Search results for "Toe"

showing 10 items of 3824 documents

Simple, Fast, Bright, and Stable Light Sources

2012

In this work we show that solution-processed light-emitting electrochemical cells (LECs) based on only an ionic iridium complex and a small amount of ionic liquid exhibit exceptionally good performances when applying a pulsed current: sub-second turn-on times and almost constant high luminances (>600 cd m(-2) ) and power efficiencies over the first 600 h. This demonstrates the potential of LECs for applications in solid-state signage and lighting.

SIMPLE (dark matter experiment)Materials scienceLightbusiness.industryMechanical EngineeringAnalytical chemistryTin Compoundschemistry.chemical_elementIonic bondingElectrochemical TechniquesEquipment DesignThiophenesIridiumElectrochemical cellchemistry.chemical_compoundchemistryCoordination ComplexesMechanics of MaterialsIonic liquidPolystyrenesOptoelectronicsGeneral Materials ScienceGlassIridiumbusinessAdvanced Materials
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Towards Si-based photonic circuits: Integrating photonic crystals in silicon-on-insulator platforms

2007

In the context of Si-based photonics, we report on a strategy to integrate two optical components, a 3D photonic crystal light emitter and a waveguide, in a silicon-on-insulator patterned substrate. Self-assembled colloidal photonic crystals are produced with high crystalline quality and spatial selectivity. Plane wave expansion and finite-difference time-domain have been used to find suitable configurations for positioning emitters and waveguides. The first steps toward the realisation of these configurations are presented.

SOIMaterials sciencebusiness.industryPhotonic integrated circuitPlane wavesiliconPhysics::OpticsSilicon on insulatorCondensed Matter PhysicsYablonoviteElectronic Optical and Magnetic Materialslaw.inventionsilicon-on-insulatorOpticslawphotonic crystalsMaterials ChemistryOptoelectronicsPlane wave expansionElectrical and Electronic EngineeringPhotonicsbusinessWaveguidePhotonic crystalSolid-State Electronics
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Influence of mobile ions on the electroluminescence characteristics of methylammonium lead iodide perovskite diodes

2016

In this work, we study the effect of voltage bias on the optoelectronic behavior of methylammonium lead iodide planar diodes. Upon biasing the diodes with a positive voltage, the turn-on voltage of the electroluminescence diminishes and its intensity substantially increases. This behavior is reminiscent of that observed in light-emitting electrochemical cells (LECs), single-layer electroluminescent devices in which the charge injection is assisted by the accumulation of ions at the electrode interface. Because of this mechanism, performances are largely independent from the work function of the electrodes. The similarities observed between planar perovskite diodes and LECs suggest that mobi…

SOLAR-CELLSMaterials scienceEMITTING ELECTROCHEMICAL-CELLSEXCITON BINDING-ENERGY02 engineering and technologyElectroluminescence010402 general chemistry01 natural sciencesElectrochemical cellEFFECTIVE MASSESRECENT PROGRESSGeneral Materials ScienceWork functionHYSTERESISPerovskite (structure)DiodeRenewable Energy Sustainability and the Environmentbusiness.industryBiasingGeneral ChemistryPERFORMANCE021001 nanoscience & nanotechnologyTURN-ON TIMESHALIDE PEROVSKITES0104 chemical sciencesP-N-JUNCTIONElectrodeOptoelectronics0210 nano-technologybusinessp–n junctionJournal of Materials Chemistry A
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Light absorption in silicon quantum dots embedded in silica

2009

The photon absorption in Si quantum dots (QDs) embedded in SiO2 has been systematically investigated by varying several parameters of the QD synthesis. Plasma-enhanced chemical vapor deposition (PECVD) or magnetron cosputtering (MS) have been used to deposit, upon quartz substrates, single layer, or multilayer structures of Si-rich- SiO2 (SRO) with different Si content (43-46 at. %). SRO samples have been annealed for 1 h in the 450-1250 °C range and characterized by optical absorption measurements, photoluminescence analysis, Rutherford backscattering spectrometry and x-ray Photoelectron Spectroscopy. After annealing up to 900 °C SRO films grown by MS show a higher absorption coefficient a…

