Search results for "Thermal"

The role of transportation and its involved sources of energy in the environmental assessment of marble producing sites

2018

Marble is acquiring large popularity as building material. Since building materials are now required to be characterized by high energy and environmental performances, marble is entailed to fulfill top-level requirements. About its environmental performances an important European Decision establishes criteria for the award of the Community eco-label to this material. Unfortunately, this Decision is focused on mining and processing activities, seemingly neglecting marble transport. In contrast, this phase affects the whole working chain because it releases (pollutant) emissions and involves the use of primary and, in case, secondary energy sources. Here, the focus is on the role played by tr…

Water diffusion and swelling stresses in ionizing radiation cured epoxies as matrices for carbon fiber composites

2017

Cross-linking polymerization initiated by high energy radiation is a very attractive technique for the production of high performance composite materials. This method in fact offers many advantages compared to conventional thermal curing processes, due to the possibility to operate at mild temperature and in short time, limiting both energy and time consuming [1-2]. High performance composite materials mainly consist of epoxy resins as matrix and carbon fibers as reinforce, due to their excellent properties in terms of thermal and mechanical resistance. An important requirement of such systems for structural applications is their ability to maintain the properties within a fixed range durin…

Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure

2007

7-Bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine 1 at 1.7 atm and 100ºC decompose to form a pyridylcarbene intermediate by nitrogen expulsion. The carbene stabilization give 2-bromo-6- vinylpyridine 2, 1-(6-bromopyridin-2-yl)ethanol 3, 1-(6-Bromopyridin-2-yl)ethanone 4, 2- bromo-6-[2-(6-bromopyridin-2-yl)-2-methyl-trans-cyclopropyl]pyridine 5, and 2-bromo-6-[2-(6- bromopyridin-2-yl)-2-methyl-cis-cyclopropyl]pyridine 6. Abarca Gonzalez, Belen, Belen.Abarca@uv.es ; Ballesteros Campos, Rafael, Rafael.Ballesteros@uv.es

Optimization of ZnO:Al/Ag/ZnO:Al structures for ultra-thin high-performance transparent conductive electrodes

2012

Al-doped ZnO (AZO)/Ag/AZO multilayer coatings (50-70 nm thick) were grown at room temperature on glass substrates with different silver layer thickness, from 3 to 19 nm, by using radio frequency magnetron sputtering. Thermal stability of the compositional, optical and electrical properties of the AZO/Ag/AZO structures were investigated up to 400 °C and as a function of Ag film thickness. An AZO film as thin as 20 nm is an excellent barrier to Ag diffusion. The inclusion of 9.5 nm thin silver layer within the transparent conductive oxide (TCO) material leads to a maximum enhancement of the electro-optical characteristics. The excellent measured properties of low resistance, high transmittanc…

Granular chains for the assessment of thermal stress in slender structures

2015

Slender beams subjected to compressive stress are common in civil and mechanical engineering. The rapid in-situ measurement of this stress may prevent structural anomalies. In this paper, we describe the coupling mechanism between highly nonlinear solitary waves (HNSWs) propagating along an L-shaped granular system and a beam in contact with the granular medium. We evaluate the use of HNSWs as a tool to measure stress in thermally loaded structures and to estimate the neutral temperature, i.e. the temperature at which this stress is null. We investigated numerically and experimentally one and two L-shaped chains of spherical particles in contact with a prismatic beam subjected to heat. We f…

Injectable Hydrogel for Synergetic Low Dose Radiotherapy, Chemodynamic Therapy and Photothermal Therapy

2021

Higher doses of radiotherapy (RT) are associated with resistance induction, therefore highly selective and controllable radiosensitizers are urgently needed. To address this issue, we developed a FeGA-based injectable hydrogel system (FH) that can be used in combination with low-dose radiation. Our FH can deliver FeGA directly to the tumor site via intratumoral injection, where it is a reservoir-based system to conserve FeGA. The photothermal properties of FeGA steadily dissolve FH under laser irradiation, and, simultaneously, FeGA reacts with a large amount of H2O2 in the cell to produce OH (Fenton reaction) which is highly toxic to mitochondria, rendering the cell inactive and reducing ra…

Il miglioramento energetico nel recupero degli edifici storici. Applicazione al patrimonio architettonico palermitano

L'architettura storica può assumere un ruolo rilevante nel raggiungimento degli obiettivi europei di efficienza energetica per il settore edile, obiettivi che, tuttavia, devono essere compatibili con la conservazione del patrimonio storico e del suo valore culturale. A tal fine è necessario far riferimento ai caratteri specifici dell'architettura storica e alla sua dimensione locale. La presente tesi, sulla base di tale assunto, esamina le prestazioni energetiche degli edifici storici e il loro potenziale miglioramento, concentrandosi sul patrimonio architettonico di Palermo, caso di studio significativo per l'area mediterranea. La ricerca, condotta con riferimento sia alla scala urbana sia…

Local structure of perovskites ReO3and ScF3with negative thermal expansion: interpretation beyond the quasiharmonic approximation

2016

We propose an approach beyond the quasiharmonic approximation for interpretation of EXAFS and XRD data and for ab initio calculations of electronic and vibration properties of materials with negative thermal expansion. Ab initio electronic structure and lattice dynamics calculations for cubic and distorted ScF3 were performed using the linear combination of atomic orbitals (LCAO) method. The band gap obtained in calculations for ScF3 is equal to 10.54 eV and agree well with the expected value. The calculated infrared spectra of F displaced (FD) cubic ScF3 allow us to predict that its mean Sc-F-Sc angle within NTE deviates from 180 degree.

Positive ion extraction across the superfluid-vapor helium interface

2009

The extraction efficiency of positive (219)Rn ions across the superfluid-vapor helium interface above similar to 1.3 K indicates that extraction results from thermal activation across a barrier of about 20 K. Below similar to 1.3 K, the extraction efficiency is constant at about 0.7%. The evaporation of the superfluid surface by second sound pulses has a negative impact on the ion extraction, but not on the ions themselves. It takes 3.2( 6) s at 1.60 K and 15( 6) s at 1.15 K for the extraction process to recover from a disturbed state of yet unknown nature.

Maximizing phonon thermal conductance for ballistic membranes

2007

At low temperatures, phonon scattering can become so weak that phonon transport becomes ballistic. We calculate the ballistic phonon conductance G for membranes using elasticity theory, considering the transition from three to two dimensions. We discuss the temperature and thickness dependence and especially concentrate on the issue of material parameters. For all membrane thicknesses, the best conductors have, counter-intuitively, the lowest speed of sound.