Search results for "Surfaces and interfaces"
showing 10 items of 939 documents
Determining the optical properties of adsorbate covered surfaces by dichroism in VUV-photoemission
1999
The dichroic effects of photoemission excited by polarised light depend on the angle of photon incidence. Measurements of the difference in the angle-resolved photoemission intensities from Cs 5p semi-corelevels excited by photons of opposite helicity, or of orthogonal linear polarisation are reported. It was thought that the dependence of dichroism on the angle of incidence cannot be described using equations omitting metal optics. A complete consideration of the vector potential of the exciting light is needed, including the phase shift between it's parallel and perpendicular components. The phase shift is produced by the complex index of refraction. Using the Fresnel equations for struct…
AN EXPERIMENTAL PROOF OF THE BACK-SCATTERING MODEL FOR DICHROIC EFFECTS IN VUV PHOTOEMISSION
2002
The energy dependence of the circular dichroism in the angular distribution of photoelectrons (CDAD) was investigated from the shallow Cs 5p core levels. Cesium was prepared in a hexagonal ordered monolayer on W(110). The results are mainly influenced by scattering of the photoelectrons within the adlayer. At low energies, the behavior observed is described by means of a model that treats only the back-scattering of photoelectrons at the potential step between the adlayer and the substrate. It leads to a simple method determining the position of the monolayer with respect to the substrate. In this approach, the back-scattering model is matched with the measured energy dependence of the CDA…
ORMOSIL thin films: Tuning mechanical properties via a nanochemistry approach
2006
The mechanical properties (hardness and elastic modulus) of organically modified silicate thin films can be finely tuned by varying the degree of alkylation and thus the fraction of six- and four-membered siloxane rings in the organosilica matrix. This opens the way to large tunability of parameters that are of crucial practical importance for films that are finding increasing application in numerous fields ranging from microelectronics to chemical sensing.
The linguistic representation of gender violence in (written) media discourse
2014
‘Woman’ is a key social actor, and a central conceptualization, in the construction of media discourses of gender-based violence. Scholarly research at the turn of the 21st century (Bengoechea 2000; Lledó 2002; Fernández Díaz 2003; Jorge 2004) showed that in the Spanish press, media discourses had a tendency to naturalize male aggression not as violence but as part of the (private) sexual arrangement between the sexes. In this paper we explore the treatment of the phrasemujer maltratada(EN ‘battered woman’) in intimate partner violence newspaper articles from 2005 to 2010. Our aims are: (i) to account for the discursive representation of violence against women (VAW) in Spanish contemporary …
Atomic physics of positronium with intense slow positron beams
2002
Abstract The theory of quantum electrodynamics has presented a complete calculation of the energy levels of positronium (Ps, e + e − ) up to the order R ∞ α 4 . The annihilation rates for para -Ps (1 1 S 0 ) and ortho -Ps (1 1 S 1 ) are completely known up to the order R ∞ α 5 and R ∞ α 6 , respectively. The present experimental uncertainty for spectroscopic results is 5–100 times larger than the theoretical uncertainty. For the annihilation rates the experimental situation is even worse. The theoretical predictions have presently reached a level of precision which is a challenge to experimentalists! The experimental uncertainty for the fine- and hyperfine transitions in the Ps atom is dete…
Attractive ion-ion correlation forces and the dielectric approximation.
2016
We analyze the classical problem of the interaction between two charged surfaces separated by a solution containing neutralizing counter-ions. The focus is on obtaining a description where the solvent is treated explicitly rather than through a dielectric approximation as is conventionally done. We summarize the results of three papers where we have used a Stockmayer fluid model in Monte Carlo simulations. It is shown that the attractive ion-ion correlation mechanism is also operating when the solvent is described explicitly. There appears an oscillatory component to the force, but when this is accounted for, there is a semi-quantitative agreement between the continuum model and the model w…
Gaussian quantum dots of type II in in-plane electric field
2007
The growing interest is recently focusing on QDs of type II, which contrary to type I QDs attract electrons and repulse holes (or conversely). In such QDs an electron-hole pair (Xexciton) can still be traped due to electron-hole Coulomb attraction, resulting in significantly more complex structure of excitonic states. We consider an X exciton in QD of type II defined by electrostatic focusing in a narrow quantum well, in the presence of additional external in-plane electric field. The dependence of PL spectrum on dot size and in-plane electric field is analysed within the Hartree approach for model planar Gaussian confinement. The exciton ground state and its energy red-shift are found as a…
Laser action in electrically driven quantum dot matrix
2007
A lasing system based on electrically driven quantum dot matrix is proposed, where population inversion of the dot matrix is obtained by rapid (nonadiabatic) switching on of in-plane electric field as a pumping force. Numerical analysis of electron-photon system kinetics is performed for various electric fields and temperatures. For parabolic type of confinement in QDs, a convenient amplification of contribution from several levels is indicated. The relevant analysis utilises an exact solution of Cauchy problem for an infinite chain of linear differential equations.
Orbital origin and matrix element effects in the Ag/Si(111)-()R30° Fermi surface
2007
The Fermi surface (FS) of the Ag/Si(1 1 1)-3×3 reconstruction with an excess of Ag has been mapped by angle resolved photoemission spectroscopy with polarized light in a wide region of the reciprocal space and with different detection geometries. In contrast to previous results, a strong polarization dependence is observed. Applying the dipole selection rules, it is found that the surface state at the Fermi level, S1 state, has odd symmetry with respect to the mirror plane of the honeycomb-chained triangle structure, indicating that it is mainly derived from Ag 5px and 5py orbitals. This conclusion is revised in the new frame of a inequivalent-triangle structure for the Ag/Si(1 1 1)-3×3 at …
Properties of the Ising magnet confined in a corner geometry
2007
Abstract The properties of Ising square lattices with nearest neighbor ferromagnetic exchange confined in a corner geometry, are studied by means of Monte Carlo simulations. Free boundary conditions at which boundary magnetic fields ± h are applied, i.e., at the two boundary rows ending at the lower left corner a field + h acts, while at the two boundary rows ending at the upper right corner a field − h acts. For temperatures T less than the critical temperature T c of the bulk, this boundary condition leads to the formation of two domains with opposite orientation of the magnetization direction, separated by an interface which for T larger than the filling transition temperature T f ( h ) …