SOLAR-CELLSPhotoluminescenceMaterials scienceEFFICIENCYSiliconAnalytical chemistryGeneral Physics and Astronomychemistry.chemical_elementChemical vapor depositionOPTICAL-PROPERTIESRutherford backscattering spectrometryFILMSSettore ING-INF/01 - Elettronica3RD-GENERATION PHOTOVOLTAICSSettore FIS/03 - Fisica Della MateriaMULTIPLE EXCITON GENERATIONchemistryX-ray photoelectron spectroscopyPlasma-enhanced chemical vapor depositionQuantum dotRAY PHOTOELECTRON-SPECTROSCOPYLUMINESCENCESI NANOCRYSTALSCOEFFICIENTAbsorption (electromagnetic radiation)
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Computational determination of the dominant triplet population mechanism in photoexcited benzophenone

2014

In benzophenone, intersystem crossing occurs efficiently between the S-1(n pi(star)) state and the T-1 state of dominant n pi(star) character, leading to excited triplet states after photoexcitation. The transition mechanism between S-1(n pi(star)) and T-1 is still a matter of debate, despite several experimental studies. Quantum mechanical calculations have been performed in order to assess the relative efficiencies of previously proposed mechanisms, in particular, the direct S-1 -> T-1 and indirect S-1 -> T-2(pi pi(star)) -> T-1 ones. Multiconfigurational wave function based methods are used to discuss the nature of the relevant states and also to determine minimum energy paths a…

STATE DIPOLE-MOMENTSPopulationMechanistic organic photochemistryEXCITED BENZOPHENONEGeneral Physics and AstronomyGAS-PHASEABSORPTION-SPECTROSCOPYchemistry.chemical_compoundORGANIC-PHOTOCHEMISTRYMOLECULAR WAVE-FUNCTIONSBenzophenonePhysical and Theoretical ChemistryeducationWave functioneducation.field_of_studyROW ATOMSChemistryCONICAL INTERSECTIONSPhotoexcitation[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryIntersystem crossingExcited state2ND-ORDER PERTURBATION-THEORYANO BASIS-SETSAtomic physicsPhosphorescence
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Optimization of surface plasmons launching from subwavelength hole arrays: modelling and experiments

2009

International audience; The launching of surface plasmons by micro-gratings of subwavelength apertures milled in a thick metal film is important for the development of surface plasmon based circuits. By comparing the near-field optical images of such surface plasmon sources with the results of a Huygens-Fresnel principle based scattering model, we show that the properties of the locally launched SP beams such as divergence or uniformity can be tuned by adjusting the shape of the micro-gratings. This allows us to propose an optimized source array well adapted for providing a narrow, collimated and uniform beam. (c) 2007 Optical Society of America.

SURFACE PLASMONMaterials science[SPI.NANO] Engineering Sciences [physics]/Micro and nanotechnologies/MicroelectronicsNanophotonicsPhysics::Optics02 engineering and technology01 natural sciencesCollimated light010309 opticsOptics0103 physical sciencesSCATTERING[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/MicroelectronicsDiffraction gratingPlasmonINTERFERENCEbusiness.industryScatteringSurface plasmon021001 nanoscience & nanotechnologySurface plasmon polaritonAtomic and Molecular Physics and OpticsOptoelectronics[ SPI.NANO ] Engineering Sciences [physics]/Micro and nanotechnologies/Microelectronics0210 nano-technologybusinessLocalized surface plasmon
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Scanning tunneling microscopy and spectroscopy of Mo clusters grown on TiO2(110).

