Search results for "Transition Temperature"
showing 10 items of 137 documents
Synergetic effect of host-guest chemistry and spin crossover in 3D Hofmann-like metal-organic frameworks [Fe(bpac)M(CN)4] (M=Pt, Pd, Ni).
2012
The synthesis and characterization of a series of three-dimensional (3D) Hofmann-like clathrate porous metal-organic framework (MOF) materials [Fe(bpac)M(CN) 4] (M=Pt, Pd, and Ni; bpac=bis(4-pyridyl)acetylene) that exhibit spin-crossover behavior is reported. The rigid bpac ligand is longer than the previously used azopyridine and pyrazine and has been selected with the aim to improve both the spin-crossover properties and the porosity of the corresponding porous coordination polymers (PCPs). The 3D network is composed of successive {Fe[M(CN) 4]} n planar layers bridged by the bis-monodentate bpac ligand linked in the apical positions of the iron center. The large void between the layers, w…
High temperature spin crossover in [Fe(pyrazine){Ag(CN) 2 } 2 ] and its solvate
2016
A high temperature spin crossover (Tup = 367 K) was detected in a metal–organic framework [Fe(pz){Ag(CN)2}2]·MeCN (pz = pyrazine). Upon heating, this solvate released acetonitrile guest molecules, which slightly shifted the transition temperature of the complex (Tup = 370 K and Tdown = 356 K).
Towards the N_f=2 deconfinement transition temperature with O(a) improved Wilson fermions: An update
2010
We give an update on our current project to determine the transition temperature and the order of the deconfinement transition in the chiral limit of two flavour QCD. We use nonperturbatively O(a) improved Wilson fermions of the Sheikholeslami-Wohlert type, employing the efficient deflation accelerated DDHMC algorithm. We start at lattices with N_t>=12 and pion masses below 600 MeV, aiming at chiral and continuum limits with light quarks.
Effect of disorder produced by cationic vacancies at theBsites on the electronic properties of mixed valence manganites
1999
An alloy series of single-phased polycrystalline ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Na}}_{x}{\mathrm{MnO}}_{3+\mathrm{\ensuremath{\delta}}} (0l~xl~0.15)$ has been synthesized in order to study the effect of disorder on the electronic properties of mixed valence manganites. The synthetic variables allow one to maintain a constant proportion of ${\mathrm{Mn}}^{4+}$ in the samples $({\mathrm{Mn}}^{3+}{/\mathrm{M}\mathrm{n}}^{4+}=2.1\ifmmode\pm\else\textpm\fi{}0.2),$ while the similar size of ${\mathrm{La}}^{3+}$ and ${\mathrm{Na}}^{+}$ ions results in no appreciable change in the tolerance factor of the perovskite structure throughout the series. In this way, the sodium content x contro…
Charge transfer in high-Tc(Y/Pr)Ba2Cu3O7superlattices
1996
We comment on the charge-transfer model for the unique softening of the apex [O(4)] oxygen observed in Raman spectra of a- and c-oriented (${\mathrm{YBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$${)}_{\mathit{m}}$(${\mathrm{PrBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$${)}_{\mathit{n}}$ superlattices presented in a recent paper by Ham et al. [Phys. Rev. B 50, 16 598 (1994)]. We find the size of the charge transfer necessary for the observed shift too large to explain the observations. In addition, a conclusion about the unique behavior of both types of superlattices can only be drawn if the sample quality is properly considered. \textcopyright{} 1996 The American Physical Society.
The manifestation of dipoles clustering in paraelectric phase of disordered ferroelectrics
2001
Abstract We predict the existence of Griffiths phase in the dielectrics with concentrational crossover between dipole glass (electric analog of spin glass) and ferroelectricity. The peculiar representatives of above substances are KTaO3: Li, Nb, Na or relaxor ferroelectrics like Pb1−xLaxZr0.65Ti0.35O3. Since this phase exists above ferroelectric phase transition temperature (but below that temperature for ordered substance), we call it “para-glass phase”. We assert that the difference between paraelectric and para-glass phase of above substances is the existence of clusters (inherent to “ordinary” Griffiths phase in Ising magnets) of correlated dipoles. We show that randomness play a decisi…
Effect of structural and compositional inhomogeneities on spin-glass transition in Hg1−x−yCrxMnySe crystals
2004
Abstract We report experimental results on the growth of Hg 1 −x−y Cr x Mn y Se crystals and their magnetic susceptibility χ ( T ) in dependence on the crystal structure and composition. It was found that the crystals with the Mn composition y =0.01–0.08 exhibit the spin-glass transition temperature T g =100–110 K. An increase of y value leads to the saturation of the χ max and T g characteristics in the composition ranges of y >0.06 and y >0.02, respectively. This phenomenon is explained as a result of phase-separated magnetic behavior caused by the formation of HgCr 2 Se 4 inclusions and textures.
Dynamical susceptibility from simulations of a mean field Potts glass
2004
Abstract We present results of the non-linear dynamic susceptibility χ(t) in a mean field Potts glass from simulations in a wide range of temperatures above the theoretically predicted dynamical transition, for various system sizes up to 2560 spins. χ(t) has a maximum, with a height that diverges like (T−TD)−α, with α≈1. The timescale t ∗ associated with this maximum also approaches a singularity, and we show that its behavior is compatible with the relaxation time of the standard time-dependent spin autocorrelation function, also with respect to finite size effects. We find that χ(t) for temperatures near the transition temperature TD satisfies a dynamical scaling property.
Guest Removal and External Pressure Variation Induce Spin Crossover in Halogen-Functionalized 2-D Hofmann Frameworks.
2020
The effect of halogen functionalization on the spin crossover (SCO) properties of a family of 2-D Hofmann framework materials, [FeIIPd(CN)4(thioX)2]·2H2O (X = Cl and Br; thioCl = (E)-1-(5-chlorothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine) and thioBr = (E)-1-(5-bromothiophen-2-yl)-N-(4H-1,2,4-triazol-4-yl)methanimine)), is reported. Inclusion of both the chloro- and bromo-functionalized ligands into the Hofmann-type frameworks (1Cl·2H2O and 2Br·2H2O) results in a blocking of spin-state transitions due to internal chemical pressure effects derived by the collective steric bulk of the halogen atoms and guest molecules. Cooperative one-step SCO transitions are revealed by either guest r…
Investigation of Temperature-Induced Phase Transitions in DOPC and DPPC Phospholipid Bilayers Using Temperature-Controlled Scanning Force Microscopy
2004
Under physiological conditions, multicomponent biological membranes undergo structural changes which help define how the membrane functions. An understanding of biomembrane structure-function relations can be based on knowledge of the physical and chemical properties of pure phospholipid bilayers. Here, we have investigated phase transitions in dipalmitoylphosphatidylcholine (DPPC) and dioleoylphosphatidylcholine (DOPC) bilayers. We demonstrated the existence of several phase transitions in DPPC and DOPC mica-supported bilayers by both atomic force microscopy imaging and force measurements. Supported DPPC bilayers show a broad L(beta)-L(alpha) transition. In addition to the main transition …