Search results for "TENS"

showing 10 items of 12157 documents

Dual role of silver in a fluorogenic N-squaraine probe based on Ag(i)–π interactions

2021

In the presence of Ag(I), the monoanion of cyano-N-squaraine (I) generates an intense fluorescence turn-on response. Experimental evidence and DFT calculations reveal a sequence of deprotonation-coordination events in which the Ag(I) ions play a dual role as a Lewis acid and coordinating metal. The observed effect is highly selective for Ag(I) compared to other metals.

010405 organic chemistryChemistry010402 general chemistryHighly selective01 natural sciences0104 chemical sciencesIonInorganic ChemistryMetalCrystallographyDual rolevisual_artIntense fluorescencevisual_art.visual_art_mediumLewis acids and basesSequence (medicine)Dalton Transactions
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Diabetes and renin-angiotensin-aldosterone system: Implications for covid-19 patients with diabetes treatment management

2020

In the context of the COVID-19 continuous spreading, this paper focuses on the increased risk of diabetic patients regarding the metabolic control and the uncertainties related to SARS-CoV-2 infection. Chronic hyperglycaemia negatively affects the immune system, which triggers an increase of morbidity and mortality for viral infections. A key aspect of COVID-19 resides in the involvement of renin-angiotensin-aldosterone (RAAS) system that causes a cascade of reactions mediated by vasoactive peptides with implications in vasoconstriction, vascular permeability, oxidative stress remodelling and tissue injuries. Activation of RAAS at pulmonary level, is responsible for the local damage. Many q…

010405 organic chemistrybusiness.industry030209 endocrinology & metabolismContext (language use)Vascular permeabilityACEi ARBs COVID-19 Diabetes Of renin-angiotensin-aldosterone system RAAS SARS-CoV-2medicine.diseasemedicine.disease_causeBioinformatics01 natural sciences0104 chemical sciences03 medical and health sciences0302 clinical medicineImmune systemMetabolic control analysisDiabetes mellitusRenin–angiotensin systemmedicineGeneral Pharmacology Toxicology and Pharmaceuticsmedicine.symptombusinessVasoconstrictionOxidative stress
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The high-resolution far-infrared spectrum of methane at the SOLEIL synchrotron

2010

International audience; As a tetrahedral molecule, methane has no permanent dipole moment. Its spectrum, however, displays faint absorption lines in the THz region, due to centrifugal distorsion effects. This is important for planetary applications since this region is used to measure methane concentration in some planetary atmospheres, in particular on Titan. Up to now, all measurements relied either on some old low resolution infrared absorption spectra, or on high resolution Stark measurements for low J values only. Even if these results have been reexamined recently [E. H. Wishnow, G. S. Orton, I. Ozier and H. P. Gush, J. Quant. Spectrosc. Radiat. Transfer 103, 102-117 (2007)], it seeme…

010504 meteorology & atmospheric sciencesAbsorption spectroscopyAnalytical chemistrySynchrotron radiationFar infrared7. Clean energy01 natural sciencesSpectral linelaw.inventionOpticsFar infraredlaw0103 physical sciencesAbsorption (logic)010303 astronomy & astrophysicsSpectroscopy0105 earth and related environmental sciencesPhysicsRadiationSynchrotron radiationbusiness.industryResolution (electron density)BremsstrahlungAtomic and Molecular Physics and OpticsSynchrotron[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry13. Climate action[ CHIM.THEO ] Chemical Sciences/Theoretical and/or physical chemistrybusinessTitanMethaneLine intensities
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Potential impacts of a future Nordic bioeconomy on surface water quality

2020

AbstractNordic water bodies face multiple stressors due to human activities, generating diffuse loading and climate change. The ‘green shift’ towards a bio-based economy poses new demands and increased pressure on the environment. Bioeconomy-related pressures consist primarily of more intensive land management to maximise production of biomass. These activities can add considerable nutrient and sediment loads to receiving waters, posing a threat to ecosystem services and good ecological status of surface waters. The potential threats of climate change and the ‘green shift’ highlight the need for improved understanding of catchment-scale water and element fluxes. Here, we assess possible bio…

