Search results for "Toe"

Linear, tripodal, macrocyclic: Ligand geometry and ORR activity of supported Pd(II) complexes

2021

Abstract The novel ligand H3L designed to spontaneously adsorb onto MWCNT via electron-deficient pyrimidine residues and bind metal cations is used to prepare an oxygen reduction reaction (ORR) cathode catalyst based on supported Pd(II) complexes. Herein we report the synthesis of the ligand, its solution behaviour (protonation constants, binding constants for the test cation Cu(II), UV evidence of Cu(II) and Pd(II) complexes formation) and ORR performances together with XPS and STEM characterization. Tripodal nature of the H3L ligand frame it in-between previously studied macrocyclic and linear open chain ligands, allowing to draw meaningful comparisons.

Low-Noise Amplification and Frequency Conversion with a Multiport Microwave Optomechanical Device

2016

High-gain amplifiers of electromagnetic signals operating near the quantum limit are crucial for quantum information systems and ultrasensitive quantum measurements. However, the existing techniques have a limited gain-bandwidth product and only operate with weak input signals. Here we demonstrate a two-port optomechanical scheme for amplification and routing of microwave signals, a system that simultaneously performs high-gain amplification and frequency conversion in the quantum regime. Our amplifier, implemented in a two-cavity microwave optomechanical device, shows 41 dB of gain and has a high dynamic range, handling input signals up to $10^{13}$ photons per second, three orders of magn…

Room-temperature polariton luminescence from a bulk GaN microcavity

2006

We report strong exciton-photon coupling at room temperature in a hybrid high quality bulk 3 lambda/2 GaN cavity with a bottom lattice-matched AlInN/AlGaN distributed Bragg reflector through angle-resolved polarized photoluminescence (PL). Coupling of the optically active free excitons (X-A, X-B, and X-C) to the cavity mode is demonstrated, with their contribution to the PL spectra varying with polarization. Under TE polarization, exciton oscillator strengths for X-A and X-B are about one order of magnitude larger than in bulk GaAs. Photoluminescence exhibits a strong bottleneck effect despite its thermal lineshape.

Structural quality of CH3NH3PbI3 perovskites for photovoltaic applications analyzed by electron microscopy techniques

2016

Web-wide imaging of paper; Analyzing the potential of on-line light transmittance measurement in quality control and diagnostics of paper

2013

State Preparation and Tomography of a Nanomechanical Resonator with Fast Light Pulses

2018

Pulsed optomechanical measurements enable squeezing, non-classical state creation and backaction-free sensing. We demonstrate pulsed measurement of a cryogenic nanomechanical resonator with record precision close to the quantum regime. We use these to prepare thermally squeezed and purified conditional mechanical states, and to perform full state tomography. These demonstrations exploit large photon-phonon coupling in a nanophotonic cavity to reach a single-pulse imprecision of 9 times the mechanical zero-point amplitude $x_\mathrm{zpf}$. We study the effect of other mechanical modes which limit the conditional state width to 58 $x_\mathrm{zpf}$, and show how decoherence causes the state to…

Practical system for the generation of pulsed quantum frequency combs

2017

The on-chip generation of large and complex optical quantum states will enable low-cost and accessible advances for quantum technologies, such as secure communications and quantum computation. Integrated frequency combs are on-chip light sources with a broad spectrum of evenly-spaced frequency modes, commonly generated by four-wave mixing in optically-excited nonlinear micro-cavities, whose recent use for quantum state generation has provided a solution for scalable and multi-mode quantum light sources. Pulsed quantum frequency combs are of particular interest, since they allow the generation of single-frequency-mode photons, required for scaling state complexity towards, e.g., multi-photon…

Novel Narrow-Band Spectral Interference Filter with Very High Transmittance

2011

We report a novel scheme to improve the effective transmission of a standard interference filter, and demonstrate over 97% passband transmission. Such high efficiency is critical for quantum information applications, e.g. high-efficiency single-photon generation utilizing parametric down-conversion. The scheme can also be modified to function with a tilted filter, thereby allowing tuning of the passband frequency. In addition, the tilted configuration creates an infinite number of consecutive reflections from and transmissions through the filter, further improving the net filter transmission. Because spectral interference filters are a key element in optical quantum information experiments …

A single photon source based on NV centers in diamond nanocrystals

2009

The development of reliable devices to generate single photons is crucial for applications in quantum cryptography, as well as for fundamental quantum optics experiments. Due to their extremely high photostability at room temperature, optically active defects in solids, the so called color centers, are among the most promising candidates. Single NV(nitrogen-vacancy) centers in diamond have been demonstrated to be able to generate single photons and have already shown advantages compared to attenuated laser pulses in a quantum cryptography experiment [1]. The nitrogen-vacancy center (NV center) in diamond consists of a substitutional nitrogen atom and an adjacent vacancy. This complex exhibi…

Laser induced thermal profiles in thermally and optically thin films

1988

The temperature field generated by the weak absorption of a gaussian laser beam in an optically and thermally thin film bounded by two transparent plates is discussed. An analytical solution of the problem is presented together with an algorithm for the numerical integration. The influence of the finite thermal conductivity of the plates is shown in an example.