimizing internal layers through tailored properties of thin film coatings, as well as subsequent laser patterning of thin film stack. Inorganic thin films have been deposited on glass by physical vapor deposition. Corresponding refractive index, thickness, uniformity and dielectric characteristics and other electro-optical properties have been measured and their impact on the res…
Controlled Self-Assembly of Electron Donor Nanotubes
2009
We employ a combination of urea-urea hydrogen bonds and pi-pi stacking interactions to obtain soluble self-assembled nanotubes decorated with electron-donor TTF derivatives on the periphery. We have investigated the structure and stability of the nanotubes with a combination of experiments and high-level DFT calculations. We also demonstrate that the association process can be controlled by changes in the hydrogen-bonding ability of the solvent and electrochemically.
Integration of Spatial processing and knowledge Processing through the Semantic Web Stack
2011
International audience; This paper presents the integration process of spatial technologies and Semantic Web technologies and its associated tool. The result of this work is a spatial query and rule engine of spatial. To do so, existing ontology with spatial elements is adjusted in order to process the spatial knowledge through spatial technologies. This paper outlines the methods and the processes of these adjustments and how results are returned by our tool. The SWRL and the SPARQL language are extended for spatial purpose and the existing OWL ontology wine is used as an application example.
The Use of Polyoxometalates in the Design of Layer‐Like Hybrid Salts Containing Cationic Mn 4 Single‐Molecule Magnets
2013
Herein, we describe the combination of polyoxometalates (POMs) with a polynuclear metallic cluster Mn4 {Mn4 = [Mn4(OAc)2(pdmH)6]2+, (pdmH = deprotonated pyridine-2,6-dimethanol; C7H8NO2)} for the construction of ionic crystals with layered architectures. Choosing a POM with the appropriate charge and size not only allows for the fine tuning of the stacking periodicity, but it also allows modifying the in-plane packing motif and density of the cationic metallic clusters. The isolation of differently layered hybrid crystals with the same Mn4 single-molecule-magnet (SMM) system allowed for the direct comparison of the magnetic properties of such materials. The variation of the slow relaxation …