2007

Molybdenum was deposited in two steps (3 eq. ML and 1 eq. ML) on the light blue rutile TiO2 10) (1 x 1) surface at room temperature, each Mo deposition cycle being followed by an annealing up to 950-1000 K. This procedure was found to lead to formation of separated clusters having a size in very wide range (1-20 nm). Scanning tunneling microscopy showed a dependence of the cluster morphology as a function of the size. The scanning tunneling spectra of Mo clusters was studied as a function of cluster dimensions and discussed in comparison with photoelectron spectroscopy results previously obtained for homogeneous Mo films. The dI/d V curves do not display the valence band structure of deposi…

SURFACEAnnealing (metallurgy)Schottky barrierScanning tunneling spectroscopyAnalytical chemistrychemistry.chemical_element02 engineering and technologyGrowth01 natural scienceslaw.inventionX-ray photoelectron spectroscopylaw0103 physical sciencesmorphologyMaterials ChemistryCluster (physics)GOLD010306 general physicsSpectroscopyroughnessMolybdenumNANOPOROUS TIO2 FILMSTitanium oxideScanning tunnelling spectroscopiesSurface structureSurfaces and Interfaces021001 nanoscience & nanotechnologyCondensed Matter PhysicsSurfaces Coatings and FilmsCrystallographyScanning tunnelling microscopyand topographychemistryMolybdenumScanning tunneling microscope0210 nano-technology
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Comparative study onSalmonellaisolation from sewage-contaminated natural waters

1984

Alcaide, E., Martinez, J.P. & Garay, E. 1984. Comparative study on Salmonella isolation from sewage contaminated natural waters. Journal of Applied Bacteriology56, 365–371. A comparative study of five factors influencing the isolation of salmonellas from sewage-contaminated natural waters was carried out. The effect of pre-enrichment in buffered peptone water was compared with single-step enrichment in NR10 broth incubated at 43dC. A modification of NR10 has been compared with the original composition. Bismuth sulphite agar (BSA), Hektoen enteric agar (HE) and brilliant green agar (BGA) have been used as plating media. Other factors considered have been temperature of the water and sampling…

Salmonellafood.ingredientSewageFresh WaterBiologymedicine.disease_causeApplied Microbiology and BiotechnologyMicrobiologyMicrobiologychemistry.chemical_compoundfoodSalmonellamedicineAgarFood scienceWater pollutionSewagebusiness.industryHektoen enteric agarContaminationIsolation (microbiology)Culture MediaBrilliant greenchemistryWater MicrobiologybusinessJournal of Applied Bacteriology
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New Acylated Triterpene Saponins from Silene fortunei that Modulate Lymphocyte Proliferation

2002

Three new acylated triterpene saponins 1-3, with a quillaic acid as aglycon, were isolated from the roots of Silene fortunei together with a known phytoecdysteroid (20-hydroxyecdysone). The compounds were characterized mainly by a combination of 2D NMR techniques, mass spectrometry, and chemical methods. Saponins 1-3, jenisseensosides C and D (4, 5), and 6 (deacylated form of 2/3 and 4/5) were found to stimulate the proliferation of the Jurkat tumor cell lines at low concentration. At high concentration, 2/3 and 4/5 inhibited the proliferation of the cells and suggested the induction of apoptosis.

SaponinPhytoecdysteroidPharmaceutical ScienceApoptosisLymphocyte proliferationPharmacognosyLymphocyte ActivationPlant RootsJurkat cellsAnalytical ChemistryJurkat CellsTriterpeneDrug DiscoveryHumansSileneNuclear Magnetic Resonance BiomolecularPharmacologychemistry.chemical_classificationSilenePlants MedicinalMolecular StructurebiologyHydrolysisOrganic ChemistryGlycosideAcetylationStereoisomerismSaponinsbiology.organism_classificationTriterpenesComplementary and alternative medicinechemistryBiochemistryMolecular MedicineJournal of Natural Products
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Design scaling laws for self-phase modulation-based 2R-regenerators

2006

We report global scaling laws linking the design of SPM-based 2R-regenerators to their ability to reduce amplitude noise and improve the signal extinction ratio.

Scaling lawEngineeringExtinction ratiobusiness.industryfungi02 engineering and technologysocial sciences01 natural sciencesSignalNoise (electronics)humanities010309 optics020210 optoelectronics & photonicsSignal-to-noise ratioControl theory0103 physical sciences0202 electrical engineering electronic engineering information engineeringElectronic engineeringDispersion (water waves)Self-phase modulationbusinessComputingMilieux_MISCELLANEOUSEfficient energy use
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