Search results for "Time-of-flight"
showing 10 items of 61 documents
Calibration of a neutron time-of-flight multidetector system for an intensity interferometry experiment
2004
We present the details of an experiment on light particle interferometry. In particular, we focus on a time-of-flight technique which uses a cyclotron RF signal as a start and a liquid scintillator time signal as a stop, to measure neutron energy in the range of En approximate to 1.8-150 MeV. This dynamic range (up to 300 ns) is much larger than the beam bunch separation (54 ns) of the AGOR cyclotron (KVI). However, the problem of a short burst period is overcome by using the time information obtained from a fast projectile fragment phoswich detector. The complete analysis procedure to extract the final neutron kinetic energy spectra, is discussed. (C) 2003 Elsevier B.V. All rights reserved.
Secondary electron flight times and tracks in the carbon foil time pick-up detector
2014
Carbon foil time pick-up detectors used in the time-of-flight measurements of MeV energy ions have been studied in connection to time-of-flight-energy spectrometer used for heavy ion elastic recoil detection analysis. In experimental coincident TOF-E data characteristic halos are observed around light element isobars, and the origin of these halos were studied. The experimental data indicated that these halos originate from single electron events occurring before the electron multiplication in the microchannel plate. By means of electron trajectory simulations, this halo effect is explained to originate from single electron, emitted from the carbon foil, hitting the non-active area of the m…
A statistical design of experiments for optimizing the MALDI-TOF-MS sample preparation of polymers. An application in the assessment of the thermo-me…
2011
[EN] The sample preparation procedure for MALDI-TOF MS of polymers is addressed in this study by the application of a statistical Design of Experiments (DoE). Industrial poly (ethylene terephthalate) (PET) was chosen as model polymer. Different experimental settings (levels) for matrixes, analyte/matrix proportions and concentrations of cationization agent were considered. The quality parameters used for the analysis were signal-to-noise ratio and resolution. A closer inspection of the statistical results provided the study not only with the best combination of factors for the MALDI sample preparation, but also with a better understanding of the influence of the different factors, individua…
Assessing the MALDI-TOF MS sample preparation procedure to analyze the influence of thermo-oxidative ageing and thermo-mechanical degradation on poly…
2011
[EN] Multiple processing by means of successive injection cycles was used to simulate the thermo-mechanical degradation effects on the oligomeric distribution of PLA under mechanical recycling. Likewise, an accelerated thermal ageing over PLA glass transition was performed in order to simulate its service life. MALDI-TOF MS was used for the analysis and the sample preparation procedure was assessed by means of a statistical Design of Experiments (DoE). The quality effects in use for the analysis were signal-to-noise ratio and Resolution. Different matrixes, analyte/matrix proportions and the use of NaTFA as cationization agent were considered. A deep inspection of the statistical results pr…
Cluster calibration in mass spectrometry: laser desorption/ionization studies of atomic clusters and an application in precision mass spectrometry.
2003
For accurate mass measurements and identification of atomic and molecular species precise mass calibration is mandatory. Recent studies with laser desorption/ionization and time-of-flight analysis of cluster ion production by use of fullerene and gold targets demonstrate the generation of atomic clusters for calibration purposes. Atomic ion results from the Penning trap mass spectrometer ISOLTRAP, in which a carbon cluster ion source has recently been installed, are presented as an application in the field of precision mass spectrometry.
Principle and analytical applications of resonance lonization mass spectrometry
1989
Resonance ionization mass spectrometry (RIMS) is a very sensitive analytical technique for the detection of trace elements. This method is based on the excitation and ionization of atoms with resonant laser light followed by mass analysis. It allows element and, in some cases, isotope selective ionization and is applicable to most of the elements of the periodic table. A high selectivity can be achieved by applying three step photoionization of the elements under investigation and an additional mass separation for an unambiguous isotope assignment. An effective facility for resonance ionization mass spectrometry consists of three dye lasers which are pumped by two copper vapor lasers and of…
Laser desorption/ionization cluster studies for calibration in mass spectrometry
2003
Precise mass calibration is mandatory in many fields of mass spectrometry. We have performed laser desorption/ionization cluster studies with a MALDI-TOF mass spectrometer on gold and fullerene targets to produce atomic clusters. These investigations demonstrate that clusters are ideally suited for this purpose. Pulsed N 2 -laser and Nd:YAG-laser ablation was used to produce positively as well as negatively charged clusters. Earlier observations of dianionic metal clusters are confirmed. First results from the tandem Penning trap mass spectrometer ISOLTRAP using carbon clusters as mass references show how carbon clusters can be applied to precision mass spectrometry by providing absolute ma…
Analysis of complex autoantibody repertoires by surface-enhanced laser desorption/ionization-time of flight mass spectrometry
2003
Normal sera contain a large number of naturally occurring autoantibodies which can mask important disease-associated ones. Western blotting has evolved as the most important tool to demonstrate autoantibodies in autoimmune diseases, because of its ability to simultaneous screening for a wide spectrum of different antigens. In previous studies we have shown the diagnostic potential of the analysis of autoantibodies in autoimmune diseases by means of multivariate statistics and artificial neural networks. However, the Western blotting procedure remains very time-consuming and is also limited in sensitivity. Therefore, we used an on-chip approach for the analysis of autoantibodies. This Protei…
High Resolution Time Domain Reflectometry for Dielectric State Monitoring in High Voltage Cables
2017
A high resolution Time Domain Reflectometry system has been designed in order to investigate the possibility of measuring with good accuracy the dielectric properties of high voltage cables insulator materials by means of Time-of-Flight measures. The system employs a dedicated Time-To-Digital Converter in order to achieve a time resolution of 90 ps. By exploiting averaging techniques the resolution has been further increased. Experimental results showed the possibility of measuring the dielectric constant with a resolution of 0.03%.
Sensor Fusion Combining 3-D and 2-D for Depth Data Enhancement
2012
Time-of-Flight (ToF) cameras are known to be cost-efficient 3-D sensing systems capable of providing full scene depth information at a high frame rate. Among many other advantages, ToF cameras are able to provide distance information regardless of the illumination conditions and with no texture dependency, which makes them very suitable for computer vision and robotic applications where reliable distance measurements are required. However, the resolution of the given depth maps is far below the resolution given by standard 2-D video cameras which, indeed, restricts the use of ToF cameras in real applications such as those for safety and surveillance. In this thesis, we therefore investigate…