Search results for "Syngas"
showing 10 items of 14 documents
New waves underneath the purple strain.
2016
Summary Successful merging of chemical and biotechnological operations is essential to achieve cost‐efficient industrialization of bio‐based processes. The demonstration of the use of syngas, derived from microwave assisted pyrolysis of municipal solid waste, for the improved growth and poly‐3‐hydroxybutyrate production in Rhodospirillium rubrum, stands out as an example of the synergistic contribution of chemical engineering and applied microbiology to sustainable biomaterial manufacturing, paving the way to similar applications for other syngas derived bioproducts.
The influence of water and of alkali promotor on the carbon number distribution of fischer-tropsch products formed over iron catalysts
1987
The carbon number distribution of Fischer-Tropsch products formed over an alkalized precipitated iron catalyst has been studied as a function of the water vapor pressure of the synthesis gas. The carbon number distribution of formed hydrocarbons is characterized by a bimodal Schulz-Flory distribution of growth probabilities P1 ≈ 0.6 and P2 ≈ 0.87 attributed to unpromoted and promoted (alkalized) sites on the catalyst surface. Promoted sites are more stable with respect to oxidation (deactivation) by water than unpromoted sites. The growth probability of unpromoted sites decreases with increasing ratio P/P — Studies using Mossbauer spectroscopy have shown that iron foils treated with water c…
Numerical and Experimental Investigation of Equivalence Ratio (ER) and Feedstock Particle Size on Birchwood Gasification
2017
This paper discusses the characteristics of Birchwood gasification using the simulated results of a Computational Fluid Dynamics (CFD) model. The CFD model is developed and validated with the experimental results obtained with the fixed bed downdraft gasifier available at the University of Agder (UIA), Norway. In this work, several parameters are examined and given importance, such as producer gas yield, syngas composition, lower heating value (LHV), and cold gas efficiency (CGE) of the syngas. The behavior of the parameters mentioned above is examined by varying the biomass particle size. The diameters of the two biomass particles are 11.5 mm and 9.18 mm. All the parameters investigate wit…
Development of net energy ratio and emission factor for quad-generation pathways
2014
Published version of an article in the journal: Energy Systems. Also available from the publisher at: http://dx.doi.org/10.1007/s12667-014-0126-4 The conversion of biomass to four different outputs via gasification is a renewable technology that could reduce the use of fossil fuels and greenhouse gas (GHG) emissions. This study investigates the energy aspects for a new concept of biomass based quad-generation plant producing power, heat, methanol and methane. Circulating fluidized bed gasifier and the gas technology institute (GTI) gasifier technologies are used for this quad-generation process. Two different biomass feedstocks are considered in this study. The net energy ratio for six diff…
Future district heating plant integrated with municipal solid waste (MSW) gasification for hydrogen production
2019
Abstract Characterizing municipal solid waste (MSW) is a critical step in planning, designing, operating, or upgrading solid waste management systems. For a theoretical investigation of hydrogen production by gasification and water-gas shift reaction, we characterized Norwegian MSW and used the data. Three different gasification setups, named as ‘A-1’, ‘A&S-2’, and ‘S-3’ were modeled using Aspen plus simulation software for direct and indirect gasification processes according to the different gasification agents. The MSW characterization result showed a reasonable agreement with existing studies in different countries. The maximum hydrogen yield achieved in setup ‘S-3’ was around 94% of the…
Analisi di inventario di un sistema di valorizzazione energetica di biomasse residuali di origine forestale in un’ottica di ciclo di vita
2021
Il presente lavoro descrive i risultati dell’analisi di inventario di un impianto integrato “gassificatore – cogeneratore” impiegato per la valorizzazione energetica di biomasse residuali di origine forestale, in un’ottica di ciclo di vita. Il sistema gassificatore – cogeneratore è un prototipo realizzato presso il laboratorio di Bioenergia e Biocombustibili dell’Università di Bolzano. L’impianto è costituito da un gassificatore down-draft e un cogeneratore con motore diesel dual – fuel e una potenza elettrica di 3 kW. L’analisi di inventario è stata sviluppata in accordo agli standard della serie ISO 14040. L’unità funzionale (UF) è 1 kWh di energia elettrica immessa in rete. I confini del…
PBI mixed matrix hollow fiber membrane: Influence of ZIF-8 filler over H2/CO2 separation performance at high temperature and pressure
2020
High performance and commercially attractive mixed-matrix membranes were developed for H2/CO2 separation via a scalable hollow fiber spinning process. Thin (~300 nm) and defect-free selective layers were successfully created with a uniform distribution of the nanosized (~60 nm) zeolitic-imidazole framework (ZIF-8) filler within the polymer (polybenzimidazole, PBI) matrix. These membranes were able to operate at high temperature (150 °C) and pressure (up to 30 bar) process conditions required in treatment of pre-combustion and syngas process gas streams. Compared with neat PBI hollow fibers, filler incorporation into the polymer matrix leads to a strong increase in H2 permeance from 65 GPU t…
Development of an Electrochemical Process for the Simultaneous Treatment of Wastewater and the Conversion of Carbon Dioxide to Higher Value Products
2016
Many researchers have shown that selected anodic processes allow effective treatment of a very large amount of wastewater contaminated by pollutants resistant to biological processes. In the meantime, various authors have also shown that carbon dioxide can be converted into higher value products, such as formic acid or synthesis gas, by cathodic reduction at suitable cathodes. These two processes present interesting economic potential that, however, still needs to be improved for further development at an industrial level. Herein, these two kinds of process are combined in the same cell to improve their economic feasibility. In particular, the anodic treatment of wastewater at a boron-doped…
High-pressure synthesis of CO and syngas from CO2 reduction using Ni-N-doped porous carbon electrocatalyst
2022
Abstract Electrochemical conversion of CO2 to CO or syngas (CO/H2 mixture) is considered one of the most promising approaches to valorise waste-CO2. To develop the process on industrial scale, it would be necessary to use selective and inexpensive electrodes and to obtain high productivities with low energy consumption. In this frame, Ni−NC catalysts are considered among the most interesting ones because of their relatively low cost, high faradaic efficiency in CO ( F E C O ), and high stability. However, up to now, quite low productivities were obtained as a result of low current densities achieved in aqueous electrolytes. In this work, we have evaluated the performances of a Ni−NC electro…
The role of nano-sized iron particles in slurry phase Fischer–Tropsch synthesis
2003
Abstract The slurry phase Fischer–Tropsch (F–T) activity of three α-Fe2O3-based materials, two unsupported nano-sized, NANOCAT (3 nm) and BASF (20–80 nm), and a supported micron-sized (32.5 μm ) UCI, are compared with respect to total hydrocarbon production from synthesis gas (H2/CO∼2/1) at 513 K. Low temperature Mossbauer spectra of the quenched slurry samples after 120 h on-line show that all three catalysts are essentially a mixture of oxide and carbide phases with magnetite (Fe3O4) being the dominant phase. TEM images of the quenched samples reveal unexpected particle characteristics. While both unsupported nano-sized materials essentially avoid expected agglomeration, the micron-sized …