Search results for "TRANSITION"
showing 10 items of 3988 documents
Identification of isomeric states in the N=73 neutron-deficient nuclei 132Pr and 130La
2012
Decays from isomeric states in the neutron-deficient N=73 nuclei 132Pr and 130La have been observed for the first time. Half-lives of 486(70) ns and 2.46(4) μs were measured for two isomeric states in 132Pr. The decay from the 486ns (8 -) isomer has been interpreted as a hindered E1 transition from the bandhead state of the excited πh 11/2νg 7/2 configuration. The decay from the 2.5 μs (8 +) isomer is consistent with the Weisskopf estimate for a low-energy E2 transition. An analogous 0.74(3) μs decay from an (8 +) isomer in the neighboring isotone 130La has also been observed which similarly can be explained if the transition has E2 character. The Weisskopf interpretation for the isomer hin…
Coulomb excitation of 222Rn
2022
International audience; The nature of quadrupole and octupole collectivity in $^{222}$Rn was investigated by determining the electric-quadrupole (E2) and octupole (E3) matrix elements using subbarrier, multistep Coulomb excitation. The radioactive $^{222}$Rn beam, accelerated to 4.23 MeV/u, was provided by the HIE-ISOLDE facility at CERN. Data were collected in the Miniball $\gamma$ -ray spectrometer following the bombardment of two targets, $^{120}$Sn and $^{60}$Ni. Transition E2 matrix elements within the ground-state and octupole bands were measured up to 10 ¯h and the results were consistent with a constant intrinsic electric-quadrupole moment, 518(11) $e$ fm$^2$ . The values of the int…
Synthesis and characterization of chalcogenide glasses from the system Ga-Ge-Sb-S and preparation of a single-mode fiber at 1.55 μm
2008
International audience; The aim of this work is to study different compositions in the Ga-Ge-Sb-S system for the definition of two compositions compatible with the elaboration of a single-mode fiber at the 1.55 μm telecom wavelength. The variations of the glass transition temperature (Tg), the dilatation coefficient (α) and the refractive index (n) have been studied for two glasses series: GaxGe25−xSb10S65 (series 1), Ga5Ge25−xSb10S60+x (series 2). This study has lead to the choice of the Ga4Ge21Sb10S65 composition as clad glass for the preparation of the single-mode fiber and Ga5Ge20Sb10S65 composition as the core. The discrepancies for the studied parameters between the core and clad comp…
Quantum-chemical determination of Born–Oppenheimer breakdown parameters for rotational constants: the open-shell species CN, CO+ and BO
2013
The quantum-chemical protocol for computing Born-Oppenheimer breakdown corrections to rotational constants in the case of diatomic molecules is extended to open-shell species. The deviation from the Born-Oppenheimer equilibrium rotational constant is obtained by considering three contributions: the adiabatic correction to the equilibrium bond distance, the electronic contribution to the moment of inertia requiring the computation of the rotational g-tensor, and the so-called Dunham correction. Values for the Born-Oppenheimer breakdown parameters of CN, CO+, and BO in their (2)sigma(+) electronic ground states are reported based on coupled-cluster calculations of the involved quantities and …
H-He collision-induced satellite in the Lyman alpha profile of DBA white dwarf stars
2020
The spectra of helium-dominated white dwarf stars with hydrogen in their atmosphere present a distinctive broad feature centered around 1160~\AA\/ in the blue wing of the Lyman-$\alpha$ line. It is extremely apparent in WD 1425+540 recently observed with HST COS. With new theoretical line profiles based on ab initio atomic interaction potentials we show that this feature is a signature of a collision-induced satellite due to an asymptotically forbidden transition. This quasi-molecular spectral satellite is crucial to understanding the asymmetrical shape of Lyman-$\alpha$ seen in this and other white dwarf spectra. Our previous work predicting this absorption feature was limited by molecular…
Do Vulnerable Youth Dream Of Precarious Employment? Decision Making at (In/Ex) clusion Pathways
2015
Este trabajo aborda el análisis de los discursos de jóvenes que han tenido dificultades en su itinerario educativo y que han participado en “itinerarios de segunda oportunidad”. A partir de entrevistas a jóvenes, pretendemos aproximarnos a los argumentos desde los que dan sentido a sus itinerarios académicos y a las decisiones a las que se han enfrentado. Estos argumentos muestran fuertes implicaciones de la posición social de los actores, y están influidos por agentes de la institución educativa y familiar. En ese marco los jóvenes van configurando unas expectativas de futuro. Estas expectativas se debaten entre tres vías: salidas a espacios laborales poco cualificados y precarios, aunque …
Profesorado : revista de curriculum y formación del profesorado
2015
Este trabajo aborda el análisis de los discursos de jóvenes que han tenido dificultades en su itinerario educativo y que han participado en 'itinerarios de segunda oportunidad'. A partir de entrevistas a jóvenes, pretendemos aproximarnos a los argumentos desde los que dan sentido a sus itinerarios académicos y a las decisiones a las que se han enfrentado. Estos argumentos muestran fuertes implicaciones de la posición social de los actores, y están influidos por agentes de la institución educativa y familiar. En ese marco los jóvenes van configurando unas expectativas de futuro. Estas expectativas se debaten entre tres vías: salidas a espacios laborales poco cualificados y precarios, aunque …
Water absorption and hydrothermal ageing of epoxy adhesives reinforced with amino-functionalized graphene oxide nanoparticles
2021
Abstract The study is focused on quantitative characterization of water absorption and hydrothermal ageing effects in a room-temperature amine cured epoxy adhesive widely used in automotive, aerospace, construction, and marine industries. Amino-functionalized graphene oxide (mGO) nanoparticles were incorporated into the epoxy (up to 1.72 wt.%) enabled cross-linking reactions and providing high interfacial adhesion, superior reinforcement efficiency and enhanced resistance to hydrothermal ageing of nanocomposites. Anomalous water absorption accompanied by progressive weight loss of samples (down to 7%) is fitted by two-stage models considering additive and coupled contribution from water dif…
Vibrational analysis of Ni(II)- and Cu(II)-octamethylchlorin by polarized resonance Raman and Fourier transform infrared spectroscopy
2001
We measured the polarized resonance Raman spectra of Cu(II)-2,2,7,8,12,13,17,18-octamethylchlorin in CS2 at various excitation wavenumbers in a spectral region covering the Qy, Qx and Bx optical absorption bands. Additionally, we measured the FTIR-Raman spectrum of the highly overcrowded spectral region between 1300 and 1450 cm−1. The spectral decomposition was carried out by a self-consistent global fit to all spectra obtained. The thus identified Raman and IR lines were assigned by comparison with the resonance Raman spectra of Cu(II)-octaethylporphyrin, by utilizing their depolarization ratio dispersions and by a normal mode analysis. The latter was based on a modified transferable molec…
Electronic structure of p-type ultraviolet-transparent conducting CuScO2 films
2008
Abstract We investigate the electronic structure of CuScO 2 thin films grown on sapphire and mica substrates by pulsed laser deposition. X-ray diffraction and microanalysis confirm that the films have the expected delafossite crystal structure and stoichiometric proportions. The electronic structure is investigated by means of X-ray and ultraviolet photoelectron spectroscopy. Electronic states in the range 0–1350 eV are identified, making reference to theoretical density-of-states calculations up to 80 eV. Photoelectron spectra near the Fermi energy confirm the p-character of the films. Optical absorption spectroscopy shows that the films are transparent up to 3.7 eV and exhibit an intense …