Search results for "Temperatures"
showing 10 items of 70 documents
Coadsorption of hydrogen and deuterium on zeolites at cryogenic temperatures : influence of the sorbent’s properties on selectivity
2019
The adsorption of hydrogen and deuterium (single gases and mixtures) was studied on a series of zeolites with varied parameters (Si/Al ratio, nature of the charge-compensating cation, pore geometry and diameter of pore aperture). Thermodynamic adsorption selectivities towards deuterium with respect to hydrogen were measured in a large pressure range (0.1 – 1000 hPa) and for several temperatures (45 – 100 K). The adsorption selectivity was assessed using direct coadsorption measurements performed by manometry coupled with mass spectrometry. For all studied zeolites and experimental conditions, the coadsorption process is selective towards deuterium, in agreement with the literature. However,…
Thermal nucleation of cavities in liquid helium at negative pressures
1993
We have investigated the nucleation rate at which cavities are formed in $^{4}\mathrm{He}$ and $^{3}\mathrm{He}$ at negative pressures due to thermal fluctuations. To this end, we have used a density functional that reproduces the He liquid-gas interface along the coexistence line. The inclusion of thermal effects in the calculation of the barrier against nucleation results in a sizable decrease of the absolute value of the tensile strength above 1.5 K.
Microwave characterization and modeling of packaged HEMTs by a direct extraction procedure at cryogenic temperatures
2004
In the present work we employ a direct extraction procedure to determine small signal equivalent circuit of microwave GaAs FETs by means of scattering (S-) parameter measurements down to cryogenic temperatures. The direct extraction procedure was tested on packaged AlGaAs/InGaAs HEMTs and good agreement between the simulated and measured S-parameters was obtained at different bias and temperature conditions. We employed a properly designed cryogenic set-up operating in our laboratory that allows to perform DC and RF characterization down to 30 K.
Superconducting tantalum nitride-based normal metal-insulator-superconductor tunnel junctions
2014
We report the development of superconducting tantalum nitride (TaN$_{x} $) normal metal-insulator-superconductor (NIS) tunnel junctions. For the insulating barrier, we used both AlO$_{x}$ and TaO$_{x}$ (Cu-AlO$_{x}$-Al-TaN$_{x} $ and Cu-TaO$_{x}$-TaN$_{x} $), with both devices exhibiting temperature dependent current-voltage characteristics which follow the simple one-particle tunneling model. The superconducting gap follows a BCS type temperature dependence, rendering these devices suitable for sensitive thermometry and bolometry from the superconducting transition temperature $T_{\text{C}}$ of the TaN$_{x} $ film at $\sim 5$ K down to $\sim$ 0.5 K. Numerical simulations were also performe…
Ab initio studies on the lattice thermal conductivity of silicon clathrate frameworks II and VIII
2016
The lattice thermal conductivities of silicon clathrate frameworks II and VIII are investigated by using ab initio lattice dynamics and iterative solution of the linearized Boltzmann transport equation(BTE) for phonons. Within the temperature range 100-350 K, the clathrate structures II and VIII were found to have lower lattice thermal conductivity values than silicon diamond structure (d-Si) by factors of 1/2 and 1/5, respectively. The main reason for the lower lattice thermal conductivity of the clathrate structure II in comparison to d-Si was found to be the harmonic phonon spectra, while in the case of the clathrate structure VIII, the difference is mainly due to the harmonic phonon spe…
Simulation of extreme heat events over the Valencia coastal region: Sensitivity to initial conditions and boundary layer parameterizations
2019
The Valencia coastal region (Western Mediterranean) is especially sensitive to extreme heat events, where they are really common. However, due to its geophysical characteristics and climatic conditions, the incidence of high and extreme temperatures may still be modulated over this area by means of sea breeze circulations, defining a Sea Breeze Convergence Zone (SBCZ) due to the meet and interaction of these mesoscale conditions and Western synoptic-scale wind regimes. A proper definition of this convergence zone is of significant importance over the study area for the simulation and forecast of intense-heat meteorological events. This study analyses a week period in August 2010 over this a…
Impact of Initial Soil Temperature Derived from Remote Sensing and Numerical Weather Prediction Datasets on the Simulation of Extreme Heat Events
2016
Extreme heat weather events have received increasing attention and has become of special importance as they can remarkably affect sectors as diverse as public health, energy consumption, water resources, natural biodiversity and agricultural production. In this regard, summer temperatures have become a parameter of essential interest under a framework of a hypothetical increase in the number of intense-heat conditions. Thus, their forecast is a crucial aspect bearing in mind a mitigation of the effects and impacts that these intense-heat situations could produce. The current work tries to reach a better understanding of these sorts of situations that are really common over the Western Medit…
Engineering thermal conductance using a two-dimensional phononic crystal
2014
Controlling thermal transport has become relevant in recent years. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centres in the material (nanoparticles, impurities, etc). Here we take another approach and demonstrate that one can also use coherent band structure effects to control phonon thermal conductance, with the help of periodically nanostructured phononic crystals. We perform the experiments at low temperatures below 1 K, which not only leads to negligible bulk phonon scattering, but also increases the wavelength of the dominant thermal phonons by more than two orders of magnitude compared to room temperature…
Protein isotope effects in dihydrofolate reductase from Geobacillus stearothermophilus show entropic-enthalpic compensatory effects on the rate const…
2014
Catalysis by dihydrofolate reductase from the moderately thermophilic bacterium Geobacillus stearothermophilus (BsDHFR) was investigated by isotope substitution of the enzyme. The enzyme kinetic isotope effect for hydride transfer was close to unity at physiological temperatures but increased with decreasing temperatures to a value of 1.65 at 5 °C. This behavior is opposite to that observed for DHFR from Escherichia coli (EcDHFR), where the enzyme kinetic isotope effect increased slightly with increasing temperature. These experimental results were reproduced in the framework of variational transition-state theory that includes a dynamical recrossing coefficient that varies with the mass of…
Modulation of metallothionein and metal partitioning in liver and kidney of Solea senegalensis after long-term acclimation to two environmental tempe…
2014
9 pages, 3 figures, 5 tables