Search results for "Surfaces"
showing 10 items of 2837 documents
Novel constant current driver for ISFET/MEMFETs characterization
2001
Abstract In the present work a new constant current driver for ISFETs and MEMFETs sensors has been developed. The proposed circuit maintains the ISFET/MEMFET operation point at constant drain–source current and voltage. The combination of some programmable current sources and an appropriate selection of a simple precision resistor allow a good ISFET/MEMFET polarization. The use of operational amplifiers with low offset and drift are required to provide the buffering function needed by the sensor.
Theory of mercury intrusion in a distribution of unconnected wedge-shaped slits
2004
Effective mercury intrusion in a wedge-shaped slit is gradual, the intruded depth increasing with applied pressure. The Washburn equation must be modified accordingly. It relates the distance, e, separating the three-phase contact lines on the wedge faces to the hydrostatic pressure, P, wedge half-opening angle alpha, mercury surface tension gamma, and contact angle theta: e=(-2gamma/P)cos(theta-alpha) if theta-alpha>pi2. The equations relating the volume of mercury in a single slit to hydrostatic pressure are established. The total volume of mercury V(Hg)(tot)(E(0),e) intruded in a set of unconnected isomorphous slits (same alpha value) with opening width, E, distributed over interval [E(0…
Pattern image enhancement by extended depth of field
2014
Abstract Most optical defect localization techniques such as dynamic laser stimulation or photon emission microscopy require a pattern image of the device to be taken. The main purpose is for device navigation, but it also enables the analyst to identify the location of the monitored activity by superimposing it onto the pattern image. The defect localization workflow usually starts at low or medium magnification. At these scales, several factors can lead to a lack of orthogonality of the sample with the optical axis of the system. Therefore, images can be locally out of focus and poorly resolved. In this paper, a method based on Depth of Field Extension is suggested to correct the pattern …
Density Functional Theory Investigation on the Nucleation and Growth of Small Palladium Clusters on a Hyper-Cross-Linked Polystyrene Matrix
2014
Density functional theory calculations were employed to investigate the nucleation and growth of small palladium clusters, up to Pd9, into a microcavity of the porous hyper-cross-linked polystyrene (HPS). The geometries and the electronic structures of the palladium clusters inside the HPS cavity, following the one-by-one atom addition, are affected by a counterbalance between the Pd–phenyl (Pd−Φ) and Pd–Pd interactions. The analysis performed on energetics, cavity distortions, and cluster geometries indeed suggest that the cluster growth is dominated by the Pd−Φ interactions up to the formation of Pd4 aggregates, whereas the metal–metal interactions actually rule the growth of the larger c…
A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification
2017
International audience; A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.
Coordination chemistry on surfaces through vapor phase processing: smart molecular/graphene heterostructures based on spin-crossover complexes and 2D…
2023
Los compuestos de coordinación están últimamente focalizando la atención de los investigadores en el campo de la nanociencia. Particular interés están generando aquellos compuestos con propiedades magnéticas de cara a su integración a la nanoescala en ramas como la electrónica y/o la espintrónica moleculares. Sin embargo, para su uso real en dispositivos destinados a estas aplicaciones, su procesabilidad es un requisito indispensable. En el marco de esta necesidad, la presente tesis doctoral se ha destinado al estudio del procesado sobre superficies mediante técnicas de fase gas de dos tipos distintos de compuestos de coordinación. Por tanto, el trabajo se ha dividido en dos partes. La prim…
Inhibitoren der Korrosion 27 (1). Inhibitoren der Korrosion von Kupfer - Gibt es eine Struktur-Wirkungsbeziehung?
1982
Mehr als 570 Verbindungen der unterschiedlichsten Struktur wurden unter Standardbedingungen im “Schuttelversuch” und pH-statisch auf ihre Korrosionsschutzwirkung gegenuber Kupfer getestet und mit Hilfe eines Computers ausgewertet. Die erhaltenen Ergebnisse stehen relativ haufig in Ubereinstimmung mit Dem “Hart-Weich-Konzept” von Pearson. Eine gezielte Synthese von Inhibitoren, die sich in diesem Konzept orientiert, ist jedoch nicht moglich. Inhibitors of corrosion 27 (1). Inhibitors of the corrosion of copper Does there exist a structure-effect-relation? Over 570 compounds of greatly varying structure have been tested under controlled conditions in agitation and pH-stat experiments designed…
Retracted Article: Differential detection and quantification of cyclic AMP and other adenosine phosphates in live cells
2017
A new naphthol-based rhodamine derivative (NpRD) has been developed for the selective and differential detection of adenosine 3′,5′-cyclic monophosphate (cAMP) and adenosine phosphates (APs) (ATP, ADP, and AMP) from other nucleotides. The simple detection and quantification of cAMP in human blood cells and in other samples based on the ‘turn on’ fluorescence properties of this chemosensor through colorimetry or fluorometry makes it unique for probable application in high throughput screening.
Self-assembly of an iron(ii)-based M5L6 metallosupramolecular cage
2011
A pentanuclear M(5)L(6) coordination cage is self-assembled in solution from a rigid linear heteroditopic phen-tpy ligand and an iron (II) salt.
Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautif…
2019
In this Feature Article, we highlight the feasibility of a new, recently developed approach towards the synthesis of high-spin molecules and single-molecule magnets (SMMs). The key to the preparation of such molecular compounds is the organic azide precursor Me3SiN3, which fosters the formation of 3d-metal azido clusters and coordination polymers without requiring the assistance of any organic chelating/bridging group. All the isolated compounds contain metallic cores which are surrounded by end-on bridging N3− groups. Consequently, the reported molecular materials exhibit ferromagnetic exchange interactions between the spin carriers, resulting in the stabilization of the maximum possible s…