010504 meteorology & atmospheric sciencesClimate ChangeVDP::Landbruks- og Fiskerifag: 900::Landbruksfag: 910Geography Planning and DevelopmentLand managementClimate changemaankäyttö010501 environmental sciences01 natural sciencesEnvironmental Effects of a Green Bio-EconomyEcosystem servicesVDP::Matematikk og Naturvitenskap: 400::Zoologiske og botaniske fag: 480::Økologi: 488Environmental ChemistryProduction (economics)Humans14. Life underwaterVDP::Landbruks- og Fiskerifag: 900::Fiskerifag: 920Ecosystem0105 earth and related environmental sciences2. Zero hungerBiomass (ecology)EcologyLand usebusiness.industryEnvironmental resource managementSurface waterGeneral Medicine15. Life on landModels TheoreticalvedenlaatuBioeconomy6. Clean waterWater qualitypintavesi13. Climate actionLand useEnvironmental scienceWater qualitybusinessbiotalousSurface waterForecasting
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Effects of natural radiation damage on back-scattered electron images of single crystals of minerals

2006

Generally, it has been assumed that signal intensity variations in back-scattered electron (BSE) images of minerals are mainly controlled by chemical heterogeneity. This is especially true for images of single crystals, where effects of different crystal orientations with respect to the incident beam on the observed BSE are excluded. In contrast, we show that local variations of the structural state within single-crystals (i.e., degree of lattice order or lattice imperfectness) may also have dramatic effects on the back-scattering of electrons. As an example, we present BSE images of single-crystals of natural zircon, ZrSiO 4 , whose intensity patterns are predominantly controlled by struct…

010504 meteorology & atmospheric sciencesCondensed matter physicsChemistryMineralogyElectron010502 geochemistry & geophysics01 natural sciencesStructural heterogeneityCrystalGeophysicsGeochemistry and PetrologyRadiation damageIncident beamSignal intensity0105 earth and related environmental sciencesZirconChemical heterogeneityAmerican Mineralogist
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Comment on “Rill erosion processes on steep colluvial deposit slope under heavy rainfall in flume experiments with artificial rain by F. Jiang et al.”

2020

Abstract Since rill flows are characterized by small water depths and steeply sloping channels, the corresponding hydraulic conditions are very different to those which are typically found in channels of streams and rivers. Furthermore, limited information is currently available on the effect of rainfall on flow resistance. The objective of this comment was to investigate the applicability of a recently theoretically deduced rill flow resistance equation, based on a power-velocity profile, using measurements carried out by Jiang et al. for both different slope steepness conditions and rainfall intensity. The relationship between the velocity profile parameter Γ, the channel slope and the fl…

010504 meteorology & atmospheric sciencesFlow (psychology)Soil scienceSTREAMSRill erosion01 natural sciencessymbols.namesakeRill velocityDarcy-Weisbach friction factorFroude number0105 earth and related environmental sciencesEarth-Surface ProcessesColluviumgeographyRill erosiongeography.geographical_feature_categoryRainfall impact04 agricultural and veterinary sciencesRillFlumeFlow resistance040103 agronomy & agriculturesymbols0401 agriculture forestry and fisheriesIntensity (heat transfer)Geology
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Testing a theoretical resistance law for overland flow on a stony hillslope

2020

Overland flow, sediments, and nutrients transported in runoff are important processes involved in soil erosion and water pollution. Modelling transport of sediments and chemicals requires accurate estimates of hydraulic resistance, which is one of the key variables characterizing runoff water depth and velocity. In this paper, a new theoretical power–velocity profile, originally deduced neglecting the impact effect of rainfall, was initially modified for taking into account the effect of rainfall intensity. Then a theoretical flow resistance law was obtained by integration of the new flow velocity distribution. This flow resistance law was tested using field measurements by Nearing for the …

010504 meteorology & atmospheric sciencesFlow (psychology)rainfall0207 environmental engineering02 engineering and technology01 natural sciencessymbols.namesakeWetted perimeteroverland flowdimensional analysiFroude numberSettore AGR/08 - Idraulica Agraria E Sistemazioni Idraulico-Forestali020701 environmental engineering0105 earth and related environmental sciencesWater Science and Technologyself-similarityReynolds numberLaminar flowstony hillslopeFlow velocityLawsymbolsvelocity profileEnvironmental scienceSurface runoffflow resistanceIntensity (heat transfer)
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Collapse of a two-dimensional brittle granular column: Implications for understanding dynamic rock fragmentation in a landslide

2015

We investigate numerically the failure, collapse and flow of a two-dimensional brittle granular column over a horizontal surface. In our discrete element simulations, we consider a vertical monolayer of spherical particles that are initially held together by tensile bonds, which can be irreversibly broken during the collapse. This leads to dynamic fragmentation within the material during the flow. Compared to what happens in the case of a non-cohesive granular column, the deposit is much rougher, and the internal stratigraphic structure of the column is not preserved during the collapse. As has been observed in natural rockslides, we find that the deposit consists of large blocks laying on …

010504 meteorology & atmospheric sciencesGeometryLandslideRockslide01 natural sciences010305 fluids & plasmasEarth surfaceGeophysicsBrittlenessFragmentation (mass spectrometry)0103 physical sciencesMonolayerUltimate tensile strengthGeotechnical engineeringGeology0105 earth and related environmental sciencesEarth-Surface ProcessesJournal of Geophysical Research: Earth Surface
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Projecting Exposure to Extreme Climate Impact Events Across Six Event Categories and Three Spatial Scales

2020

Summarization: The extent and impact of climate‐related extreme events depend on the underlying meteorological, hydrological, or climatological drivers as well as on human factors such as land use or population density. Here we quantify the pure effect of historical and future climate change on the exposure of land and population to extreme climate impact events using an unprecedentedly large ensemble of harmonized climate impact simulations from the Inter‐Sectoral Impact Model Intercomparison Project phase 2b. Our results indicate that global warming has already more than doubled both the global land area and the global population annually exposed to all six categories of extreme events co…

010504 meteorology & atmospheric sciencesHYDROLOGICAL MODELSPopulation0207 environmental engineeringFLOOD RISKEnvironmental Sciences & Ecology02 engineering and technologySubtropics[SDU.STU.ME]Sciences of the Universe [physics]/Earth Sciences/Meteorology01 natural sciencesPopulation densityLatitudeClimate-related extreme events/dk/atira/pure/sustainabledevelopmentgoals/climate_actionEarth and Planetary Sciences (miscellaneous)SDG 13 - Climate ActionMeteorology & Atmospheric SciencesBURNED AREAGLOBAL CROP PRODUCTIONGeosciences Multidisciplinary020701 environmental engineeringeducation0105 earth and related environmental sciencesGeneral Environmental ScienceEvent (probability theory)education.field_of_studyScience & TechnologyLand useGlobal warmingGlobal warmingVEGETATION MODEL ORCHIDEEGeology15. Life on landTERRESTRIAL CARBON BALANCE13. Climate actionClimatologyPhysical SciencesTROPICAL CYCLONE ACTIVITYHURRICANE INTENSITYEnvironmental scienceTropical cycloneINTERANNUAL VARIABILITYLife Sciences & BiomedicineEnvironmental SciencesINCORPORATING SPITFIRE
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High-resolution spectroscopy and analysis of the nu3/2nu4 dyad of CF4

2011

International audience; CF4 is a strong greenhouse gas of both anthropogenic and natural origin [D.R. Worton et al., Environ. Sci. Technol. 41, 2184 (2007)]. However, high-resolution infrared spectroscopy of this molecule has received only a limited interest up to now. Until very recently, the public databases only contained cross-sections for this species, but no detailed line list. We reinvestigate here the strongly absorbing ν3 region around 7.8 μm. New Fourier transform infrared (FTIR) spectra up to a maximal resolution of 0.0025 cm−1 have been recorded: (i) room-temperature spectra in a static cell and (ii) a supersonic expansion jet spectrum at a 23 K estimated temperature. Following …

010504 meteorology & atmospheric sciencesInfraredBiophysicsAnalytical chemistryInfrared spectroscopycarbon tetrafluoride01 natural sciencesSpectral linesymbols.namesake0103 physical sciencesPhysical and Theoretical ChemistryFourier transform infrared spectroscopySpectroscopyMolecular Biologyemi-classical analysis0105 earth and related environmental sciences010304 chemical physicsChemistryResolution (electron density)Condensed Matter Physics[ PHYS.PHYS.PHYS-CHEM-PH ] Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]Fourier transform13. Climate actiongreenhouse gassymbolsinfrared absorption[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]tensorial formalismMicrowave
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